| Budget Amount *help |
¥169,390,000 (Direct Cost: ¥130,300,000、Indirect Cost: ¥39,090,000)
Fiscal Year 2020: ¥21,190,000 (Direct Cost: ¥16,300,000、Indirect Cost: ¥4,890,000)
Fiscal Year 2019: ¥22,100,000 (Direct Cost: ¥17,000,000、Indirect Cost: ¥5,100,000)
Fiscal Year 2018: ¥21,190,000 (Direct Cost: ¥16,300,000、Indirect Cost: ¥4,890,000)
Fiscal Year 2017: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2016: ¥85,410,000 (Direct Cost: ¥65,700,000、Indirect Cost: ¥19,710,000)
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| Outline of Final Research Achievements |
This study has aimed to establish design and synthetic methods for asymmetric coordination spheres in metal complexes, to establish asymmetric induction methods, to stabilize the configuration of chiral centers, and to pioneer asymmetric catalytic reactions and chiral materials. The following research results were obtained and published in international journals.
(1) Asymmetric induction and stabilization of tetrahedral chiral zinc complexes with unsymmetric achiral tridentate ligands, (2) porous supramolecular metal complexes by self-assembly of helical macrocyclic metal complexes: asymmetric molecule adsorption and construction of chiral environment field, and (3) asymmetric induction of enzyme-like metal centers using chiral DNA molecules as templates
In particular, the result of (1) is the first example in the world of asymmetric induction and configuration stabilization of a Werner-type substitution-active chiral-at-metal complex.
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