| Budget Amount *help |
¥79,560,000 (Direct Cost: ¥61,200,000、Indirect Cost: ¥18,360,000)
Fiscal Year 2021: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2020: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2019: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2018: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2017: ¥21,320,000 (Direct Cost: ¥16,400,000、Indirect Cost: ¥4,920,000)
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| Outline of Final Research Achievements |
The development of the efficient synthesis methods of high-value-added molecules from simple, stable and readily available molecules is important for the maintenance and future development of the highly civilized society. However, it must be said that the conversion of simple molecules with generally low reactivity is extremely difficult even with current cutting-edge science and technology. In this study, we aimed to construct hybrid catalyst systems for the transformation of simple molecules by activating metal complex catalysts with photo/electrochemical stimulation and by utilizing the catalytically active species generated. As a result, a hybrid catalytic system for the conversion of C1 compounds was created using a pentanuclear cobalt complex, and a highly efficient electrochemical oxygen-evolution hybrid catalytic system using a tetranuclear cobalt complex was successfully developed.
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