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Development of efficient molecular transformation system using [metal complexes/chiral Brønsted acids] hybrid catalysis

Planned Research

Project AreaHybrid Catalysis for Enabling Molecular Synthesis on Demand
Project/Area Number 17H06447
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

TERADA Masahiro  東北大学, 理学研究科, 教授 (50217428)

Project Period (FY) 2017-06-30 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥119,860,000 (Direct Cost: ¥92,200,000、Indirect Cost: ¥27,660,000)
Fiscal Year 2021: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
Fiscal Year 2020: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
Fiscal Year 2019: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
Fiscal Year 2018: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
Fiscal Year 2017: ¥34,060,000 (Direct Cost: ¥26,200,000、Indirect Cost: ¥7,860,000)
Keywords不斉合成 / 有機分子触媒 / 遷移金属錯体 / 物質変換 / ハイブリッド触媒 / 触媒
Outline of Final Research Achievements

In this research, we aimed to develop a two-component hybrid catalyst system that combines "selective molecular transformation using organocatalysts, especially chiral Bronsted acids", that the applicant has been involved in so far, with "a specific molecular transformation using a metal complex catalyst". In order to develop an efficient and selective method for the preparation of enantioenriched compounds that surpass conventional catalytic systems, we connected these catalytic systems in a relay manner in one-pot during the course of the substance conversion. We have successfully established several hybrid catalytic systems using chiral Bronsted acids combined not only with metal complexes but also with photoactivation system. In addition, we also achieved the development of a chiral Bronsted acid catalyst having a higher acidity than that of conventional chiral acids, which is the key to achieving a hybrid catalytic system.

Academic Significance and Societal Importance of the Research Achievements

医薬品などの複雑化、多様化に伴い、光学活性化合物の効率的かつ選択的な合成法の確立は、益々重要となってきている。これらの迅速な供給には、効率と選択性を究極まで高めた高度分子変換反応の開発が不可欠である。加えて環境問題の深刻化により廃棄物の削減など環境に配慮した合成法の開発は急務である。本研究では二成分ハイブリッド触媒系とすることで、これらの触媒による物質変換をワンポットでリレー式につなぎ、従来系を凌ぐ効率的かつ選択的な光学活性化合物の供給法を確立することを目的としている。本研究により環境への負荷軽減や多様化する有用物質を選択的かつ効率的に供給する高度分子変換反応の開発が期待される。

Report

(6 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (63 results)

All 2022 2021 2020 2019 2018 2017 Other

All Journal Article (31 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 31 results,  Acknowledgement Compliant: 2 results) Presentation (24 results) (of which Int'l Joint Research: 15 results,  Invited: 22 results) Remarks (8 results)

  • [Journal Article] Chiral Bronsted Acid Catalyzed Enantioconvergent Synthesis of Chiral Tetrahydrocarbazoles with Allenylsilanes from Racemic Indolylmethanols2022

    • Author(s)
      Umemiya Shigenobu、Lingqi Kong、Eto Yuno、Terada Masahiro
    • Journal Title

      Chemistry Letters

      Volume: 51 Issue: 4 Pages: 391-394

    • DOI

      10.1246/cl.210803

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pd-Catalyzed Indolization/<i>peri</i>-C-H Annulation/<i>N</i>-Dealkylation Cascade to Cyclopenta-Fused Acenaphtho[1,2-<i>b</i>]indole Scaffold2021

    • Author(s)
      Jin Tienan、Suzuki Shin、Ho Hon Eong、Matsuyama Hidenori、Kawata Masaki、Terada Masahiro
    • Journal Title

      Organic Letters

      Volume: 23 Issue: 24 Pages: 9431-9435

    • DOI

      10.1021/acs.orglett.1c03575

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of chiral bisphosphoric acid/boronic acid co-catalyst system for enantioselective SN2’ reaction2021

    • Author(s)
      Kayal Satavisha、Kikuchi Jun、Shinagawa Naoya、Umemiya Shigenobu、Terada Masahiro
    • Journal Title

      Tetrahedron

      Volume: 98 Pages: 132412-132412

    • DOI

      10.1016/j.tet.2021.132412

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioconvergent Substitution Reactions of Racemic Electrophiles by Organocatalysis2021

    • Author(s)
      Kikuchi Jun、Terada Masahiro
    • Journal Title

      Chemistry - A European Journal

      Volume: 27 Issue: 40 Pages: 10215-10225

    • DOI

      10.1002/chem.202100439

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Bronsted acid catalyst2021

    • Author(s)
      Toda Yasunori、Korenaga Toshinobu、Obayashi Ren、Kikuchi Jun、Terada Masahiro
    • Journal Title

