• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of luminescence properties by the manipulation of interface in Soft Crystals

Planned Research

Project AreaSoft Crystals: Science and Photofunctions of Easy-Responsive Systems with Felxibility and Higher-Ordering
Project/Area Number 17H06374
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionAoyama Gakuin University

Principal Investigator

Hasegawa Miki  青山学院大学, 理工学部, 教授 (70306497)

Co-Investigator(Kenkyū-buntansha) 山中 正道  明治薬科大学, 薬学部, 教授 (10377715)
徐 超男  国立研究開発法人産業技術総合研究所, エレクトロニクス・製造領域, 総括研究主幹 (70235810)
Project Period (FY) 2017-06-30 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥84,110,000 (Direct Cost: ¥64,700,000、Indirect Cost: ¥19,410,000)
Fiscal Year 2021: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2020: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2019: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2018: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2017: ¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Keywords希土類錯体 / 界面・薄膜 / 発光機能 / ソフトクリスタル / 構造 / 光化学 / 発光 / 構造解析 / 界面錯形成 / 希土類 / 界面 / 複合体 / 薄膜
Outline of Final Research Achievements

The study aims to develop the photo-function of soft crystals with molecular interface specificity. In particular, the molecular association by the wet-film formation process exhibits linearly polarized luminescence. It was expected that the transition dipole transition of the ligand by photoexcitation as the energy donor was related to the polarized luminescence of the acceptor, lanthanide ion. The result which proved this experimentally was obtained.
The synthesis of a series of helical rare earth complexes in a unit of soft crystal and the system which explains the relation between the luminescence phenomenon and the distortion of the ligand field were found. For example, a chiral rare earth complex was synthesized and its structure was analyzed, and circularly polarized luminescence and its enhancement in aggregation were clarified.
These results have reported widely in international journals as articles, reviews and books.

Academic Significance and Societal Importance of the Research Achievements

希土類錯体の発光は光励起によるエネルギー移動を経由している。例えば、ソフトクリスタルとして分子薄膜を累積した系は、配位子そのものの遷移双極子モーメントが効率よく金属イオンに転写されることを見出した。このような系は溶液や粉末では相殺されて現れない現象で、学術的に新しい解釈を実験的に示すことができた。
このような、分子レベルの層構造が結晶としてソフトクリスタル現象を示す場合の、原理解明や制御ができれば、新素材へのコンセプト提供となりうる。

Report

(6 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (113 results)

All 2022 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (4 results) Journal Article (37 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 36 results,  Open Access: 23 results) Presentation (63 results) (of which Int'l Joint Research: 32 results,  Invited: 27 results) Book (1 results) Remarks (5 results) Patent(Industrial Property Rights) (1 results) Funded Workshop (2 results)

  • [Int'l Joint Research] Technical University of Vienna(オーストリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Strasbourg University/CNRS(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Technical Institute of Vienna(オーストリア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Strasbourg University(フランス)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Luminescence of lanthanide complexes: From fundamental to prospective approaches related to water- and molecular-stimuli2022

    • Author(s)
      Hasegawa Miki、Ohmagari Hitomi、Tanaka Hideyuki、Machida Kanade
    • Journal Title

      Journal of Photochemistry and Photobiology C: Photochemistry Reviews

      Volume: 50 Pages: 100484-100484

    • DOI

      10.1016/j.jphotochemrev.2022.100484

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hidden Heterometallic Interaction Emerges from Resonant Inelastic X-ray Scattering in Luminescent Tb-Pt Molecules2022

    • Author(s)
      Yoshida, Takefumi; Shabana, Ahmed; Izuogu, David; Fuku, Kentaro; Sato, Tetsu; Zhang, Haitao ; Yamamoto, Yukina; Kamata, Jun; Ohmagari, Hitomi ; Hasegawa, Miki; Cosquer, Goulven; Takaishi, Shinya; Kaneko, Takuma; Uruga, Tomoya; Iwasawa, Yasuhiro; Yamashita, Masahiro
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: xxx

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Asymmetric Lumino-Transformer: Circularly Polarized Luminescence of Chiral Eu(III) Coordination Polymer with Phase Transition Behavior2022

