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New Polymeric Materials Based on Element-Blocks

Administrative Group

Project AreaCreation of Element-Block Polymer Materials
Project/Area Number 24102001
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University

Principal Investigator

Chujo Yoshiki  京都大学, 工学研究科, 教授 (70144128)

Co-Investigator(Kenkyū-buntansha) 菅原 義之  早稲田大学, 理工学術院, 教授 (50196698)
中 建介  京都工芸繊維大学, 工芸科学研究科, 教授 (70227718)
渡辺 明  東北大学, 多元物質科学研究所, 准教授 (40182901)
大下 浄治  広島大学, 工学(系)研究科(研究院), 教授 (90201376)
國武 雅司  熊本大学, 自然科学研究科, 教授 (40205109)
冨田 育義  東京工業大学, 総合理工学研究科(研究院), 教授 (70237113)
郡司 天博  東京理科大学, 理工学部, 教授 (20256663)
西野 孝  神戸大学, 工学(系)研究科(研究院), 教授 (40180624)
松川 公洋  地方独立行政法人大阪市立工業研究所, 電子材料研究部, その他 (90416321)
内藤 裕義  大阪府立大学, 工学(系)研究科(研究院), 教授 (90172254)
長谷川 靖哉  北海道大学, 工学(系)研究科(研究院), 教授 (80324797)
田中 一義  京都大学, 学内共同利用施設等, 研究員 (90155119)
Project Period (FY) 2012-06-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥263,380,000 (Direct Cost: ¥202,600,000、Indirect Cost: ¥60,780,000)
Fiscal Year 2016: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2015: ¥30,420,000 (Direct Cost: ¥23,400,000、Indirect Cost: ¥7,020,000)
Fiscal Year 2014: ¥30,550,000 (Direct Cost: ¥23,500,000、Indirect Cost: ¥7,050,000)
Fiscal Year 2013: ¥34,060,000 (Direct Cost: ¥26,200,000、Indirect Cost: ¥7,860,000)
Fiscal Year 2012: ¥142,350,000 (Direct Cost: ¥109,500,000、Indirect Cost: ¥32,850,000)
Keywords元素ブロック / 高分子
Outline of Final Research Achievements

A structural unit consisting of various groups of heteroatoms is defined an "element-block." By employing new element-blocks and achieving hierarchical interface control in order to yield the desired functions, the creation of new materials that share, at a high level, various properties not achievable with conventional organic polymeric materials as well as forming properties of molding processability and flexible designability that inorganic materials lack can be expected. Based on this idea, we have developed various kinds of element-blocks. Furthermore, highly-functional materials can be constructed by combination of element-blocks. From these results, we can say that new diagnoses for material designs were able to be established by our research group based on element-blocks.

Report

(6 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (32 results)

All 2014 2013 2012 Other

All Journal Article (24 results) (of which Peer Reviewed: 23 results) Presentation (7 results) (of which Invited: 5 results) Remarks (1 results)

  • [Journal Article] л-Conjugated Polymers Composed of BODIPY or Aza-BODIPY Derivatives Exhibiting High Electron Mobility and Low Threshold Voltage in Electron-Only Devices2014

    • Author(s)
      Yoshii, R. ; Yamane, H. ; Nagai, A. ; Tanaka, K. ; Taka, H. ; Kita, H. ; Chujo, Y.
    • Journal Title

      Macromolecules

      Volume: (印刷中)(Early View) Issue: 7 Pages: 2316-2323

    • DOI

      10.1021/ma5002047

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conjugated Polymers Based on Tautomeric Units : Regulation of Main-Chain Conjugation and Expression of Aggregation Induced Emission Property via Boron-Complexation2014

    • Author(s)
      Yoshii, R. ; Tanaka, K. ; Chujo, Y.
    • Journal Title

      Macromolecules

      Volume: (印刷中)(Early View) Issue: 7 Pages: 2268-2278

    • DOI

      10.1021/ma500082e

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of Three Radical Cations from a Single Photon Using a Photo Acid Generator2014

    • Author(s)
      Tanaka, K.; Ohashi, W.; Okada, H.; Chujo, Y.
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Issue: 9 Pages: 1635-1659

    • DOI

      10.1016/j.tetlet.2014.01.092

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Sulfonic Acid-Containing POSS and Its Filler Effects for Enhancing Thermal Stabilities and Lowering Melting Temperatures of Ionic Liquids2014

    • Author(s)
      Jeon, J.-H.; Tanaka, K.; Chujo, Y.
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 3 Pages: 624-630

    • DOI

      10.1039/c3ta14039c

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Dye Dispersibility in Silica Hybrids through Local Heating Induced by the Imidazolium Group under Microwave Irradiation2014

    • Author(s)
      Kajiwara, Y.; Tanaka, K.; Chujo, Y.
    • Journal Title

      Polym. J.

