| Budget Amount *help |
¥38,610,000 (Direct Cost: ¥29,700,000、Indirect Cost: ¥8,910,000)
Fiscal Year 2020: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2019: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2018: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2017: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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| Outline of Final Research Achievements |
This research aims to develop new dynamic metal complex systems that can undergo changes in the "coordination chirality" upon stimulation, by which we can finely control the response speeds and the time profiles of the changes in the dynamic chirality. We have developed various kinds of dynamic helical complex systems, e.g., (1) a series of single helical complex that can control helicity by using lanthanide contraction, (2) single helical complexes that can undergo helicity inversion by fluoride ion with a controllable helicity inversion rate, (3) triple helical complex that can undergo helicity inversion driven by ligand exchange with a controllable reaction rate.
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