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Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands

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Abstract

A new nickel(II) coordination polymer, Ni2(DBA)2(BIDPE)2(H2O) (1) (H2DBA = 4,4′-methylenedibenzoic acid and BIDPE = 4,4′-bis(imidazole-l-yl)diphenyl ether), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. Complex 1 features a one-dimensional chain structure based on triply bridged binuclear units, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions. Variable-temperature magnetic data shows weak antiferromagnetic behavior in 1.

Graphical Abstract

A new nickel(II) coordination polymer, Ni2(DBA)(BIDPE)(H2O), has been prepared by hydrothermal synthesis and features a one-dimensional chain structure based on triply bridged binuclear units. Variable-temperature magnetic data shows weak antiferromagnetic behavior

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 20971004, 20901004), the Key Project of Chinese Ministry of Education (No. 210102) and the Natural Science Foundation of Anhui Province (No. 11040606M45).

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Correspondence to Guang-Xiang Liu.

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Liu, GX., Zha, XC., Wang, Y. et al. Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands. J Inorg Organomet Polym 22, 258–263 (2012). https://doi.org/10.1007/s10904-011-9530-6

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  • DOI: https://doi.org/10.1007/s10904-011-9530-6

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