      Volume: 46 Issue: 3 Pages: 195-199

    • DOI

      10.1038/pj.2013.81

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Flexible Conductive Films Based on Polymer Composites with Tetrathiafulvalene Nanowires2013

    • Author(s)
      Tanaka, K.; Matsumoto, T.; Nakamura, K.; Kawabe, S.; Chujo, Y.
    • Journal Title

      Synth. Met.

      Volume: 180 Pages: 49-53

    • DOI

      10.1016/j.synthmet.2013.07.030

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Simultaneous Emission from RGB-Emitting Organoboron Dyes Incorporated into Organic-Inorganic Hybrids and Preparation of White Light-Emitting Materials2013

    • Author(s)
      Kajiwara, Y.; Nagai, A.; Tanaka, K.; Chujo, Y.
    • Journal Title

      J. Mater. Chem.

      Volume: 1 Issue: 29 Pages: 4437-4444

    • DOI

      10.1039/c3tc30276h

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Dibenzo[b,f]silepins with a Benzoquinolyl Ligand2013

    • Author(s)
      Tokoro, Y.; Tanaka, K.; Chujo, Y.
    • Journal Title

      Org. Lett.

      Volume: 15 Issue: 10 Pages: 2366-2369

    • DOI

      10.1021/ol400730n

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational Design of POSS Fillers for Simultaneous Improvements of Thermomechanical Properties and Lowering Refractive Indices of Polymer Films2013

    • Author(s)
      Jeon, J.-H.; Tanaka, K.; Chujo, Y.
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem.

      Volume: 51 Issue: 17 Pages: 3583-3589

    • DOI

      10.1002/pola.26757

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Modulation of Optical Properties of Diketonate-Containing Polymers by Regulating Complexation Ratios with Boron2013

    • Author(s)
      Tanaka, K.; Tamashima, K.; Nagai, A.; Okawa, T.; Chujo, Y.
    • Journal Title

      Macromolecules

      Volume: 46 Issue: 8 Pages: 2969-2975

    • DOI

      10.1021/ma400368e

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rapid Heat Generation under Microwave Irradiation by Imidazolium-Presenting Silica Nanoparticles2013

    • Author(s)
      Okada, H.; Kajiwara, Y.; Tanaka, K.; Chujo, Y.
    • Journal Title

      Colloids Surf., A

      Volume: 428 Pages: 65-69

    • DOI

      10.1016/j.colsurfa.2013.03.048

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hypoxic Conditions-Selective Upconversion via Triplet-Triplet Annihilation Based on POSS-Core Dendrimer Complexes2013

    • Author(s)
      Tanaka, K.; Okada, H.; Jeon, J.-H.; Inafuku, K.; Ohashi, W.; Chujo, Y.
    • Journal Title

      Bioorg. Med. Chem.

      Volume: 21 Issue: 10 Pages: 2678-2681

    • DOI

      10.1016/j.bmc.2013.03.029

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective Light-Harvesting Antennae Based on BODIPY-Tethered Cardo Polyfluorenes via Rapid Energy Transferring and Low Concentration Quenching2013

    • Author(s)
      Yeo, H.; Tanaka, K.; Chujo, Y.
    • Journal Title

      Macromolecules

      Volume: 46 Issue: 7 Pages: 2599-2605

    • DOI

      10.1021/ma400015d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Optical Properties of Stable Gallafluorene Derivatives: Investigation of Their Emission via Triplet States2013

    • Author(s)
      Matsumoto, T.; Tanaka, K.; Chujo, Y.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 11 Pages: 4211-4214

    • DOI

      10.1021/ja400287y

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and tuning of optical properties of conjugated polymers involving benzo [h] quinoline-based neutral pentacoordinate organosilicon complexes in the main2013

    • Author(s)
      所雄一郎、呂鉉旭、田中一生、中條善樹
    • Journal Title

      Polymer Chemistry

      Volume: (印刷中) Issue: 20 Pages: 5237-5242

    • DOI

      10.1039/c3py00215b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Light Absorbers Based on Thiophene-Fused Boron Dipyrromethene (BODIPY) Dyes2013

    • Author(s)
      Tanaka, K.; Yamane, H.; Yoshii, R.; Chujo, Y.
    • Journal Title

      Bioorg. Med. Chem.

