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Development of high efficiency dye-sensitized solar cells combing the ZnO nanostructures and carbon nanotubes as the electrodes

Research Project

Project/Area Number 24561060
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy engineering
Research InstitutionKochi University of Technology

Principal Investigator

LI CHAOYANG  高知工科大学, 公私立大学の部局等, 教授 (50461380)

Co-Investigator(Kenkyū-buntansha) KAWAHARAMURA Toshiyuki  高知工科大学, 公私立大学の部局等, 准教授 (00512021)
FURUTA Hiroshi  高知工科大学, 工学部, 准教授 (10389207)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords太陽電池 / ナノ構造 / 酸化物 / 透明導電膜 / アニーリング / 色素増感型薄膜太陽電池 / 酸化亜鉛 / ナノロート / 高配向 / ナノ構造体 / 色素増感太陽電池
Outline of Final Research Achievements

A novel dye-sensitized solar cell using ZnO nanostructures as photoanodes was fabricated successfully. The conductive and low-cost ITO substrates were synthesized, which was comparable to the commercial ones. The novel multiple-annealing process was developed for fabricating the ZnO nanostructures, the high-alignment, high transparency, and high stability of ZnO nanostructures were achieved at the low temperature. The morphology of ZnO nanorods was successfully modified by the mist CVD method.The large area and controllable ZnO nanorods were achieved, which contributed to the high efficiency absorption of dye.Finally the dye-sensitized solar cell was demonstrated using both ZnO nanorods and the TiO2 coated ZnO as photoanodes. The overall conversion efficiency of demonstrated ZnO-based solar cell was 5.48%.
This research supplied the new ideal and technique to fabricate the environment friendly solar cell, with the low cost and easy process.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (45 results)

All 2015 2014 2013 2012 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 2 results) Presentation (29 results) (of which Invited: 13 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Thickness of ITO thin film influences on fabricating ZnO nanorods applying for dye-sensitized solar cell2015

    • Author(s)
      Xin Li, Chaoyang Li , Shengwen Hou, Akimitsu Hatta, Jinhong Yu , Nan Jiang
    • Journal Title

      Composites Part B: Engineering

      Volume: 74 Pages: 147-152

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Epoxy composites filled with one-dimensional SiC nanowires two-dimensional grapheme nanoplatelets hybrid nanofillers2014

    • Author(s)
      Yi Wang, Jinhong Yu, Wen Dai, Dong Wang, Yingze Song, Hua Bai, Xufeng Zhou, Chaoyang Li, Cheng-Te Lin and Nan Jiang
    • Journal Title

      Royal Society of Chemistry

      Volume: 4 Issue: 103 Pages: 59409-59417

    • DOI

      10.1039/c4ra07878k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Zinc Oxide Nanostructures by Mist Chemical Vapor Deposition2014

    • Author(s)
      Xin Li, Chaoyang Li, Toshiyuki Kawaharamura, Dapeng Wang, Noriko Nitta, Mamoru Furuta, Hiroshi Furuta and Akimitsu Hatta
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 39(2) Pages: 161-164

    • NAID

      130005004316

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Substrates on Formation of Zinc Oxide Nanostructures by a Novel Reducing Annealing Method2014

    • Author(s)
      X. Li, C. Li, T. Kawaharamura, D. Wang, N. Nitta, M. Furuta, H. Furuta, and A. Hatta
    • Journal Title

      Nanoscience and Nanotechnology Letters

      Volume: 6 Issue: 2 Pages: 174-180

    • DOI

      10.1166/nnl.2014.1708

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure Transformation and Dielectric Properties of Polymer Composites Incorporating Zinc Oxide Nanorod2014

    • Author(s)
      J. Yu, W. Wu, D. Dai, Y. Song, C. Li, and N. Jiang
    • Journal Title

      Macromolecular Research, Vol. 22, No. 1, 19-25

      Volume: 22 Pages: 19-25

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure Transformation and Dielectric Properties of Polymer Composites Incorporating Zinc Oxide Nanorods2014

