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Development of Difficult Substrate Conversion Reaction toward Carbon Dioxide Utilization

Planned Research

Project AreaPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions
Project/Area Number 15H05796
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

NOZAKI Kyoko  東京大学, 大学院工学系研究科(工学部), 教授 (60222197)

Project Period (FY) 2015-06-29 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥115,830,000 (Direct Cost: ¥89,100,000、Indirect Cost: ¥26,730,000)
Fiscal Year 2019: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2018: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2017: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2016: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2015: ¥52,910,000 (Direct Cost: ¥40,700,000、Indirect Cost: ¥12,210,000)
Keywords合成化学 / 高分子合成 / 有機化学 / 均一系触媒 / 再生可能資源
Outline of Final Research Achievements

We have accomplished three research projects to realize effective use of carbon dioxide: (1) The highest level of catalytic activity was achieved in the formic acid production by hydrogenation of carbon dioxide with organic base. Since formic acid can be purified by distillation, the method opens a new route to its practical use in industry. (2) In the synthesis of aliphatic polycarbonate by the alternating copolymerization of epoxide and carbon dioxide, the highest level of turnover number was accomplished. (3) In our trials to use carbon dioxide in its reaction with C-C and C-O double bonds, we developed a new reaction to afford alpha-hydroxyacids from aldehydes and carbon dioxide.

Academic Significance and Societal Importance of the Research Achievements

二酸化炭素は炭素化合物の燃焼最終生成物であり、熱力学的に安定な、不活性な化合物である。一方で、二酸化炭素は安価で豊富な炭素資源であり、その有効利用は科学的興味に留まらず社会的にも大きなインパクトをもつ。本研究で達成された二酸化炭素の変換反応のうち、ギ酸の合成と脂肪族ポリ炭酸エステルの合成はいずれも世界最高レベルの活性を達成しており、工業的に用いられるレベルに至った。また、α-ヒロキシカルボン酸合成は、医農薬合成中間体の合成法として今後の展開が期待できる。

Report

(6 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (82 results)

All 2020 2019 2018 2017 2016 2015 Other

All Journal Article (28 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 28 results,  Acknowledgement Compliant: 6 results,  Open Access: 1 results) Presentation (49 results) (of which Int'l Joint Research: 31 results,  Invited: 24 results) Remarks (5 results)

  • [Journal Article] Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes2020

    • Author(s)
      Asaba, H.; Iwasaki, T.; Hatazawa, M.; Deng, J.; Nagae, H.; Mashima, K.; Nozaki, K.
    • Journal Title

      Inorg. Chem.

      Volume: in press

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aluminum Porphyrins with Quaternary Ammonium Halides as Catalysts for Copolymerization of Cyclohexene Oxide and CO2: Metal-Ligand Cooperative Catalysis2020

    • Author(s)
      J. Deng, M. Ratanasak, Y. Sako, H. Tokuda, C. Maeda, J. Hasegawa, K. Nozaki, T. Ema
    • Journal Title

      Chem. Sci.

      Volume: in press Issue: 22 Pages: 5669-5675

    • DOI

      10.1039/d0sc01609h

    • NAID

      120006869575

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids2020

    • Author(s)
      K. Masada, S. Kusumoto, K. Nozaki
    • Journal Title

      Org. Lett.

      Volume: in press. Issue: 13 Pages: 4922-4926

    • DOI

      10.1021/acs.orglett.0c00995

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copolymerization of Nonpolar Olefins and Allyl Acetate Using Nickel Catalysts Bearing a Methylene-bridged Bisphosphine Monoxide Ligand2020

    • Author(s)
      J. Jung, H. Yasuda, K. Nozaki
    • Journal Title

      Macromolecules

      Volume: 53 Issue: 7 Pages: 2547-2556

    • DOI

      10.1021/acs.macromol.0c00183

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cleavage of C-C and C-O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes2020

    • Author(s)
      S. Kusumoto, M. Kishino, K. Nozaki
    • Journal Title

      Chemistry Letters

      Volume: 13 Issue: 5 Pages: 1775-1784

    • DOI

      10.1246/cl.200037

    • NAID

      130007840210

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Fluorinated Dialkyl Carbonates from Carbon Dioxide as a Carbonyl Source2020