    • Author(s)
      Tsurui, Makoto; Kitagawa, Yuichi; Shoji, Sunao; Ohmagari, Hitomi ; Hasegawa, Miki; Gon, Masayuki; Tanaka, Kazuo; Kobayashi, Masato; Taketsugu, Tetsuya; Fushimi, Koji; Hasegawa, Yasuchika
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: xxx

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Rare Earth-containing Langmuir-Blodgett Films and their Application as a Sensing Film for Taste Sensor2021

    • Author(s)
      HASEGAWA Yuki、HASEGAWA Miki
    • Journal Title

      Vacuum and Surface Science

      Volume: 64 Issue: 4 Pages: 168-173

    • DOI

      10.1380/vss.64.168

    • NAID

      130008023849

    • ISSN
      2433-5835, 2433-5843
    • Year and Date
      2021-04-10
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Computational Studies for Crystal Structures of Helicate Lanthanide Complexes Based on X-ray Analyses2021

    • Author(s)
      Nakayama Naofumi、Hijikata Masahiro、Ohmagari Hitomi、Tanaka Hideyuki、Inazuka Yudai、Saito Daisuke、Obata Shigeaki、Ohta Kazuo、Kato Masako、Goto Hitoshi、Hasegawa Miki
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 12 Pages: 2973-2981

    • DOI

      10.1246/bcsj.20210339

    • NAID

      130008144728

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Electrofluorochromic Device Based on a Redox-Active Europium(III) Complex2020

    • Author(s)
      Kim Yuna、Ohmagari Hitomi、Saso Akira、Tamaoki Nobuyuki、Hasegawa Miki
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 12 Issue: 41 Pages: 46390-46396

    • DOI

      10.1021/acsami.0c13765

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thin-film formation for promoting the potential of luminescent lanthanide coordination complexes2020

    • Author(s)
      Hasegawa Miki、Ishii Ayumi
    • Journal Title

      Coordination Chemistry Reviews

      Volume: 421 Pages: 213458-213458

    • DOI

      10.1016/j.ccr.2020.213458

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chiroptical Spectroscopic Studies on Lanthanide Complexes with Valinamide Derivatives in Solution2020

    • Author(s)
      Hasegawa Miki、Iwasawa Daichi、Kawaguchi Takuma、Koike Hikaru、Saso Akira、Ogata Shuhei、Ishii Ayumi、Ohmagari Hitomi、Iwamura Munetaka、Nozaki Koichi
    • Journal Title

      ChemPlusChem

      Volume: 85 Issue: 2 Pages: 294-300

    • DOI

      10.1002/cplu.201900692

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Aspects of lanthanide complexes for selectivity, intensity and sharpness in luminescence bands from twenty-four praseodymium, europium and gadolinium complexes with differently distorted-hexadentate ligands2020

    • Author(s)
      Hasegawa Miki、Sakurai Shoya、Yamaguchi Masafumi Andrew、Iwasawa Daichi、Yajima Naho、Ogata Shuhei、Inazuka Yudai、Ishii Ayumi、Suzuki Kengo
    • Journal Title

      Photochemical & Photobiological Sciences

      Volume: 19 Issue: 8 Pages: 1054-1062

    • DOI

      10.1039/d0pp00069h

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mixed Tb/Dy coordination ladders based on tetra(carboxymethyl)thiacalix[4]arene: a new avenue towards luminescent molecular nanomagnets2020

    • Author(s)
      Ovsyannikov A. S.、Khariushin I. V.、Solovieva S. E.、Antipin I. S.、Komiya H.、Marets N.、Tanaka H.、Ohmagari H.、Hasegawa M.、Zakrzewski J. J.、Chorazy S.、Kyritsakas N.、Hosseini M. W.、Ferlay S.
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 20 Pages: 11755-11765

    • DOI

      10.1039/d0ra01263g

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 自然落下現象を利用した希土類錯体のトリボルミネッセンス評価2020

    • Author(s)
      長谷川美貴、大曲仁美
    • Journal Title

      日本画像学会誌

      Volume: 59 Pages: 49-53

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Helicate Lanthanide Complexes: The Luminescent Elements2020