      Volume: 21 Issue: 10 Pages: 2715-2719

    • DOI

      10.1016/j.bmc.2013.03.050

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Emission Boron Ketoiminates as A New Class of Aggregation-Induced Emission Enhancement Fluorophores2013

    • Author(s)
      R. Yoshii, A. Nagai, K. Tanaka, Y. Chujo
    • Journal Title

      Cheaistry - A European Journal

      Volume: 19 Issue: 14 Pages: 4506-4512

    • DOI

      10.1002/chem.201203703

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly NIR Emissive Di (iso) indomethene BODIPY-Based Polyfluorene : Drastic Change from Deep-Red to NIR Emission via Quantitative Polymer Reaction2013

    • Author(s)
      R. Yoshii, A. Nagai, K. Tanaka, Y. Chujo
    • Journal Title

      Journal of Polyimer Science, Part A : Polymer Chemistry

      Volume: 51 Issue: 8 Pages: 1726-1733

    • DOI

      10.1002/pola.26547

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Highly Transparent Conductive Films with Strong Absorption in Near-Infrared Region Based on Tetrathiafulvalene-Tethered Pendant-Type Polymers2013

    • Author(s)
      Tanaka, K.; Matsumoto, T.; Chujo, Y.
    • Journal Title

      Synth. Met.

      Volume: 163 Issue: 23 Pages: 13-18

    • DOI

      10.1002/pola.23684

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catch and Release with DNA by Imidazolium-Presenting Iron Oxide Nanoparticles via Anion Exchange2013

    • Author(s)
      Tanaka, K.; Narita, A.; Chujo, Y.
    • Journal Title

      Compos. Interface.

      Volume: 20 Issue: 1 Pages: 27-32

    • DOI

      10.1080/15685543.2013.762891

    • NAID

      120005466677

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regulation of Dispersion/Aggregation of Phosphonium-Presenting Iron Oxide Nanoparticles by Anion Exchange2013

    • Author(s)
      Tanaka, K.; Narita, A.; Suzuki, K.; Chujo, Y.
    • Journal Title

      Compos. Interface.

      Volume: 20 Issue: 9 Pages: 557-564

    • DOI

      10.1080/15685543.2012.762862

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] POSS Fillers for Modulating Thermal Properties of Ionic Liquids2013

    • Author(s)
      Jeon, J.-H.; Tanaka, K.; Chujo, Y.
    • Journal Title

      RSC Adv.

      Volume: 3 Issue: 7 Pages: 2422-2427

    • DOI

      10.1039/c2ra22683a

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heat-Initiated Detection for Reduced Glutathione with 19F NMR Probes Based on Modified Gold Nanoparticles2013

    • Author(s)
      Kitamura, N.; Tanaka, K.; Chujo, Y.
    • Journal Title

      Bioorg. Med. Chem. Lett.

      Volume: 23 Issue: 1 Pages: 281-286

    • DOI

      10.1016/j.bmcl.2012.10.105

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機ホウ素錯体を基盤とした元素ブロック高分子2013

    • Author(s)
      田中一生, 中條善樹
    • Journal Title

      高分子、最近の進歩

      Volume: 62 Pages: 143-147

    • NAID

      10031155058

    • Related Report
      2012 Annual Research Report
  • [Presentation] 元素ブロック高分子材料の創出、趣旨説明2013

    • Author(s)
      中條善樹
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学、滋賀
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] 元素ブロック高分子材料の創出2012

    • Author(s)
      中條善樹
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] Development of POSS-based Functional Materials

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      KIPS-ESPCI 2013 Meeting
    • Place of Presentation
      フランス、パリ
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Design of Advanced Materials Based on POSS

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      BIT’s 3rd Annual World Congress of Nano Science & Technology-2013
    • Place of Presentation
      中国、西安
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] POSSネットワークポリマーを基盤とした光駆動型人工酵素の開発

    • Author(s)
      田中一生、ジョン=ジョンファン、中條善樹
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Aggregation-Induced Emission of Organoboron Compounds

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      The 1st International Symposium on Aggregation-Induced Emission
    • Place of Presentation
      中国、武漢
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ナノマテリアルを基盤とした分子プローブ開発と生体情報の定量化

    • Author(s)
      田中一生、中條善樹
    • Organizer
      東京大学化学生命工学専攻講演会
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks] 領域ホームページ

    • URL

      http://element-block.org/

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-11-27   Modified: 2019-07-29  

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