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Creation of Asymmetric Coordination Magnetic Compounds

Planned Research

Project AreaCoordination Asymmetry: Design of Asymmetric Coordination Sphere and Anisotropic Assembly for the Creation of Functional Molecules
Project/Area Number 16H06521
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionUniversity of Tsukuba

Principal Investigator

Tokoro Hiroko  筑波大学, 数理物質系, 教授 (50500534)

Project Period (FY) 2016-06-30 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥36,270,000 (Direct Cost: ¥27,900,000、Indirect Cost: ¥8,370,000)
Fiscal Year 2020: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2019: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2018: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2017: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords固体物性 / 磁性 / 相転移 / 磁気特性 / 格子振動 / 物質科学 / 電気特性 / 結晶構造 / 金属錯体 / 電荷移動 / スピン転移
Outline of Final Research Achievements

In this work, we focused on asymmetry from the viewpoint of magnetism among various solid-state properties, and aimed to find the correlation effect and physical properties derived from asymmetry in magnetic coordination compounds.
During this research period, we report various research results, i.e., a development of a superionic conductive ferromagnetic metal complex with a chiral structure, development of a magnetic oxide with second harmonic generation based on asymmetric crystal structure, observation of a terahertz absorption in an asymmetric structure of magnetic metal complex, theoretical prediction of phase transition in an asymmetric structure, observation of the propagation of phase transition accompanied by symmetry breaking, and observation of the correlation effect between unharmonic phonon and long-range magnetic ordering in a molecule-based magnet, etc.

Academic Significance and Societal Importance of the Research Achievements

本研究で報告した、磁性化合物におけるアシンメトリーに由来した様々な相関効果や物性現象は、アシンメトリーとスピンや磁気秩序が種々の固体物性に及ぼす影響を具体的な物性現象として観測したものであり、固体科学分野における物性開発の研究に大きく貢献するものである。

Report

(6 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (117 results)

All 2021 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (15 results) Journal Article (22 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 22 results,  Open Access: 11 results,  Acknowledgement Compliant: 1 results) Presentation (65 results) (of which Int'l Joint Research: 15 results,  Invited: 13 results) Book (3 results) Remarks (12 results)

  • [Int'l Joint Research] レンヌ大学(フランス)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] ヤゲロニア大学(ポーランド)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] イリノイ大学/アメリカ国立標準技術研究所(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] レンヌ大学(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ヤゲロニア大学/ポーランド科学アカデミー(ポーランド)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] アメリカ国立標準技術研究所/イリノイ大学(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] レンヌ大学/グルノーブル大学(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ヤゲロニア大学/The Szewalski Institute(ポーランド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] バレンシア大学(スペイン)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] レンヌ大学/グルノーブル大学/パリ大学(第6)(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] バレンシア大学(スペイン)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ヤゲロニア大学(ポーランド)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ベルサイユ大学/グルノーブル大学/ボルドー大学(フランス)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] バレンシア大学(スペイン)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ヤゲロニア大学(ポーランド)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Strain wave pathway to semiconductor-to-metal transition revealed by time-resolved X-ray powder diffraction2021

    • Author(s)
      C. Mariette, M. Lorenc, et al., H. Tokoro, V. Esposito, Y. Deng, G. Ingold, M. Chergui, G. F. Mancini, R. Mankowsky, C. Svetina, S. Zerdane, A. Mozzanica, A. Bosak, M. Wulff, M. Levantino, H. Lemke, M. Cammarata
    • Journal Title

      Nature. Commun.

      Volume: 12 Issue: 1 Pages: 1239-1239

    • DOI

      10.1038/s41467-021-21316-y

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Advances in magnetic films of epsilon-iron oxide toward next-generation high-density recording media2021

    • Author(s)
      H. Tokoro, A. Namai, S. Ohkoshi
    • Journal Title

      Dalton Trans.

      Volume: 50 Issue: 2 Pages: 452-459

    • DOI

      10.1039/d0dt03460f

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic-Pole Flip by Millimeter Wave2020

    • Author(s)
      Shin-ichi Ohkoshi, Marie Yoshikiyo, Kenta Imoto, Kosuke Nakagawa, Asuka Namai, Hiroko Tokoro, Yuji Yahagi, Kyohei Takeuchi, Fangda Jia, Seiji Miyashita, Makoto Nakajima, Hongsong Qiu, Kosaku Kato, Takehiro Yamaoka, Masashi Shirata, Kenji Naoi, Koichi Yagishita, and Hiroaki Doshita
    • Journal Title

      Adv. Mater.