    • Author(s)
      Hasegawa Miki、Ohmagari Hitomi
    • Journal Title

      Chemistry Letters

      Volume: 49 Issue: 7 Pages: 845-854

    • DOI

      10.1246/cl.200184

    • NAID

      130007872531

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Solvent‐Dependent Bending Ability of Salen‐Derived Organic Crystals2020

    • Author(s)
      Kusumoto Sotaro、Saso Akira、Ohmagari Hitomi、Hasegawa Miki、Kim Yang、Nakamura Masaaki、Lindoy Leonard F.、Hayami Shinya
    • Journal Title

      ChemPlusChem

      Volume: 85 Issue: 8 Pages: 1692-1696

    • DOI

      10.1002/cplu.202000362

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Lanthanide Luminescence Enhancement of Core?Shell Magnetite?SiO<sub>2</sub> Nanoparticles Covered with Chain-Structured Helical Eu/Tb Complexes2020

    • Author(s)
      Goderski Szymon、Kanno Shuhei、Yoshihara Koushi、Komiya Hiroaki、Goto Kenta、Tanaka Takeshi、Kawaguchi Shogo、Ishii Ayumi、Shimoyama Jun-ichi、Hasegawa Miki、Lis Stefan
    • Journal Title

      ACS Omega

      Volume: 5 Issue: 51 Pages: 32930-32938

    • DOI

      10.1021/acsomega.0c03746

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Elements of Sports: From IYPT 2019 to Tokyo 20202020

    • Author(s)
      Miki Hasegawa, Masamichi Yamanaka, Osamu Miyamae and Hayanon Science Manga Studeio
    • Journal Title

      Chemistry International

      Volume: 42 Issue: 1 Pages: 5-7

    • DOI

      10.1515/ci-2020-0102

    • Related Report
      2019 Annual Research Report
    • Open Access
  • [Journal Article] Strong Luminescent Europium Complexes Induced by the Unprecedented Anti-chelate Effect of Acyl Groups on a N6-Hexadentate Ligand2019

    • Author(s)
      S. Ogata, H. Komiya, N. Goto, R. Tanabe, K. Sugimoto, S. Kawaguchi, K. Goto, M. Hatanaka, A. Ishii and M. Hasegawa
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 6 Pages: 593-596

    • DOI

      10.1246/cl.190140

    • NAID

      130007659778

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Lanthanide-Oligomeric Brush Films: From Luminescence Properties to Structure Resolution2019

    • Author(s)
      Nicolas Marets, Shuhei Kannom Shuhei Ogata, Ayumi Ishii Shogo Kawaguchi and Miki Hasegawa
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 13 Pages: 15512-15520

    • DOI

      10.1021/acsomega.9b01775

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Preparation of Tetrazole-fused π-Conjugated Molecules and Their Fluorescence Behavior2019

    • Author(s)
      Takeshi Hata, Yoshiki Hayashi, Yuki Hasegawa, Masaki Iwai, Ayumi Ishii, Miki Hasegawa, Masayuki Shigeta and Hirokazu Urabe
    • Journal Title

      Chemirstry Letters

      Volume: 48 Issue: 7 Pages: 662-665

    • DOI

      10.1246/cl.190150

    • NAID

      130007674901

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gelation and luminescence of lanthanide hydrogels formed with deuterium oxide2019

    • Author(s)
      Zama Yusuke、Yanai Kazushige、Takeshita Juri、Ishii Ayumi、Yamanaka Masamichi、Hasegawa Miki
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 4 Pages: 1949-1955

    • DOI

      10.1039/c8ra08504h

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Soft Crystals: Flexible Response Systems with High Structural Order2019

    • Author(s)
      Kato Masako、Ito Hajime、Hasegawa Miki、Ishii Kazuyuki
    • Journal Title

      Chemistry, A European Journal

      Volume: 25 Issue: 20 Pages: 5105-5112

    • DOI

      10.1002/chem.201805641

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Trap-controlled mechanoluminescent materials2019

    • Author(s)
      Zhang Jun-Cheng、Wang Xusheng、Marriott Gerard、Xu Chao-Nan
    • Journal Title

      Progress in Materials Science

      Volume: 103 Pages: 678-742

    • DOI

      10.1016/j.pmatsci.2019.02.001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Multicolor upconversion luminescence of dye-coordinated Er3+ at the interface of Er2O3 and CaF2 nanoparticles2019

