2015 Fiscal Year Final Research Report
Development of High Performance Heterogeneous Catalysts for Truly Powerful Liquid-Phase Organic Synthesis
Project/Area Number |
25289283
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
|
Research Institution | The University of Tokyo |
Principal Investigator |
YAMAGUCHI Kazuya 東京大学, 工学(系)研究科(研究院), 准教授 (50334313)
|
Project Period (FY) |
2013-04-01 – 2016-03-31
|
Keywords | 酸化反応 / 酸化的クロスカップリング / アンモニアを窒素源とした有機合成 / 新反応開発 / 固体触媒 |
Outline of Final Research Achievements |
In this study, we have developed highly active catalysts and efficient catalytic reaction systems for realizing environmentally-friendly new oxidation reactions using molecular oxygen as the terminal oxidant. By utilizing the acid and oxidation properties of heteropoly acids, thiadiazole synthesis through oxidative dimerization of thioamides and regioselective oxidative cyanation of quinolines have been developed. We have developed oxidative α-functionalization of amines and oxidative nucleophilic strategy for functionalization of thiols. Furthermore, several dehydrogenative cross-coupling reactions have been realized by using supported gold catalysts.
|
Free Research Field |
触媒化学
|