    • Author(s)
      Sugiyama Masafumi、Akiyama Midori、Nishiyama Kohei、Okazoe Takashi、Nozaki Kyoko
    • Journal Title

      ChemSusChem

      Volume: 13 Issue: 7 Pages: 1775-1784

    • DOI

      10.1002/cssc.202000090

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cyanide‐Free One‐Pot Synthesis of Methacrylic Esters from Acetone2019

    • Author(s)
      Koyama Minoru、Kawakami Takafumi、Okazoe Takashi、Nozaki Kyoko
    • Journal Title

      Chemistry ? A European Journal

      Volume: 25 Issue: 46 Pages: 10913-10917

    • DOI

      10.1002/chem.201901933

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Polyethylene with In‐Chain α,β‐Unsaturated Ketone and Isolated Ketone Units: Pd‐Catalyzed Ring‐Opening Copolymerization of Cyclopropenone with Ethylene2019

    • Author(s)
      Wang Xiaoming、Seidel Falk William、Nozaki Kyoko
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 37 Pages: 12955-12959

    • DOI

      10.1002/anie.201906990

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Polymer-Chain Modification: Ring-Opening and Closing of Polylactone2019

    • Author(s)
      Moon Seunghwan、Masada Koichiro、Nozaki Kyoko
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 28 Pages: 10938-10942

    • DOI

      10.1021/jacs.9b03205

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Synthesis of Primary Anilines from NH 3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface2019

    • Author(s)
      Koizumi Yu、Jin Xiongjie、Yatabe Takafumi、Miyazaki Ray、Hasegawa Jun‐ya、Nozaki Kyoko、Mizuno Noritaka、Yamaguchi Kazuya
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 32 Pages: 10893-10897

    • DOI

      10.1002/anie.201903841

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-Ligand Cooperative C-H Bond Formation by Cyclopentadienone Platinum Complexes2019

    • Author(s)
      Takuya Higashi, Hideaki Ando, Shuhei Kusumoto*, and Kyoko Nozaki*
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 6 Pages: 2247-2250

    • DOI

      10.1021/jacs.8b13829

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Branched-Selective Hydroformylation of Nonactivated Olefins Using an N-Triphos/Rh Catalyst2018

    • Author(s)
      Phanopoulos Andreas、Nozaki Kyoko
    • Journal Title

      ACS Catalysis

      Volume: 8 Issue: 7 Pages: 5799-5809

    • DOI

      10.1021/acscatal.8b00566

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single-Step Construction of the anti-Deoxypropionate Motif from Propylene: Formal Total Synthesis of the Cuticular Hydrocarbons Isolated from Antitrogus parvulus2018

    • Author(s)
      Murayama Toshiki、Nozaki Kyoko
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 35 Pages: 11394-11398

    • DOI

      10.1002/anie.201804711

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Chain-End Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene2018

    • Author(s)
      Wang Xiaoming、Nozaki Kyoko
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 46 Pages: 15635-15640

    • DOI

      10.1021/jacs.8b10335

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts2018

    • Author(s)
      Satoko Takaoka、Aya Eizawa、Shuhei Kusumoto、Kazunari Nakajima、Yoshiaki Nishibayashi、Kyoko Nozaki
    • Journal Title

      Organometallics

      Volume: 37 Issue: 18 Pages: 3001-3009

    • DOI

      10.1021/acs.organomet.8b00377

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydrogenation of Dimethylamine?Borane Catalyzed by Half-Sandwich Ir and Rh Complexes: Mechanism and the Role of Cp* Noninnocence2018

    • Author(s)
      Pal Shrinwantu、Kusumoto Shuhei、Nozaki Kyoko
    • Journal Title

      Organometallics

      Volume: 37 Issue: 6 Pages: 906-914

    • DOI

      10.1021/acs.organomet.7b00889

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Co-Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide2017

    • Author(s)
      Hatazawa Masahiro、Takahashi Rei、Deng Jingyuan、Houjou Hirohiko、Nozaki Kyoko
    • Journal Title

      Macromolecules

      Volume: 50 Issue: 20 Pages: 7895-7900

    • DOI

      10.1021/acs.macromol.7b01130

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cp*Ir-Catalyzed Acceptorless Dehydrogenation of Carbon-Carbon Single Bonds2017

    • Author(s)
      Ando Hideaki、Kusumoto Shuhei、Wu Weiwei、Nozaki Kyoko
    • Journal Title