    • Author(s)
      Ishii Ayumi、Adachi Yuya、Hasegawa Ayaka、Komaba Miyu、Ogata Shuhei、Hasegawa Miki
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 20 Issue: 1 Pages: 44-50

    • DOI

      10.1080/14686996.2018.1558911

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Coordination competition between N6-hexadentate- and acyl-moiety in a ligand to lanthanide ions in anti-chelate effects2019

    • Author(s)
      Ogata Shuhei, Goto Naoto, Yoshihara Koushi, Kunihisa Sugimoto, Iwasawa Daichi, Kondo Takahiro, Kondo Kazuki, Mizushima Soichi, Tsuchiyagaito Junko, Kawaguchi Shogo, Goto Kenta, Hatanaka Miho, Ishii Ayumi and Miki Hasegawa
    • Journal Title

      Chemistry Letters

      Volume: 0 Pages: 00-00

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Making graphene luminescent by adsorption of an amphiphilic europium complex2018

    • Author(s)
      Hara Yusuke、Yoshihara Koushi、Kondo Kazuki、Ogata Shuhei、Watanabe Takeshi、Ishii Ayumi、Hasegawa Miki、Koh Shinji
    • Journal Title

      Applied Physics Letters

      Volume: 112 Issue: 17 Pages: 173103-173103

    • DOI

      10.1063/1.5016418

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enzymatic hydrolysis-induced degradation of a lactose-coupled supramolecular hydrogel2018

    • Author(s)
      Akama Shuto、Maki Takumi、Yamanaka Masamichi
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 64 Pages: 8814-8817

    • DOI

      10.1039/c8cc04727h

    • NAID

      120006543649

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gabriel Synthesis of Hexakis(aminomethyl)benzene and Its Derivatization2018

    • Author(s)
      Masuda Junya、Kondo Seiya、Matsumoto Yoshiteru、Yamanaka Masamichi
    • Journal Title

      ChemistrySelect

      Volume: 3 Issue: 22 Pages: 6112-6115

    • DOI

      10.1002/slct.201800985

    • NAID

      120006543646

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of a Bis-Urea Dimer and Its Effects on the Physical Properties of an Amphiphilic Tris-Urea Supramolecular Hydrogel2018

    • Author(s)
      Sawada Hiroki、Yamanaka Masamichi
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 13 Issue: 8 Pages: 929-933

    • DOI

      10.1002/asia.201800217

    • NAID

      120006542496

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Scalable Elasticoluminescent Strain Sensor for Precise Dynamic Stress Imaging and Onsite Infrastructure Diagnosis2018

    • Author(s)
      Liu Linsheng、Xu Chao-Nan、Yoshida Akihito、Tu Dong、Ueno Naohiro、Kainuma Shigenobu
    • Journal Title

      Advanced Materials Technologies

      Volume: 4 Issue: 1 Pages: 1800336-1800336

    • DOI

      10.1002/admt.201800336

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sustainable Mechanoluminescence by Designing a Novel Pinning Trap in Crystals2018

    • Author(s)
      Tu Dong、Hamabe Ryouta、Xu Chao-Nan
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 41 Pages: 23307-23311

    • DOI

      10.1021/acs.jpcc.8b06714

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Piezophotonics: From fundamentals and materials to applications2018

    • Author(s)
      Hao Jianhua、Xu Chao-Nan
    • Journal Title

      MRS Bulletin

      Volume: 43 Issue: 12 Pages: 965-969

    • DOI

      10.1557/mrs.2018.296

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Phosphorescence Resulting from Interaction between Two Non-equivalent Metals on a Helical π-Conjugated Surface2018

    • Author(s)
      Akiyama Midori、Tsuchiya Yuto、Ishii Ayumi、Hasegawa Miki、Kurashige Yuki、Nozaki Kyoko
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 13 Issue: 15 Pages: 1902-1905

    • DOI

      10.1002/asia.201800780

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Slow Magnetic Relaxation in a Palladium-Gadolinium Complex Induced by Electron Density Donation from the Palladium Ion2018