      Chemical Science

      Volume: 12 Issue: 30 Pages: 10306-10312

    • DOI

      10.1039/d1sc02122b

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Radical addition reaction between chromenols and toluene derivatives initiated by Brensted acid catalyst under light irradiation2021

    • Author(s)
      Jun Kikuchi, Shota Kodama, Masahiro Terada
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 8 Issue: 15 Pages: 4153-4159

    • DOI

      10.1039/d1qo00657f

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cu-Catalyzed [1,3]-Alkoxy Rearrangement/Diels?Alder Cascade Reactions via in Situ Generation of Functionalized ortho-Quinol Imines2021

    • Author(s)
      Nakamura Itaru、Masukawa Kazuki、Ishida Yasuhiro、Terada Masahiro
    • Journal Title

      Organic Letters

      Volume: 23 Issue: 11 Pages: 4127-4132

    • DOI

      10.1021/acs.orglett.1c00995

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Phosphoric Acid-Catalyzed Enantioselective Phospha-Michael-Type Addition Reaction of Diarylphosphine Oxides with Alkenyl Benzimidazoles2020

    • Author(s)
      Hou Linan、Kikuchi Jun、Ye Haiting、Bao Ming、Terada Masahiro
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 85 Issue: 22 Pages: 14802-14809

    • DOI

      10.1021/acs.joc.0c01840

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chiral Phosphoric Acid Catalyzed Enantioselective [4 + 2] Cycloaddition Reaction of α-Fluorostyrenes with Imines2020

    • Author(s)
      Kikuchi Jun、Ye Haiting、Terada Masahiro
    • Journal Title

      Organic Letters

      Volume: 22 Issue: 22 Pages: 8957-8961

    • DOI

      10.1021/acs.orglett.0c03360

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Oxidative Friedel?Crafts Reaction Triggered Ring Expansion Affording 9,10-Diarylphenanthrenes2020

    • Author(s)
      Yang Lu、Gridnev Ilya D.、Terada Masahiro、Jin Tienan
    • Journal Title

      Organic Letters

      Volume: 22 Issue: 22 Pages: 8920-8924

    • DOI

      10.1021/acs.orglett.0c03283

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exo‐Cyclization: Intermolecular Methylene Transfer Sequence in Au‐Catalyzed Reactions of O‐Homopropargylic Oximes2020

    • Author(s)
      Nakamura Itaru、Hirayama Arinobu、Gima Shinya、Terada Masahiro
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Issue: 68 Pages: 15816-15820

    • DOI

      10.1002/chem.202002764

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tandem Oxidative Ring Expansion for Synthesis of Dibenzocyclooctaphenanthrenes2020

    • Author(s)
      Yang Lu、Matsuyama Hidenori、Zhang Sheng、Terada Masahiro、Jin Tienan
    • Journal Title

      Organic Letters

      Volume: 22 Issue: 13 Pages: 5121-5125

    • DOI

      10.1021/acs.orglett.0c01725

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral strong Br&oslash;nsted acid-catalyzed enantioselective addition reaction of simple olefins with ethyl glyoxylate2020

    • Author(s)
      Kikuchi Jun、Aizawa Yuki、Terada Masahiro
    • Journal Title

      Organic Chemistry Frontiers

      Volume: 7 Issue: 11 Pages: 1383-1387

    • DOI

      10.1039/d0qo00448k

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One‐Pot Synthesis of Enantioenriched β‐Amino Secondary Amides via an Enantioselective [4+2] Cycloaddition Reaction of Vinyl Azides with N ‐Acyl Imines Catalyzed by a Chiral Br&oslash;nsted Acid2020

    • Author(s)
      Nakanishi Taishi、Kikuchi Jun、Kaga Atsushi、Chiba Shunsuke、Terada Masahiro
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Issue: 37 Pages: 8230-8234

    • DOI

      10.1002/chem.202002049

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of meta-Substituted Anilines via Copper-Catalyzed [1,3]-Methoxy Rearrangement2020

    • Author(s)
      Nakamura Itaru、Tashiro Hiroki、Ishida Yasuhiro、Terada Masahiro
    • Journal Title

      Organic Letters

      Volume: 22 Issue: 10 Pages: 3794-3798

    • DOI

      10.1021/acs.orglett.0c01009

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non‐Enzymatic Hybrid Catalysis for Stereoconversion of l ‐Amino Acid Derivatives to d ‐Isomers2020

