| Budget Amount *help |
¥61,620,000 (Direct Cost: ¥47,400,000、Indirect Cost: ¥14,220,000)
Fiscal Year 2020: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2019: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2018: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2017: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2016: ¥21,840,000 (Direct Cost: ¥16,800,000、Indirect Cost: ¥5,040,000)
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| Outline of Final Research Achievements |
In contrast to the symmetric electron transfer between homo-redox sites, asymmetric electron transfer between hetero-redox sites associates large entropy change as well as significant physical property changes. This project aimed at creation of electronic asymmetry units exhibiting directional electron transfers induced by heat, light, and chemical stimuli. In addition, low-dimensional aggregates through hydrogen bonding interactions were synthesized to explore specific physical properties based on the low-dimensional electronic systems. As a result, versatile strategy to obtain directional electron transfer systems has been established. In addition, new physical properties such as symmetry breaking phase transitions have been achieved, which were originating from the directional and cooperative electron/proton transfers.
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