    • Author(s)
      Izuogu David C.、Yoshida Takefumi、Zhang Haitao、Cosquer Goulven、Katoh Keiichi、Ogata Shuhei、Hasegawa Miki、Nojiri Hiroyuki、Damjanovi? Marko、Wernsdorfer Wolfgang、Uruga Tomoya、Ina Toshiaki、Breedlove Brian K.、Yamashita Masahiro
    • Journal Title

      Chemistry - A European Journal

      Volume: 24 Issue: 37 Pages: 9285-9294

    • DOI

      10.1002/chem.201800699

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Alkyl chain elongation and acyl group effects in a series of Eu/Tb complexes with hexadentate π-electronic skeletons and their enhanced luminescence in solutions2018

    • Author(s)
      Ogata Shuhei、Goto Naoto、Sakurai Shoya、Ishii Ayumi、Hatanaka Miho、Yoshihara Koushi、Tanabe Ryota、Kayano Kyosuke、Magaribuchi Ryo、Goto Kenta、Hasegawa Miki
    • Journal Title

      Dalton Transactions

      Volume: 47 Issue: 21 Pages: 7135-7143

    • DOI

      10.1039/c7dt04899h

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The Enhanced Intramolecular Energy Transfer and Strengthened ff Luminescence of a Stable Helical Eu Complex in Ionic Liquids2018

    • Author(s)
      [1]Yuki Hasegawa, Ayumi Ishii*, Yudai Inazuka, Naho Yajima, Shogo Kawaguchi, Kunihisa Sugimoto, and Miki Hasegawa*
    • Journal Title

      Molecules

      Volume: 23 Issue: 2 Pages: 55-66

    • DOI

      10.3390/molecules23020055

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhanced Quantum Yield of Fluorophores in Confined Spaces of Supermicroporous Silicas2018

    • Author(s)
      Shumpei Ogawa, Takuya Wakayama, Hiroto Watanabe, Kosei Hayashi, Shuhei Ogata, Yuya Oaki, Miki Hasegawa, and Hiroaki Imai
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 1 Pages: 87-91

    • DOI

      10.1246/bcsj.20170291

    • NAID

      130006309055

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Sensitive Photodetection with Photomultiplication Effect in an Interfacial Eu2+/3+ Complex on a Mesoporous TiO2 Film2018

    • Author(s)
      Ayumi Ishii, Tatsuro Sakai, Riku Takahashi, Shuhei Ogata, Kazuki Kondo, Takahiro Kondo, Daichi Iwasawa, Soichi Mizushima, Koushi Yoshihara, and Miki Hasegawa
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 10 Issue: 6 Pages: 5706-5713

    • DOI

      10.1021/acsami.7b18200

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Computational study on the luminescence quantum yields of terbium complexes with 2,2′-bipyridine derivative ligands2018

    • Author(s)
      Hatanaka Miho、Osawa Ayato、Wakabayashi Tomonari、Morokuma Keiji、Hasegawa Miki
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 5 Pages: 3328-3333

    • DOI

      10.1039/c7cp06361j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Luminescence of Chiral and Helicate Lanthanide Complexes2022

    • Author(s)
      Miki Hasegawa
    • Organizer
      International CREST-CPL Conference
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enhancement of lanthanide luminescence property via the soft crystalline state2021

    • Author(s)
      Miki Hasegawa
    • Organizer
      PACIFICHEM2021, #254 symposium “Photofunctions of Soft Crystals Constructed with Coordination Compounds”
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Multiple ligand-/Ln-centered luminescence of mononuclear lanthanide complexes with phenanthroline2021

    • Author(s)
      Hitomi Ohmagari, Yukina Yamamoto, Yuto Yoshida, Miki Hasegawa
    • Organizer
      PACIFICHEM2021, #254 symposium “Photofunctions of Soft Crystals Constructed with Coordination Compounds”
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Vapor-responsible luminescent terbium complexes with helicate structure2021

    • Author(s)
      Hideyuki Tanaka, Kanade Machida, Hitomi Ohmagari, Miki Hasegawa
    • Organizer
      PACIFICHEM2021, #254 symposium “Photofunctions of Soft Crystals Constructed with Coordination Compounds”
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Highly luminescent hydrogel of water-soluble Eu complexes2021