      Organometallics

      Volume: 36 Issue: 12 Pages: 2317-2322

    • DOI

      10.1021/acs.organomet.7b00245

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg-Al Layered Double Hydroxide Supported Pd Catalyst2017

    • Author(s)
      X. Jin, Y. Koizumi, K. Yamaguchi, K. Nozaki, N. Mizuno
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 39 Pages: 13821-13829

    • DOI

      10.1021/jacs.7b07347

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formal Arylation of NH3 to Produce Diphenylamines over Supported Pd Catalysts2017

    • Author(s)
      Y. Koizumi, K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 78 Pages: 10827-10830

    • DOI

      10.1039/c7cc06737b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization2017

    • Author(s)
      Jin, X.; Taniguchi, K.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 38 Pages: 5267-5270

    • DOI

      10.1039/c7cc01182b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand2017

    • Author(s)
      Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; Nozaki, K.
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 17 Pages: 2630-2633

    • DOI

      10.1039/c7cc00002b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Facile Styrene Formation from Ethylene and a Phenylplatinum(II) Complex Leading to an Observable Platinum(II) Hydride2017

    • Author(s)
      Pal Shrinwantu、Kusumoto Shuhei、Nozaki Kyoko
    • Journal Title

      Organometallics

      Volume: 36 Issue: 3 Pages: 502-505

    • DOI

      10.1021/acs.organomet.6b00892

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold-palladium bimetallic nanoparticles2017

    • Author(s)
      Taniguchi, K.; Jin, X.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    • Journal Title

      Chem. Sci.

      Volume: 8 Issue: 3 Pages: 2131-2142

    • DOI

      10.1039/c6sc04455g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] In Situ Generation of Co^Ⅲ-Salen Complexes for Copolymerization of Propylene Oxide and CO_22016

    • Author(s)
      M. Hatazawa, K. Nakabayashi, S. Ohkoshi and K. Nozaki
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 38 Pages: 13677-13681

    • DOI

      10.1002/chem.201602546

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactions of 2-Methyltetrahydropyran on Silica-Supported Nickel Phosphide in Comparison with 2-Methyltetrahydrofuran2016

    • Author(s)
      Phuong Bui, S. Ted Oyama, Atsushi Takagaki, Brad P. Carrow, Kyoko Nozaki
    • Journal Title

      ACS Catalysis

      Volume: 6 Issue: 7 Pages: 4549-4558

    • DOI

      10.1021/acscatal.6b01033

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of Highly Active Ir­PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases2016

    • Author(s)
      W. Aoki, N. Wattanabinin, S. Kusumoto, K. Nozaki
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 89 Issue: 1 Pages: 113-124

    • DOI

      10.1246/bcsj.20150311

    • NAID

      130005119446

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pyrazole Supported Zinc(II) Benzoates as Catalysts for the Ring Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide2016

    • Author(s)
      M. L. Lephoto, K. Nakano, D. Appavoo, B. O. Owaga, K. Nozaki, J. Darkwa
    • Journal Title

      Catalysts

      Volume: 6 Issue: 1 Pages: 17-17

    • DOI

      10.3390/catal6010017

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Toward Efficient Utilization of Renewable Resources: Ligand Contribution to Late Transition Metal Mediated Reactions2019

    • Author(s)
      Nozaki, K.
    • Organizer
      The 2nd Japan Germany Singapore Trilateral Symposium on Precision Synthesis and Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Cobalt/Lanthanide Multinuclear Complexes for Copolymerization of An Epoxide with Carbon Dioxide2019

    • Author(s)
      浅場 裕貴・岩﨑 孝紀・長江 春樹・真島 和志・野崎 京子
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Homogeneous Catalysis for Today and Tomorrow2019

    • Author(s)
      Nozaki, K.
    • Organizer
      GDCh Science Forum Chemistry (WiFo 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS) of Polymers2019

    • Author(s)
      Nozaki, K.
    • Organizer
      20th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Homogeneous Catalysis for Organic Synthesis and Polymer Synthesis2019

    • Author(s)
      Nozaki, K.
    • Organizer
      47th IUPAC World Chemistry Congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A novel rigid bidentate B/P ligand: Synthesis and Coordination Chemistry2019