    • Author(s)
      J. Yu, W. Wu, D. Dai, Y. Song, C. Li, and N. Jiang
    • Journal Title

      Macromolecular Research

      Volume: 22 Pages: 13233-13233

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of drain bias on negative gate bias and illumination stress induced degradation in amorphous InGaZnO thin-film transistors2014

    • Author(s)
      D. Wang, M.-P. Hung, J. Jiang, T. Toda, C. Li, and M. Furuta
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 3S1 Pages: 03CC01-03CC01

    • DOI

      10.7567/jjap.53.03cc01

    • NAID

      210000143469

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Substrates on Formation ofZinc Oxide Nanostructures by a Novel Reducing Annealing Method2013

    • Author(s)
      Xin Li, Chaoyang Li, Toshiyuki Kawaharamura, Dapeng Wang,Noriko Nitta, Mamoru Furuta, Hiroshi Furuta, and Akimitsu Hatta
    • Journal Title

      Nanoscience and Nanotechnology Letters

      Volume: 5 Pages: 1-7

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Arrayed ZnO Nanorods Fabrication on ZnO Film by Self-catalyst Growth Method in Aqueous Solution2013

    • Author(s)
      E. K.C. Pradeep, X. Li, T. Kawaharamura, D.Wang, A. Hatta, C. Li*
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1584 Pages: 1204-1204

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of Well-Aligned ZnO Nanorods as Photoelectrode for Dye-Sensitized Solar Cell Application2013

    • Author(s)
      C. Li, D.Wang, T. Kawaharamura, N. Nitta, H. Furuta, A. Akimitsu
    • Journal Title

      EUPVSEC proceeding

      Volume: 2013 Pages: 434-437

    • DOI

      10.4229/28thEUPVSEC2013-1AV.3.24

    • Related Report
      2013 Research-status Report
  • [Journal Article] Stoichiometry control of ZnO thin film by adjusting working gas ratio during radio frequency magnetron sputtering2013

    • Author(s)
      C. Li, D. Wang, Z. Li, X. Li, M. Furuta, T. Kawaharamura
    • Journal Title

      Journal of Materials

      Volume: 2013 Pages: 1-7

    • DOI

      10.1155/2013/547271

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Well-arrayed ZnO nanostructures formed by multi-annealing processes at low temperature2012

    • Author(s)
      Dapeng Wang, Zeming Li, Toshiyuki Kawaharamura, Mamoru Furuta, Tadashi Narusawa, Chaoyang Li
    • Journal Title

      Physica Status Solidi C

      Volume: 9 Pages: 194-197

    • NAID

      120005729026

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] ZnO nanorods fabricated to apply as photanodes in DSSC2015

    • Author(s)
      Chaoyang Li
    • Organizer
      IUMRS-ICAM2015
    • Place of Presentation
      ICC, Jeju, Korea
    • Year and Date
      2015-10-25 – 2015-10-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Fabrication of ZnO Nanorods on AZO Substrates as Photoelectrodes for Dye-Sensitized Solar Cell Application2015

    • Author(s)
      Chaoyang Li
    • Organizer
      30th European Photovoltaic Solar Energy Conference and Exhibition
    • Place of Presentation
      Hamburg, Germany
    • Year and Date
      2015-09-14 – 2015-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Polyethylene Naphthalene Film as Substrate for Synthesizing ZnO Nanorods on AZO Layers at Low Temperature2015

    • Author(s)
      Chaoyang Li
    • Organizer
      The 22nd International Workshop on Active Matrix Flatpanel Display and Devices
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2015-07-01 – 2015-07-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Oxygen annealing effect on enhancement of green emission from ZnO nanorods recrystallized growth from sputtered ZnO thin film2015

    • Author(s)
      Chaoyang Li
    • Organizer
      Display Week 2015
    • Place of Presentation
      San Jose Convention Center, USA
    • Year and Date
      2015-06-02 – 2015-06-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Self-assembled ZnO Nanorods Synthesis Improved by Conductive Oxide Films in Chemical Bath Deposition2015