      Volume: 32 Issue: 48 Pages: 2004897-2004897

    • DOI

      10.1002/adma.202004897

    • NAID

      120007180694

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Landau Theory for Non-Symmetry-Breaking Electronic Instability Coupled to Symmetry-Breaking Applied to Prussian Blue Analogue2020

    • Author(s)
      G. Azzolina, R. Bertoni, C. Ecolivet, H. Tokoro, S. Ohkoshi, E. Collet
    • Journal Title

      Phys. Rev. B

      Volume: 102, 134104 Issue: 13 Pages: 1-13

    • DOI

      10.1103/physrevb.102.134104

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sigmoidally hydrochromic molecular porous crystal with rotatable dendrons2020

    • Author(s)
      Yamagishi Hiroshi、Nakajima Sae、Yoo Jooyoung、Okazaki Masato、Takeda Youhei、Minakata Satoshi、Albrecht Ken、Yamamoto Kimihisa、Bad?a-Dom?nguez Irene、Oliva Maria Moreno、Delgado M. Carmen Ruiz、Ikemoto Yuka、Sato Hiroyasu、Imoto Kenta、Nakagawa Kosuke、Tokoro Hiroko、Ohkoshi Shin-ichi、Yamamoto Yohei
    • Journal Title

      Communications Chemistry

      Volume: 3 Issue: 1 Pages: 1-8

    • DOI

      10.1038/s42004-020-00364-3

    • NAID

      120007161329

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Crystal growth control of rod-shaped ε-Fe2O3 nanocrystals2020

    • Author(s)
      H. Tokoro, J. Fukui, K. Watanabe, M. Yoshikiyo, A. Namai, S. Ohkoshi
    • Journal Title

      RSC Adv.

      Volume: 10 Issue: 65 Pages: 39611-39616

    • DOI

      10.1039/d0ra07256g

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of λ-Ti3O5 nanocrystals using a block copolymer2020

    • Author(s)
      Y. Araki, S. Ohkoshi, H. Tokoro
    • Journal Title

      Mater. Today Energy

      Volume: 18, 100525 Pages: 1-6

    • DOI

      10.1016/j.renene.2021.01.144

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of nanosize tetratitanium heptoxide and its anomalous phase transition2020

    • Author(s)
      H. Tokoro, Y. Araki, I. Nagata, T. Kondo, K. Imoto, S. Ohkoshi
    • Journal Title

      Mater. Res. Lett.

      Volume: 8 Issue: 7 Pages: 261-267

    • DOI

      10.1080/21663831.2020.1743788

    • NAID

      120007132920

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A photoswitchable polar crystal that exhibits superionic conduction2020

    • Author(s)
      S. Ohkoshi, K. Nakagawa, K. Imoto, H. Tokoro, Y. Shibata, K. Okamoto, Y. Miyamoto, M. Komine, M. Yoshikiyo, A. Namai
    • Journal Title

      Nature Chem.

      Volume: 12 Issue: 4 Pages: 338-344

    • DOI

      10.1038/s41557-020-0427-2

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Functional phase bistability in a nanocrystalline RbMn[Fe(CN)6] thin film fabricated by matrix-assisted laser evaporation2020

    • Author(s)
      D. Maskowicz, M. Sawczak, R. Jendrzejewski, M. Gazda, H. Tokoro, S. Ohkoshi, Y. Garcia, G. Sliwinski
    • Journal Title

      Scr. Mater.

      Volume: 183 Pages: 50-54

    • DOI

      10.1016/j.scriptamat.2020.03.019

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Low-pressure-responsive heatstorage ceramics for automobiles2019

    • Author(s)
      S. Ohkoshi, H. Tokoro, K. Nakagawa, M. Yoshikiyo, F. Jia, A. Namai
    • Journal Title

      Scientific Rep.