    • Author(s)
      Falk William Seidel・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of Macrocyclic Cobalt/Lanthanide Multinuclear Complexes for Copolymerization of An Epoxide with Carbon Dioxide and Study on Its Activity2019

    • Author(s)
      浅場 裕貴・岩崎 孝紀・長江 春樹・真島 和志・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Polymer modification involving structural change of a polymer chain2019

    • Author(s)
      Seunghwan Moon・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Metal-Ligand Cooperative C-H Bond Formation and Cleavage by Cyclopentadienone Platinum Complexes2019

    • Author(s)
      東 拓也・安藤 秀明・楠本 周平・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] A Hybrid of Corannulene and Azacorannulene: Synthesis and Properties of a Highly Curved Nitrogen-Containing Buckybowl2019

    • Author(s)
      時丸 祐輝・伊藤 慎庫・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Copolymerization of ethylene and polar monomers using a cobalt complex with tethered cyclopentadienyl ligand2019

    • Author(s)
      Jin Jung・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Design and Synthesis of Novel Palladium/Phosphine?Sulfonate Catalysts for Highly Stereospecific Polymerization of Propylene2019

    • Author(s)
      富澤 泉・堅固山 千尋・伊藤 慎庫・野崎 京子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of PC(II)P-Ir Complex and Application to Hydrogenation of CO22018

    • Author(s)
      Takaoka, S. Eizawa, A. Kusumoto, S. Nakajima, K. Nishibayashi, Y. Nozaki, K.
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of stereospecific propylene oligomerization toward single-step synthesis of deoxypropionate motif2018

    • Author(s)
      Murayama, T. Ota, Y. Nozaki, K.
    • Organizer
      28th International Conference on Organometallic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Iso-Selective Hydroformylation of Non-Activated Alkenes2018

    • Author(s)
      Phanopoulos, A. Nozaki, K.
    • Organizer
      21st International Symposium on Homogeneous Catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アザペンタベンゾコラニュレンをコアとする液晶性分子の合成と性質2018

    • Author(s)
      永野 太郎・宮島 大吾・伊藤 慎庫・相田 卓三・野崎 京子
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of a Method for Introducing Substituents to Azapentabenzocorannulenes2018

    • Author(s)
      中村 公洋・永野 太郎・時丸 祐輝・伊東 慎庫・野崎 京子
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence2018

    • Author(s)
      Shrinwantu Pal・楠本 周平・野崎 京子
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Bifunctional Aluminum Porphyrin Complexes2018

    • Author(s)
      前田 千尋・徳田 秀樹・依馬 正・Jingyuan Deng・野崎 京子
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PCP-Ir錯体の合成と二酸化炭素水素化反応への応用2017

    • Author(s)
      高岡 咲都子・永澤 彩・楠本 周平・中島 一成・西林 仁昭・野崎 京子
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] アセトン、クロロホルム、アルコールを原料としたメタクリル酸エステルのワンポット合成2017

    • Author(s)
      公山 稔・川上 貴史・岡添 隆・野崎 京子
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] PCP-Ir錯体の合成と二酸化炭素水素化反応への応用2017

    • Author(s)
      高岡 咲都子・永澤 彩・楠本 周平・中島 一成・西林 仁昭・野崎 京子
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ロジウム触媒を用いた縫合反応によるキノイド型縮環オリゴシロールの合成および物性探索2017

    • Author(s)
      津田 知拓・新谷 亮・三澤 奈々・飯野 亮・藤井 幹也・山下 晃一・野崎 京子
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Unsymmterical bidentate ligand for homogeneous catalysis2017

    • Author(s)
      Kyoko Nozaki
    • Organizer
      Symposium des 50 ans du LHFA
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electron Transport of Solid-State Single Molecular Device with Quinoidal Fused Oligosilole Derivative2017

    • Author(s)
      Seung Joo Lee, Shuhei Urayama, Yasuo Azuma, Tomohiro Tsuda, Ryo Takano, Ryo Shintani, Kyoko Nozaki, Yutaka Majima
    • Organizer
      Gwangju Institute of Science and Technology, Gwangju, Korea
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Structure, and Properties of Azapentabenzocorannulenes2017

    • Author(s)
      Shingo Ito, Taro Nagano, Yuki Tokimaru, Kyoko Nozaki
    • Organizer
      17th International Symposium on Novel Aromatics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration2017