    • Author(s)
      Kanade Machida, Hitomi Ohmagari, Takayuki Nonoyama, Jian Ping Gong, Miki Hasegawa
    • Organizer
      PACIFICHEM2021, #254 symposium “Photofunctions of Soft Crystals Constructed with Coordination Compounds”
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Luminescence properties of terbium complex with the tetradentate ligand bridging two phenanthroline moietie2021

    • Author(s)
      Yukina Yamamoto, Yuto Yoshida, Hitomi Ohmagari, Miki Hasegawa
    • Organizer
      PACIFICHEM2021, #254 symposium “Photofunctions of Soft Crystals Constructed with Coordination Compounds”21
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Triboluminescence of Rare Earth Complexes Relating to the Pillar Formation in the Soft-Crystalline State2021

    • Author(s)
      Miki Hasegawa
    • Organizer
      The 3rd International Symposium on Soft Crystals
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 架橋した4座フェナントロリン誘導体の希土類イオンに対する配位に関わる知見2021

    • Author(s)
      大曲仁美, 吉田雄斗, 山本侑貴奈, 長谷川美貴
    • Organizer
      第二回オンラインライジングスター研究会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Helicate Europium Complexes for the Design of Efficiend Luminescence and Electro Luminescence Devices2021

    • Author(s)
      Miki Hasegawa
    • Organizer
      239th ECS Meeting
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ソフトクリスタル特性と希土類錯体の発光2020

    • Author(s)
      長谷川美貴
    • Organizer
      錯体化学会オンライン研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 2個のフェナントロリンを架橋した四座配位子を有するテルビウム錯体の発光特性2020

    • Author(s)
      山本 侑貴奈, 大曲 仁美, 田中 敦也, 長谷川 美貴
    • Organizer
      錯体化学会第70会討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] シッフ塩基を配位子とした可視光励起型可視発光性希土類錯体の開発2020

    • Author(s)
      鎌田 諄・MARETS Nicolas・齋藤 大将・大曲 仁美・加藤 昌子・長谷川 美貴
    • Organizer
      錯体化学会第70会討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Dual Energy Donor System in a Helicate Terbium Complex Exhibiting Vapochromic-luminescence2020

    • Author(s)
      Hideyuki Tanaka, Hitomi Ohmagari, Daisuke Saito, Yasuhiro Shigeta, Eiji Ishibori, Shogo Kawaguchi, Masako Kato, Miki Hasegawa
    • Organizer
      錯体化学会第70会討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水溶性ユウロピウム錯体を導入した強発光性ヒドロゲルの開発2020

    • Author(s)
      町田 奏, 大曲 仁美, 野々山 貴行, グン 剣萍, 長谷川美貴
    • Organizer
      錯体化学会第70会討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 蒸気応答型発光性テルビウム錯体のエネルギー緩和機構の解明2020

    • Author(s)
      田中 秀幸・大曲 仁美・齋藤 大将・西堀 英治・河口 彰吾・加藤 昌子・長谷川 美貴
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 連結型フェナントロリンの電子状態を利用したππ*およびff遷移による多重発光性希土類錯体の開発2020

    • Author(s)
      大曲仁美・山本侑貴奈・田中敦也・長谷川美貴
    • Organizer
      複合系の光機能研究会オンラインライジングスター研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Linearly Polarized Luminescence of Eu with Amphiphilic Naphthalene Based Complexes of the Layered-Molecular Films2019

    • Author(s)
      Miki Hasegawa
    • Organizer
      International Symposium on Soft Crystals
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Linearly Polarized Luminescence of Eu with Amphiphilic Naphthalene Based Complexes of the Layered-Molecular Films2019

    • Author(s)
      Miki Hasegawa
    • Organizer
      International Symposium on Photchemistry and Photophysics on Coordination Compounds
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Helicate Molecular Structure Enhances the Luminescence of Lanthanide Complexes2019