    • Author(s)
      Shengwen Hou
    • Organizer
      E-MRS Spring Meeting and Exhibit
    • Place of Presentation
      Lille, France
    • Year and Date
      2015-05-11 – 2015-05-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Well-controllable Fabrication of Aligned ZnO Nanorods for Dye sensitized Solar Cell Application2015

    • Author(s)
      Chaoyang Li
    • Organizer
      MRS Spring Meeting& Exhibition
    • Place of Presentation
      San Francisco, California, USA
    • Year and Date
      2015-04-06 – 2015-04-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Growth, Structural, and Cathodoluminescence Property of ZnO Nanorods Prepared with Low Temperature Reducing Annealing2014

    • Author(s)
      Chaoyang Li
    • Organizer
      IDW2014
    • Place of Presentation
      新潟、日本
    • Year and Date
      2014-12-02 – 2014-12-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Low-temperature Process for Nanostructured ZnO Thin Film Phosphor Fabrication2014

    • Author(s)
      Chaoyang Li
    • Organizer
      SID-Mid Europe 20th Anniversary Meeting
    • Place of Presentation
      Stuttgart, Germany
    • Year and Date
      2014-10-09 – 2014-10-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ZnO Nanostructures: Growth, Properties and Optoelectronic Application2014

    • Author(s)
      Xin Li
    • Organizer
      29th European Photovoltaic Solar Energy Conference and Exhibition
    • Place of Presentation
      Amsterdam, Nertherland
    • Year and Date
      2014-09-22 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fabrication of Vertical Aligned ZnO Nanorods on AZO Thin Film for Photovoltaic Applications2014

    • Author(s)
      Chaoyang Li
    • Organizer
      AM-FPD14
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2014-07-02 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] ZnO Nanostructures: Growth, Properties and Optoelectronic Application2014

    • Author(s)
      Chaoyang Li
    • Organizer
      IUMRS-ICAM2014
    • Place of Presentation
      Taiwan
    • Year and Date
      2014-06-10 – 2014-06-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ZnO Thin Film Phosphor Prepared on Different Substrates by Novel Multiple Reducing Annealing2014

    • Author(s)
      Chaoyang Li
    • Organizer
      SID display week 2014
    • Place of Presentation
      San Diago, USA
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] ZnO Nanostructures: Growth, Properties and Optoelectronic Application2014

    • Author(s)
      李 朝陽
    • Organizer
      International Union of Materials Research Societies – International Conference on Electronic Materials 2014 (IUMRS-ICEM 2014)
    • Place of Presentation
      Taipei World Trade Center Nangang (TWTC Nangang) Exhibition Hall in Taipei, Taiwan.
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Development of Well-aligned Zinc Oxide Nanorods as Photo Electrodes Applying for Dye-sensitized Solar Cell2013

    • Author(s)
      李 朝陽
    • Organizer
      2013 JSAP-MRSジョイントシンポジウム
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] A promising electrical and optical material- ZnO film and nano structures fabrication and application2013

    • Author(s)
      李 朝陽
    • Organizer
      2013 3rd ISSD Workshop on Advanced Materials for Energy
    • Place of Presentation
      広島大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] High luminance Nano-structured ZnO thin film fabrication2013

    • Author(s)
      李 朝陽
    • Organizer
      6th IEEE/International Conference on Advanced Infocomm Technology
    • Place of Presentation
      Hsinchu, Taiwan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] A novel method for fabrication well-aligned zno nanostructures2013

    • Author(s)
      李 朝陽
    • Organizer
      IEEE international Nanoelectronics Conference (INEC) 2013
    • Place of Presentation
      Singapore
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Single- crystalline ZnO Nanorods Fabricated by Mist Chemical Vapor Deposition for Optical Applications2013

    • Author(s)
      李 朝陽
    • Organizer
      International Display Workshop 13
    • Place of Presentation
      札幌コンベンションセンター、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Morphology Controlled Single-crystal ZnO Nanostructures Fabricated by a Novel Mist Chemical Vapor Deposition2013