      Volume: 9 Issue: 1 Pages: 13203-13203

    • DOI

      10.1038/s41598-019-49690-0

    • NAID

      120007127901

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 固体-固体相転移を利用した蓄熱セラミックスの開発2019

    • Author(s)
      大越慎一、生井飛鳥、所裕子
    • Journal Title

      化学工学会誌 特集:蓄熱技術の最前線と社会実装への挑戦

      Volume: 83 Pages: 506-509

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single laser shot photoinduced phase transition of rubidium manganese hexacyanoferrate investigated by X-ray diffractio2019

    • Author(s)
      G. Azzolina, E. Collet, C. Mariette, M. Cammarata, E. Trzop, M. Sander, M. Levantino, K. Nakagawa, H. Tokoro, S. Ohkoshi, R. Bertoni
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: - Issue: 27 Pages: 3142-3147

    • DOI

      10.1002/ejic.201801478

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Humidity sensitivity, organic molecule sensitivity, and superionic conductivity on porous magnets based on cyano-bridged bimetal assemblies2019

    • Author(s)
      S. Ohkoshi, A. Namai, H. Tokoro
    • Journal Title

      Coord. Chem. Rev.

      Volume: 380 Pages: 572-583

    • DOI

      10.1016/j.ccr.2018.10.004

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical prediction of a charge-transfer phase transition2018

    • Author(s)
      H. Tokoro, A. Namai, M. Yoshikiyo, R. Fujiwara, K. Chiba, S. Ohkoshi
    • Journal Title

      Sci. Rep.

      Volume: 8 Issue: 1 Pages: 46-52

    • DOI

      10.1038/s41598-017-18213-0

    • NAID

      120007134506

    • Related Report
      2020 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct Observation of Chemical Conversion from Fe3O4 to ε-Fe2O3 by a Nanosize Wet Process2018

    • Author(s)
      H. Tokoro, W. Tarora, A. Namai, M. Yoshikiyo, S. Ohkoshi
    • Journal Title

      Chem. Mater.

      Volume: 30 Issue: 9 Pages: 2888-2894

    • DOI

      10.1021/acs.chemmater.7b03708

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Probing Transient Photoinduced Charge Transfer in Prussian Blue Analogues with Time-Resolved XANES and Optical Spectroscopy2018

    • Author(s)
      S. Zerdane, M. Cammarata, L. Balducci, R. Bertoni, L. Catala, S. Mazerat, T. Mallah, M. N. Pedersen, M. Wulff, K. Nakagawa, H. Tokoro, S. Ohkoshi, E. Collet
    • Journal Title

      Eur. J. Inorg. Chem.,

      Volume: 3-4 Issue: 3-4 Pages: 272-277

    • DOI

      10.1002/ejic.201700657

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A novel oxalate-based three-dimensional coordination polymer showing magnetic ordering and high proton conductivity2017

    • Author(s)
      M. Mon, J. Vallejo, J. Pasán, O. Fabelo, C. Train, M. Verdaguer, S. Ohkoshi, H. Tokoro, K. Nakagawa, E. Pardo
    • Journal Title

      Dalton Trans.

      Volume: 46 Issue: 43 Pages: 15130-15137

    • DOI

      10.1039/c7dt03415f

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Cesium ion detection by terahertz light2017

    • Author(s)
      S. Ohkoshi, M. Yoshikiyo, A. Namai, K. Nakagawa, K. Chiba, R. Fujiwara, H. Tokoro
    • Journal Title

      Sci. Rep.

      Volume: 7 Issue: 1 Pages: 8088-8088

    • DOI

      10.1038/s41598-017-08551-4

    • NAID

      120007134879

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dielectric and optical constants of λ-Ti3O5 film measured by spectroscopic ellipsometry2017

    • Author(s)
      F. Hakoe, H. Tokoro, S. Ohkoshi
    • Journal Title

      Mater. Lett.

      Volume: 188 Pages: 8-12

    • DOI

      10.1016/j.matlet.2016.09.084

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Large optical third-order nonlinearities in a switchable Prussian blue analogue2017

    • Author(s)
      A. Ould-Hamouda, A. Iazzolino, H. Tokoro, S. Ohkoshi, E. Freysz
    • Journal Title

      Opt. Mater. Express

      Volume: 7 Issue: 2 Pages: 444-453

    • DOI

      10.1364/ome.7.000444

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Electronic structure and correlation in β-Ti3O5 and λ-Ti3O5 studied by Hard X-ray Photoelectron Spectroscopy2017

    • Author(s)
      K. Kobayashi, M. Taguchi, M. Kobata, K. Tanaka, H. Tokoro, H. Daimon, T. Okane, H. Yamagami, E. Ikenaga, S. Ohkoshi
    • Journal Title

      Phys. Rev. B

      Volume: 95 Issue: 8

    • DOI

      10.1103/physrevb.95.085133

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] FeCrCr系ヘキサシアノ金属錯体薄膜における表面磁化状態の観察2021