    • Author(s)
      Miki Hasegawa
    • Organizer
      7th Asian Conference on Coordination Chemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Luminescent Lanthanide Complexes with the Hilicate Molecular Structure toward to the Soft Crystals2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      The 7th International Mini-symposium on Advanced Coordination Chemistry: Satellite Symposium on Soft Crystals
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enhanced Luminescence in Lanthanide Complexes with Helical Molecular Structure in Solutions2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      The 10th International Symposium on Nano and Supramolecular Chemistry (ISNSC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photoelectric conversion and photoemission properties of an interfacial Eu complex on a TiO2 film2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structures and Luminescence Properties of Lanthanide Complex Immobilized on ZnO Nanorods2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Luminescence behavior in the solid state of a series of helicate Tb complex2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Luminescence properties of Eu and Tb ions in polyvinyl alcohol with organic molecules2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced Intramolecular Energy Transfer in a Strengthened Helical Structure in Europium complexes and their Luminescent Behavior in ionic liquid2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Sensing profiles of a water-soluble Eu complex with a single helical ligand2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Alkyl chain elongation of Eu complexes with helical p-electronic skeletons and their enhanced luminescence properties in solution2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The Helicate Structure in Lanthanide Complexes towards Luminescent Soft Crystals2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      43th International Conference on Coordination Chemistry 2018 (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] New Aspects of the Enhanced ff-Emission in Hilicate Complexes2018

    • Author(s)
      Miki Hasegawa
    • Organizer
      The 10th International Conference on f-Elements (ICFE10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アントラキノン誘導体を配位子としたEu錯体/TiO2薄膜素子の光電変換特性2018

    • Author(s)
      高橋陸、石井あゆみ、長谷川美貴
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] ヘリカルな水溶性Eu錯体と金属イオンの相互作用によるセンシング特性2018

    • Author(s)
      佐相輝、長谷川美貴、他
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 希土類錯体を固定化したZnOナノロッドの構造と光学特性2018

    • Author(s)
      古宮裕章、石井あゆみ、長谷川美貴
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 有機分子を導入したポリビニルアルコール中のユウロピウムおよびテルビウムの発光特性2018

    • Author(s)
      小林峻、長谷川美貴、他
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] キラル部位を含むランタニド錯体の種々の状態における発光特性2018

    • Author(s)
      稲塚雄大、長谷川美貴、他
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Lactose-coupled supramolecular hydrogel responsive to enzymatic reaction2018

    • Author(s)
      Masamichi Yamanaka
    • Organizer
      The 10th Singapore International Chemistry Conference (SICC-10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enzymatic Hydrolysis Responsive Supramolecular Hydrogel2018

    • Author(s)
      Masamichi Yamanaka
    • Organizer
      International Conference on Emerging Advanced Nanomaterials ICEAN 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Property of Hexakis-urea2018

    • Author(s)
      Masamichi Yamanaka
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 超分子ヒドロゲルを用いた生体高分子の電気泳動2018

    • Author(s)
      山中正道、他
    • Organizer
      第69回日本電気泳動学会総会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 酵素応答性超分子ヒドロゲルの開発2018

    • Author(s)
      山中正道、他
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 超分子ゲル形成における低分子ゲル化剤ダイマーの添加効果2018

    • Author(s)
      山中正道、他
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ヘキサキスアミド及びウレア誘導体の合成と物性2018

    • Author(s)
      山中正道、他
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 糖親水基を有する低分子ヒドロゲル化剤の開発2018

    • Author(s)
      山中正道、他
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] ヘキサキスアミド及びウレア誘導体の合成と構造解析2018

    • Author(s)
      山中正道、他
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 糖親水基を有する低分子ヒドロゲル化剤の開発2018

    • Author(s)
      山中正道、他
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 生体イメージングを目指した近赤外応力発光体による応力分布の可視化2018

    • Author(s)
      徐超男、他
    • Organizer
      公益社団法人日本セラミックス協会 2018年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 新規赤色応力発光材料Ca4Ti3O10:Pr3+の開発2018

    • Author(s)
      徐超男、他
    • Organizer
      公益社団法人日本セラミックス協会 2018年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 近赤外応力発光を利用した生体イメージングへの挑戦2018

    • Author(s)
      徐超男、他
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水素社会に資する見えないき裂の可視化技術2018

    • Author(s)
      徐超男
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Progress in piezoluminescence and mechanoluminescence2018

