| Budget Amount *help |
¥144,950,000 (Direct Cost: ¥111,500,000、Indirect Cost: ¥33,450,000)
Fiscal Year 2021: ¥29,250,000 (Direct Cost: ¥22,500,000、Indirect Cost: ¥6,750,000)
Fiscal Year 2020: ¥29,250,000 (Direct Cost: ¥22,500,000、Indirect Cost: ¥6,750,000)
Fiscal Year 2019: ¥29,250,000 (Direct Cost: ¥22,500,000、Indirect Cost: ¥6,750,000)
Fiscal Year 2018: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2017: ¥42,640,000 (Direct Cost: ¥32,800,000、Indirect Cost: ¥9,840,000)
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| Outline of Final Research Achievements |
In this project, we have realized previously difficult asymmetric transformations, such as the three-component 1,2-dicarbofunctionalization of acyclic olefins, which had remained an unsolved problem due to the difficulty of continuous stereocontrol. The other representative achievement is the development of hybrid catalytic system of chiral ionic organic molecular catalysts and photoredox catalysts, leading to the realization of precise stereocontrol of asymmetric radical reactions.
We have also developed unique hybrid catalytic system of zwitterionic catalysts and photoredox catalysts for implementing dehydrogenative cross-coupling, specifically a direct coupling between heteroatom-containing C－H donors and enamides or 1,1-diarylethenes, under visible-light irradiation without any external oxidants.
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