    • Author(s)
      矢作祐士, 中川幸祐, 大越慎一, 所裕子
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ロッド型イプシロン酸化鉄ナノクリスタルの異方的結晶成長2021

    • Author(s)
      渡辺浩気, 福井純平, 大越慎一, 所裕子
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] NiW系オクタシアノ金属錯体の結晶構造と磁気特性2021

    • Author(s)
      赤木慎太郎、Junhao Wang、井元健太、大越慎一、所裕子
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 鉄クロム系ヘキサシアノ磁性錯体薄膜における磁気状態の表面観察2021

    • Author(s)
      長島俊太郎、矢作祐士、中川幸祐、大越慎一、所裕子
    • Organizer
      日本化学会 第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] シアノ系金属錯体を利用した酸化鉄型複合磁性材料の合成2021

    • Author(s)
      田中万由子、大越慎一、所裕子
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 相転移特性にもとづく新機能物性の開拓2021

    • Author(s)
      所裕子
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 鉄クロム磁性錯体薄膜材料における磁気特性の評価および表面観察2020

    • Author(s)
      矢作 祐士, 大越 慎一, 所 裕子
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] CrCr系およびFeCrCr系ヘキサシアノ金属錯体薄膜の表面観察と磁気特性2020

    • Author(s)
      矢作祐士, 大越慎一, 所裕子
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] ロッド型イプシロン酸化鉄の合成における形状およびサイズ制御2020

    • Author(s)
      渡辺浩気, 福井純平, 大越慎一, 所裕子
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] イプシロン型酸化鉄磁性材料の異方的結晶成長2020

    • Author(s)
      渡辺浩気, 福井純平, 大越慎一, 所裕子
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 酸化鉄をベースとした複合磁性材料の合成と磁気特性2020

    • Author(s)
      田中万由子、大越慎一、所裕子
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 金属錯体を利用した酸化鉄複合材料の合成2020

    • Author(s)
      田中万由子、大越慎一、所裕子
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] Development of pressure-sensitive heat storage materials using a bistable property2020

    • Author(s)
      Hiroko Tokoro
    • Organizer
      The 6th Southeast Asia Collaborative Symposium on Energy Materials (SACSEM 6th)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ti4O7ナノ粒子における金属-半導体転移2020

    • Author(s)
      荒木優介, 永田伊織, 大越慎一, 所裕子
    • Organizer
      日本物理学会 第75回年次大会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] タングステン系オクタシアノ磁性金属錯体における熱膨張特性2020

    • Author(s)
      前田直孝, 井元健太, 大越慎一, 所裕子
    • Organizer
      日本物理学会 第75回年次大会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 鉄クロム系ヘキサシアノ錯体磁性薄膜における表面形状と磁気特性2020

    • Author(s)
      矢作祐士、大越慎一、所裕子
    • Organizer
      日本物理学会 第75回年次大会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゾルゲル法をもちいたロッド型イプシロン酸化鉄ナノ微粒子の形状制御と磁気特性2020

    • Author(s)
      渡辺浩気、福井純平、大越慎一、所裕子
    • Organizer
      日本物理学会 第75回年次大会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Magnetic properties of octacyano M-W (M = Ni or Zn) bimetal assemblies2020

    • Author(s)
      C. Viravaux, N. Maeda, K. Imoto, S. Ohkoshi, H. Tokoro
    • Organizer
      日本化学会 第100春季年会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Study of surface morphology and magnetic properties on magnetic thin films of iron chromate hexacyanochromate2020

    • Author(s)
      矢作祐士、大越慎一、所裕子
    • Organizer
      日本化学会 第100春季年会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Sintering temperature effect on synthesis of rod-type ε-Fe2O3 by sol-gel method2020

    • Author(s)
      K. Watanabe, J. Fukui, S. Ohkoshi, H. Tokoro
    • Organizer
      日本化学会 第100春季年会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Photoluminescent property on gadolinium-chromium cyano- bridged bimetal assemblies2020

    • Author(s)
      村上周平、王駿豪、大越慎一、所裕子
    • Organizer
      日本化学会 第100春季年会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation of composite magnetic material based on iron oxide magnet2020

    • Author(s)
      M. Tanaka, S. Ohkoshi, H. Tokoro
    • Organizer
      日本化学会 第100春季年会(2020)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Phonon mode study for manganese hexacyanoferrate Prussian blue analog2019