    • Author(s)
      徐超男
    • Organizer
      4th International Workshop on Persistent and Photostimulable Phosphors (2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Approaches to new field of multi-piezo: Ceramics, films and composites2018

    • Author(s)
      徐超男
    • Organizer
      4th International Workshop on Persistent and Photostimulable Phosphors (2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 応力発光技術に関する最近の取り組み2018

    • Author(s)
      徐超男
    • Organizer
      フレキシブルエネルギ-デバイスコンソ-シアム平成30年度第2回講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 応力発光によるノッチ入り試験片の強度評価2018

    • Author(s)
      徐超男、他
    • Organizer
      第38 回エレクトロセラミックス研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 強誘電体を用いた新規Multi-Piezo発光体の開発2018

    • Author(s)
      徐超男、他
    • Organizer
      第38 回エレクトロセラミックス研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 層状ペロブスカイト構造を有する応力発光材料の構造制御と発光特性評価2018

    • Author(s)
      徐超男、他
    • Organizer
      第38 回エレクトロセラミックス研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 近赤外応力発光体を利用した生体内の応力分布の可視化2018

    • Author(s)
      徐超男、他
    • Organizer
      第38 回エレクトロセラミックス研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Piezoluminescence LiNbO3:Pr3+ for stress sensing with no threshold2018

    • Author(s)
      徐超男
    • Organizer
      Low Dimensional Materials for Optoelectronics (LDMO2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 応力発光体とマルチピエゾ機能 -生体関連への展開-2018

    • Author(s)
      徐超男、他
    • Organizer
      公益社団法人日本セラミックス協会 第22回生体関連セラミックス討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 応力発光技術を用いた構造物の最先端損傷評価2018

    • Author(s)
      徐超男、他
    • Organizer
      サステナブル技術連携促進シンポジウム「インフラメンテナンス」 ~オール産総研の最先端インフラ点検・モニタリング・診断技術を紹介~
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] New aspects of lanthanide luminescence with helicate structures2017

    • Author(s)
      Miki Hasegawa
    • Organizer
      European Advanced Materials Congress
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Isotope Effects on the lanthanide luminescence in complexes2017

    • Author(s)
      Miki Hasegawa
    • Organizer
      the 7th International Symposium on Energy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Polarized luminescence of the thin-films of lanthanide complexes2017

    • Author(s)
      Miki Hasegawa
    • Organizer
      International Workshop on Advanced Display Materials and Devices 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Molecular design of luminescent rare earth complexes with helicate structures2017

    • Author(s)
      Miki Haseagwa
    • Organizer
      Phosphor Safari 2017; PS-IWASOM'2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] Luminescent Nanomaterials2022

    • Author(s)
      Edited by Odireleng Martin Ntwaeaborwa
    • Total Pages
      508
    • Publisher
      Taylor and Francis Group
    • ISBN
      9781003277385
    • Related Report
      2021 Annual Research Report
  • [Remarks] 青山学院大学 長谷川研究室

    • URL

      http://www.chem.aoyama.ac.jp/Chem/ChemHP/inorg2/

    • Related Report
      2019 Annual Research Report
  • [Remarks] AGU Research

    • URL

      https://gendai.ismedia.jp/articles/-/69944

    • Related Report
      2019 Annual Research Report
  • [Remarks] 青山学院大学 長谷川研究室

    • Related Report
      2018 Annual Research Report
  • [Remarks] 青山学院大学 未来材料化学デザイン研究所

    • URL

      https://www.aoyama.ac.jp/research/laboratory/fmcd/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 青山学院大学 長谷川美貴研究室

    • URL

      http://www.chem.aoyama.ac.jp/Chem/ChemHP/inorg2/

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] コア/シェル型Ln錯体ナノ粒子2018

    • Inventor(s)
      長谷川美貴、二瓶あゆみ
    • Industrial Property Rights Holder
      長谷川美貴、二瓶あゆみ
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
  • [Funded Workshop] The 7th International Mini-symposium on Advanced Coordination Chemistry: Sattelite Symposium on Soft Crystals2018

    • Related Report
      2018 Annual Research Report
  • [Funded Workshop] The sixth International Minisymposium on Advanced Coordination Chemistry2017

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-07-04   Modified: 2023-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi