Synthesis of coordination polymers which show functions based on the tube type channels.
Project/Area Number |
21550059
|
Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Shizuoka University |
Principal Investigator |
KONDO Mitsuru 静岡大学, 機器分析センター, 准教授 (80254142)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
Keywords | 超分子錯体 / チャンネル構造 / チューブ状チャンネル / 多孔性固体 / 水素結合ネットワーク / 外部刺激応答型構造 / 二酸化炭素吸着 / ニッケル錯体 / 温度応答 / 小分子吸着 / 外部刺激 / 多孔性配位高分子 / 動的チャンネル / 結晶構造 / 構造変化 / 化学刺激 / 分子吸着 / 配位高分子 / 金属錯体 / 動的挙動 / 超分子 / 細孔構造 |
Research Abstract |
Tube-like channels were constructed by two methods ; one was by connections of metal complexes with intermolecular hydrogen bonds, and the other was by assemblies of 1D polymer complexes. The former compound showed collapse and reconstructions of the channel structures responding to the removal and re-contact of methanol, which was a part of building block of the tube frameworks. Particularly, this function was useful for adsorption of larger guest molecules induced by addition of methanol. The latter compound showed reversible structural changes of the tube-like channels responding to temperature-variation. The phase-transition properties were dependent on kinds of metal ions and guest molecules in the channels.
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Report
(4 results)
Research Products
(14 results)
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[Journal Article]2011
Author(s)
K. Yamanishi, M. Miyazawa, T. Yairi, S. Sakai, N. Nishina, Y. Kobori, M. Kondo, F. Uchida
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Journal Title
Angew. Chem. Int.
Volume: 50
Pages: 6583-6586
Related Report
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[Journal Article]2010
Author(s)
M. Kondo, H. Takahashi, H. Watanabe, Y. Shimizu, K. Yamanishi, M. Miyazawa, N. Nishina, Y. Ishida, H. Kawaguchi, F. Uchida
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Journal Title
Int. J. Mol. Sci.
Volume: 11
Pages: 2821-2838
Related Report
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[Journal Article] Syntheses and Characterization of New Nickel Coordination Polymers with 4,4'-Dipyridylsulfide. Dynamic Rearrangements of One-Dimensional Chains Responding to External Stimuli : Temperature Variation and Guest Releases/Re-Inclusions2010
Author(s)
M.Kondo, H.Takahashi, H.Watanabe, Y.Shimizu, K.Yamanishi, M.Miyazawa, N.Nishina, Y.Ishida, H.Kawaguchi, F.Uchida
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Journal Title
International Journal of Molecular Science
Volume: 12
Pages: 336-339
NAID
Related Report
Peer Reviewed
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