    • Author(s)
      H. Tokoro
    • Organizer
      IUPAC PARIS 2019 (47th IUPAC CHEMISTRY CONGRESS)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Theoretical Study for Charge‐transfer‐induced Phase Transition on Bistable Cyanide‐bridged Coordination Polymer2019

    • Author(s)
      H. Tokoro
    • Organizer
      Phase Transition and Dynamical Properties of Spin Transition Materials (PDSTM 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] フォノンモード計算を用いた電荷移動型相転移錯体の設計開発2019

    • Author(s)
      所裕子
    • Organizer
      第4回 固体化学フォーラム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 熱特性を利用した未来型機能性材料の開発2019

    • Author(s)
      所裕子
    • Organizer
      野口遵研究助成金10周年記念講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 双安定性物質における熱機能性2019

    • Author(s)
      所裕子
    • Organizer
      関東光科学若手研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Control of metal-semiconductor phase transition in tetratitanium heptoxide2019

    • Author(s)
      Y. Araki, I. Nagata, S. Ohkoshi, H. Tokoro
    • Organizer
      IUPAC PARIS 2019 (47th IUPAC CHEMISTRY CONGRESS)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Far-infrared spectroscopy in manganese hexacyanoferrate coordination polymer2019

    • Author(s)
      N. Maeda, R. Fujiwara, S. Ohkoshi, H. Tokoro
    • Organizer
      IUPAC PARIS 2019 (47th IUPAC CHEMISTRY CONGRESS)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface observation of magnetic thin films of iron chromate hexacyanochromate2019

    • Author(s)
      Y. Yahagi, S. Ohkosi, H. Tokoro
    • Organizer
      IUPAC PARIS 2019 (47th IUPAC CHEMISTRY CONGRESS)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of rod-type nanoparticle of epsilon-iron oxide by sol-gel method using block copolymer2019

    • Author(s)
      K. Watanabe,Y. Araki , S. Ohkoshi and H. Tokoro
    • Organizer
      IUPAC PARIS 2019 (47th IUPAC CHEMISTRY CONGRESS)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ブロックコポリマーを用いたラムダ型五酸化三チタンの合成2019

    • Author(s)
      荒木優介、大越慎一、所裕子
    • Organizer
      第9回CSJ化学フェスタ
    • Related Report
      2019 Annual Research Report
  • [Presentation] MnFe系ヘキサシアノ金属錯体の遠赤外分光スペクトル2019

    • Author(s)
      前田直孝、藤原礼衣、梅田喜一、松永拓也、宮本靖人、大越慎一、所裕子
    • Organizer
      第9回CSJ化学フェスタ
    • Related Report
      2019 Annual Research Report
  • [Presentation] 鉄クロム磁性錯体薄膜材料における表面観察および磁気特性の評価2019

    • Author(s)
      矢作祐士、大越慎一、所裕子
    • Organizer
      第9回CSJ化学フェスタ
    • Related Report
      2019 Annual Research Report
  • [Presentation] ブロックコポリマーを用いたイプシロン型酸化鉄磁性体の合成2019

    • Author(s)
      渡辺 浩気、荒木 優介、塚本 聖哉、大越 慎一、所 裕子
    • Organizer
      第9回CSJ化学フェスタ
    • Related Report
      2019 Annual Research Report
  • [Presentation] ありふれた元素からなる機能性物質2019

    • Author(s)
      所裕子
    • Organizer
      国際周期表年2019記念シンポジウム -周期表が拓く科学と技術 国際周期表年を迎えて-
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ゾルゲル法によるブロックコポリマーを用いたイプシロン酸化鉄の合成2019

    • Author(s)
      渡辺浩気,荒木優介,塚本聖哉,所裕子,大越慎一
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] FeCrCr系ヘキサシアノ金属錯体薄膜における磁気特性2019

    • Author(s)
      矢作祐士,池田侑典,大越慎一,所裕子
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] CsMnFe プルシアンブルー類似体におけるフォノンモード観測2019

    • Author(s)
      前田直孝, 藤原礼衣, 大越慎一, 所裕子
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 七酸化四チタン金属酸化物の粒子サイズと相転移物性の関係2019

    • Author(s)
      荒木優介, 永田伊織, 大越慎一, 所裕子
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Phonon mode study of charge-transfer phase transition material of manganese hexacyanoferrate2018

    • Author(s)
      H. Tokoro
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of advanced functional materials by using bistability2018

