Issue 37, 2018, Issue in Progress

1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki–Miyaura coupling and the complex of the hexamer with C60

Abstract

A large 1,3-phenylene-bridged hexameric naphthalene wheel N6 and a heptameric wheel N7 were synthesized simply by Suzuki–Miyaura coupling via one-pot reaction from monomers. We could control the distribution of N6 and N7 via the reaction conditions. The hexameric wheel structure was revealed by X-ray diffraction analysis. The wheel N6 exhibited C60 encapsulation ability in the solid state, which was also confirmed by single crystal X-ray analysis.

Graphical abstract: 1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki–Miyaura coupling and the complex of the hexamer with C60

Supplementary files

Article information

Article type
Paper
Submitted
26 Apr 2018
Accepted
01 Jun 2018
First published
07 Jun 2018
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2018,8, 20872-20876

1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki–Miyaura coupling and the complex of the hexamer with C60

P. Mei, A. Matsumoto, H. Hayashi, M. Suzuki, N. Aratani and H. Yamada, RSC Adv., 2018, 8, 20872 DOI: 10.1039/C8RA03601B

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