    • Author(s)
      李 朝陽
    • Organizer
      SID Symposium, Seminar, and Exhibition(Display Week 2013)
    • Place of Presentation
      Vancouver,カナダ
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of High Conductive ITO Thin Film for Dye-sensitized Solar Cell Applications2013

    • Author(s)
      李 シン
    • Organizer
      International Workshop on Active-Matrix Flat pannel Displays and Devices (AM-FPF13)
    • Place of Presentation
      京都、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of Well-aligned ZnO Nanorods as Photoelectrode for Dye-sensitized Solar Cell Application2013

    • Author(s)
      李 シン
    • Organizer
      The 28th European Photovoltaic Solar Energy Conference and Exhibition
    • Place of Presentation
      Paris, フランス
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of Well-aligned Zinc Oxide Nanorods by a Novel Hybrid Method2013

    • Author(s)
      李 シン
    • Organizer
      IUMRS-ICAM2013 International Conference on Advanced Materials
    • Place of Presentation
      青島、中国
    • Related Report
      2013 Research-status Report
  • [Presentation] Arrayed ZnO Nanorods Fabrication on ZnO Film by Self-catalyst Growth Method in Aqueous Solution2013

    • Author(s)
      E.K.C. Pradeep
    • Organizer
      2013 JSAP-MRSジョイントシンポジウム
    • Place of Presentation
      同志社大学 日本
    • Related Report
      2013 Research-status Report
  • [Presentation] High Luminance Nano-structured Zinc Oxide Thin Film Fabrication2013

    • Author(s)
      李 朝陽
    • Organizer
      6th IEEE/International Conference on Advanced Infocomm Technology
    • Place of Presentation
      台湾
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] A novel method for fabrication well-aligned ZnO nanostructures2013

    • Author(s)
      李 朝陽
    • Organizer
      Nanoelectronics Conference (INEC) 2013
    • Place of Presentation
      シンガポール
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] A novel dye -sensitized solar cell using well- aligned ZnO nanorods2012

    • Author(s)
      李 朝陽
    • Organizer
      27thEuropean Photovoltaic Solar Energy Conference
    • Place of Presentation
      ドイツ
    • Related Report
      2012 Research-status Report
  • [Presentation] Self-organized growth ZnO based nanorods for photonic device application2012

    • Author(s)
      李 朝陽
    • Organizer
      The 12th International Meeting on Information Display (IMID12)
    • Place of Presentation
      韓国
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Effects of thickness on the optical properties of ZnO films prepared by radio frequency magnetron sputtering2012

    • Author(s)
      李 朝陽
    • Organizer
      20th Annual International Conference on Composites or Nano Engineering ( ICCE-20)
    • Place of Presentation
      中国
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 還元アニーリングより高配向酸化亜鉛ナノ構造作製2012

    • Author(s)
      李 朝陽
    • Organizer
      2012年秋季講演会
    • Place of Presentation
      日本
    • Related Report
      2012 Research-status Report
  • [Book] Oxide Thin Films, Multilayers, and Nanocomposites2015

    • Author(s)
      Paolo Mele, Tamio Endo, Shunichi Arisawa, Chaoyang Li, Tetsuo Tsuchiya
    • Total Pages
      316
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Book] Oxide Thin Films, Multilayers, and Nanocomposites2015

    • Author(s)
      Paolo Mele,Chaoyang Li, Shunichi Arisawa, Tetsuo Tsuchiya,Tamio Endo,
    • Total Pages
      300
    • Publisher
      Spinger
    • Related Report
      2013 Research-status Report
  • [Book] Controlled Fabrication-Advances and application2013

    • Author(s)
      李 朝陽
    • Total Pages
      738
    • Publisher
      Pan Stanford Publishing Pte. Ltd,Singapore
    • Related Report
      2012 Research-status Report
  • [Remarks] 教員情報:高知工科大学

    • URL

      http://www.kochi-tech.ac.jp/kut/about_KUT/faculty_members/prof/li-chaoyang.html

    • Related Report
      2013 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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