    • Author(s)
      H. Tokoro
    • Organizer
      The 2nd International Symposium on Coordination Asymmetry
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Thermal functionality on bistable material2018

    • Author(s)
      H. Tokoro
    • Organizer
      The 50th Reimei workshop, Universal Physics in Many-Body Quantum Systems -- From Atoms to Quarks --
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermal Functionality on Phase Transition Material2018

    • Author(s)
      H. Tokoro
    • Organizer
      The 8th TOYOTA RIKEN International Workshop on Organic semiconductors, conductors, and electronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Far-infrared spectroscopy in cesium manganese hexacyanoferrate2018

    • Author(s)
      N. Maeda, R. Fujiwara, S. Ohkoshi, H. Tokoro
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relationship between particle size and phase transition properties on Ti4O72018

    • Author(s)
      Y. Araki, I. Nagata, S. Ohkoshi and H.Tokoro,
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of ε-Fe2O3 by sol-gel method2018

    • Author(s)
      Koki Watanabe, Yusuke Araki, Seiya Tsukamoto, Shin-ichi Ohkoshi, Hiroko Tokoro,
    • Organizer
      Interdisciplinary Workshop on Science and Patents 2018,
    • Related Report
      2018 Annual Research Report
  • [Presentation] Effect of magnetic ordering in crystal structure of manganese hexacyanochromate magnet2018

    • Author(s)
      N. Maeda, T. Matsunaga, K. Nakagawa, Y. Miyamoto, S. Ohkoshi, H. Tokoro
    • Organizer
      Interdisciplinary Workshop on Science and Patents 2018,
    • Related Report
      2018 Annual Research Report
  • [Presentation] New synthesis process of lambda-Ti3O5 by using block copolymers2018

    • Author(s)
      Y. Araki, S. Ohkoshi and H.Tokoro,
    • Organizer
      Interdisciplinary Workshop on Science and Patents 2018,
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of lambda-Ti3O5 by using block copolymers2018

    • Author(s)
      Y. Araki, S. Ohkoshi and H.Tokoro,
    • Organizer
      Tsukuba Grobal Science Week 2018 Student Poster Presentation on Materials Research
    • Related Report
      2018 Annual Research Report
  • [Presentation] Temperature dependence of crystal structure of manganese hexacyanochromate magnet2018

    • Author(s)
      N. Maeda, T. Matsunaga, K. Nakagawa, Y. Miyamoto, S. Ohkoshi, H. Tokoro
    • Organizer
      Tsukuba Grobal Science Week 2018 Student Poster Presentation on Materials Research
    • Related Report
      2018 Annual Research Report
  • [Presentation] Cr系ヘキサシアノ磁性錯体における結晶構造の温度依存性2018

    • Author(s)
      前田直孝, 松永拓也, 中川幸佑, 宮本靖人, 大越慎一, 所裕子
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 七酸化四チタンにおける形状と双安定性特性の関係2018

    • Author(s)
      荒木優介, 永田伊織, 奈須義総, 大越慎一, 所裕子
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 七酸化四チタン金属酸化物のナノ微粒子合成2018

    • Author(s)
      大代紘己, 永田伊織, 奈須義総, 大越慎一, 所裕子
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] CsMnFe(CN)6プルシアンブルー類似体におけるフォノンモードの観測2018

    • Author(s)
      藤原 礼衣, 梅田 喜一, 大越 慎一, 所 裕子,
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] 双安定性を示すマンガン鉄ヘキサシアノ相転移錯体におけるフォノンモード計算2017

    • Author(s)
      所裕子
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Relationship between particle size and phase transition properties2017

    • Author(s)
      I. Nagata, T. Nasu, S. Ohkoshi, H. Tokoro
    • Organizer
      Interdisciplinary Workshop on Science and Patents 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Far-IR spectroscopy in Mn-Fe hexacyanide bimetal assembly2017

    • Author(s)
      R. Fujiwara, Y. Umeta, T. Matsunaga, Y. Miyamoto, S. Ohkoshi, H. Tokoro
    • Organizer
      Interdisciplinary Workshop on Science and Patent 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ゾルゲル法を用いたロッド型イプシロン酸化鉄の合成2017

    • Author(s)
      福井純平・太郎良和香・大越慎一・所裕子
    • Organizer
      第7回化学フェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] MnFe系ヘキサシアノ金属錯体における遠赤外分光2017