    • Author(s)
      Yosuke Sato, Chihiro Takagi, Ryo Shintani, Kyoko Nozaki
    • Organizer
      Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2017

    • Author(s)
      Nozaki, K.
    • Organizer
      U. Montreal Lecture Series
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2017

    • Author(s)
      Nozaki, K.
    • Organizer
      LAVAL University Lecture Series
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2017

    • Author(s)
      Nozaki, K.
    • Organizer
      McGill University Lecture Series
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers2016

    • Author(s)
      Nozaki, K.
    • Organizer
      International Symposium on C-O Activation (ISCO-2016)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      24th Solvay Conference on Chemistry Catalysis in Chemistry and Biology
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalysts toward Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      Merck-Pfister Lecturer in Organic Chemistry MIT
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organic Synthesis of Polymers2016

    • Author(s)
      Nozaki, K.
    • Organizer
      Merck-Pfister Lecturer in Organic Chemistry MIT
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      National Sun Yat-sen University Symposium
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      Mini-Symposium on Organic Synthesis, Organometallics and Elemento-Organic Chemistry
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Utilization of Carbon Dioxide as a Carbon Resource in Bulk Chemicals and in Polymeric Materials2016

    • Author(s)
      Nozaki, K.
    • Organizer
      Carbon Dioxide Catalysis Conference 2016 (ZING Conference)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Catalyst Development for Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      SeleCa Workshop on Precision Polymerization Catalysis
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 二酸化炭素有効利用に向けた触媒開発2016

    • Author(s)
      野崎京子
    • Organizer
      新学術領域研究「精密制御反応場」第1回公開シンポジウム
    • Place of Presentation
      東京工業大学蔵前会館 東京都目黒区 日本
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Development of New Catalysts toward Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      沖縄科学技術大学院大学(OIST)講演会
    • Place of Presentation
      沖縄科学技術大学院大学 恩納村 国頭郡 沖縄県
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO22016

    • Author(s)
      Hatazawa, M.; Nozaki, K.
    • Organizer
      Annual Florida Heterocyclic and Synthetic Conference (FLOHET-2016)
    • Place of Presentation
      University of Florida Gainesvill FL USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of New Catalysts toward Utilization of Renewable Resources2016

    • Author(s)
      Nozaki, K.
    • Organizer
      Challenges in Organic Chemistry
    • Place of Presentation
      Univ. of California Irvine USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] "Development of New Catalytic Reactions toward Utilization of Renewable Resources"2015

    • Author(s)
      Nozaki, K.
    • Organizer
      7th International Conference on Green and Sustainable Chemistry
    • Place of Presentation
      一ツ橋大学 東京都千代田区, 日本
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] "Development of New Catalytic Reactions Toward Utilization of Renewable Resources"2015

    • Author(s)
      Nozaki, K.
    • Organizer
      Gordon Research Conference-New Challenges and Opportunities for Organometallic Chemistry
    • Place of Presentation
      Salve Regina University Newport, RI ,USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Catalytic Reactions toward Utilization of Renewable Resources2015

    • Author(s)
      Nozaki, K.
    • Organizer
      IUPAC-2015
    • Place of Presentation
      Busan Exhibition & Convention Center Busan Korea
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 触媒開発:再生可能資源を利用するために2015

    • Author(s)
      野崎京子
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀 東京都江戸川区 日本
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] In Situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO22015

    • Author(s)
      Hatazawa, M.; Nozaki, K.
    • Organizer
      The 8th International Forum on Chemistry of Functional Organic Chemicals
    • Place of Presentation
      東京大学 東京都文京区 日本
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PPC/PPO selectivity dependency on oxidation state of Co/salcy complex2015

    • Author(s)
      Hatazawa, M.; Nozaki, K.
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイコンベンションセンター ホノルル ハワイ USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon dioxide as a renewable C1 feedstock for polymer synthesis2015

    • Author(s)
      Nozaki, K.
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイコンベンションセンター ホノルル ハワイ USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 東京大学大学院工学系研究科化学生命工学専攻 野崎研究室

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 東京大学工学系研究科化学生命工学専攻 野崎研究室HP

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 野崎研HP

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/publication/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東京大学大学院工学系研究科化学生命工学専攻野崎研究室

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/

    • Related Report
      2015 Annual Research Report

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Published: 2015-07-02   Modified: 2022-11-04  

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