    • Author(s)
      藤原 礼衣, 梅田 喜一, 松永 拓也, 宮本 靖人, 大越 慎一, 所 裕子
    • Organizer
      第7回化学フェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] RbMnFeヘキサシアノ錯体における負熱膨張特性2016

    • Author(s)
      所裕子, 大越慎一
    • Organizer
      第26回 日本MRS年次大会
    • Place of Presentation
      横浜 マツ・ムラ ホール (神奈川県横浜市)
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] 七酸化四チタンの相転移物性に形状制御が及ぼす影響2016

    • Author(s)
      永田伊織, 奈須義総, 大越慎一, 所裕子
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学 角間キャンパス (石川県金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] MnFe系ヘキサシアノ相転移金属錯体におけるフォノンモードの観測2016

    • Author(s)
      藤原礼衣, 梅田喜一, 松永拓也, 宮本靖人, 大越慎一, 所裕子
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学 角間キャンパス (石川県金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Optical-switching of second harmonic light in chiral photomagnet2016

    • Author(s)
      所 裕子
    • Organizer
      第40回 日本磁気学会学術講演会
    • Place of Presentation
      金沢大学 角間キャンパス (石川県金沢市)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Synthesis of rod-type ε-Fe2O3 by sol-gel method2016

    • Author(s)
      Jumpei Fukui, Shin-ichi Ohkoshi, Hiroko Tokoro
    • Organizer
      Interdisciplinary Workshop on Science and Patents (IWP) 2016
    • Place of Presentation
      筑波大学 大学会館 (茨城県つくば市)
    • Year and Date
      2016-09-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] CSJカレントビュー 有機・無機材料の相転移ダイナミクス2020

    • Author(s)
      日本化学会 編 (分担執筆 所裕子、大越慎一)
    • Total Pages
      212
    • Publisher
      化学同人
    • ISBN
      9784759813951
    • Related Report
      2020 Annual Research Report
  • [Book] CSJ35有機・無機材料の相転移ダイナミクス2020

    • Author(s)
      所裕子、大越慎一(分担執筆)
    • Total Pages
      212
    • Publisher
      化学同人
    • ISBN
      9784759813951
    • Related Report
      2019 Annual Research Report
  • [Book] フォノンエンジニアリング -マイクロ・ナノスケールの次世代熱制御技術-, 第3章 第5節 : 長期的に熱エネルギー保存できる蓄熱セラミックス2017

    • Author(s)
      分担執筆: 大越慎一、所裕子
    • Total Pages
      10
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2017 Annual Research Report
  • [Remarks] 先端機能性物質研究室

    • URL

      https://www.ims.tsukuba.ac.jp/~tokoro_lab/index.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] ミリ波・テラヘルツ波を用いた新しい磁気記録方式が登場 !!

    • URL

      https://www.tsukuba.ac.jp/journal/technology-materials/20201008143611.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 光による"ひずみ波"の伝搬で固体相転移が進行することを発見

    • URL

      https://www.tsukuba.ac.jp/journal/technology-materials/20210224140000.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 先端機能性物質研究室

    • URL

      http://www.ims.tsukuba.ac.jp/~tokoro_lab/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 筑波大学数理物質科学研究科 人と研究

    • URL

      http://www.pas.tsukuba.ac.jp/category/people/

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] 世界初!光スイッチング効果を示す超イオン伝導体を発見

    • URL

      http://www.tsukuba.ac.jp/attention-research/p202003170100.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 日本物理学会 第1回米沢富美子記念賞

    • URL

      http://www.tsukuba.ac.jp/update/awards/20200331094714.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 先端機能性物質研究室

    • URL

      http://www.ims.tsukuba.ac.jp/~tokoro/

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 筑波大学 野口遵賞

    • URL

      http://www.tsukuba.ac.jp/update/awards/20180316140601.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 筑波大学大学院数理物質科学研究科 人と研究

    • URL

      http://www.pas.tsukuba.ac.jp/category/people/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 筑波大学 2016 BEST FACULTY MEMBER 表彰式

    • URL

      http://www.tsukuba.ac.jp/event/e201701261200.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 筑波大学 ドイツ・イノベーション・アワード ゴットフリード・ワグネル賞 2016

    • URL

      http://www.tsukuba.ac.jp/update/awards/20160711093119.html

    • Related Report
      2016 Annual Research Report

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Published: 2016-07-04   Modified: 2022-01-27  

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