    • Author(s)
      Nagato Yuya、Kiyokawa Mari、Ueki Yusuke、Kikuchi Jun、Ohmatsu Kohsuke、Terada Masahiro、Ooi Takashi
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 9 Issue: 4 Pages: 447-447

    • DOI

      10.1002/ajoc.202000155

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Br&oslash;nsted Acid Catalyzed Enantioconvergent Propargylic Substitution Reaction of Racemic Secondary Propargylic Alcohols with Thiols2020

    • Author(s)
      Kikuchi Jun、Takano Kyohei、Ota Yusuke、Umemiya Shigenobu、Terada Masahiro
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Issue: 49 Pages: 11124-11128

    • DOI

      10.1002/chem.202001609

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism and Origin of Stereoselectivity in Chiral Phosphoric Acid-Catalyzed Aldol-Type Reactions of Azlactones with Vinyl Ethers2020

    • Author(s)
      Kanomata, K.; Nagasawa, Y.; Shibata, Y.; Yamanaka, M.; Egawa, F.; Kikuchi, J.; Terada, M.
    • Journal Title

      Chem. Eur. J.

      Volume: 26 Issue: 15 Pages: 3364-3372

    • DOI

      10.1002/chem.201905296

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Au-catalyzed skeletal rearrangement of O-propargylic oximes via N?O bond cleavage with the aid of a Br?nsted base cocatalyst2019

    • Author(s)
      Shiga Keigo、Gridnev Ilya D.、Terada Masahiro、Nakamura Itaru
    • Journal Title

      Chemical Science

      Volume: 10 Issue: 20 Pages: 5283-5289

    • DOI

      10.1039/c9sc00501c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Addition Reaction of Azlactones with Styrene Derivatives Catalyzed by Strong Chiral Br?nsted Acids2019

    • Author(s)
      Kikuchi Jun、Terada Masahiro
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 25 Pages: 8458-8462

    • DOI

      10.1002/anie.201903111

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis-phosphoric Acid Derived from BINOL Dimer as a Chiral Br?nsted Acid Catalyst for Enantioselective Transformations2019

    • Author(s)
      Terada Masahiro、Gupta Yogesh、Kikuchi Jun
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 3 Pages: 260-263

    • DOI

      10.1246/cl.180977

    • NAID

      130007607803

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] F10BINOL-derived chiral phosphoric acid-catalyzed enantioselective carbonyl-ene reaction: theoretical elucidation of stereochemical outcomes2019

    • Author(s)
      Kikuchi Jun、Aramaki Hiromu、Okamoto Hiroshi、Terada Masahiro
    • Journal Title

      Chemical Science

      Volume: 10 Issue: 5 Pages: 1426-1433

    • DOI

      10.1039/c8sc03587c

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Intramolecular Nicholas Reaction Catalyzed by Chiral Phosphoric Acid: Enantioconvergent Synthesis of Seven-Membered Cyclic Ethers from Racemic Diols2018

    • Author(s)
      Ota Yusuke、Kondoh Azusa、Terada Masahiro
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 42 Pages: 13917-13921

    • DOI

      10.1002/anie.201808239

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Br&oslash;nsted Base-Catalyzed Reductive Cyclization of Alkynyl α-Iminoesters through Auto-Tandem Catalysis2018

    • Author(s)
      Kondoh Azusa、Terada Masahiro
    • Journal Title

      Organic Letters

      Volume: 20 Issue: 17 Pages: 5309-5313

    • DOI

      10.1021/acs.orglett.8b02236

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Br&oslash;nsted acid-catalyzed intramolecular SN2'-reaction for enantioselective construction of a quaternary stereogenic center2018

    • Author(s)
      Shimizu Masahiro、Kikuchi Jun、Kondoh Azusa、Terada Masahiro
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 26 Pages: 5747-5757

    • DOI

      10.1039/c8sc01942h

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic cobalt-catalyzed [1,3]-rearrangement of N-alkoxycarbonyloxyanilines2018

    • Author(s)
      Nakamura Itaru、Owada Mao、Jo Takeru、Terada Masahiro
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 14 Pages: 1972-1979

    • DOI

      10.3762/bjoc.14.172

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper-Catalyzed Domino [1,3]/[1,2] Rearrangement for the Efficient Synthesis of Multisubstituted ortho-Anisidines2018

    • Author(s)
      Ishida Yasuhiro、Nakamura Itaru、Terada Masahiro
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 28 Pages: 8629-8633

    • DOI

      10.1021/jacs.8b03669

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Phosphoric Acid Catalyzed Enantioselective Ring Expansion Reaction of 1,3-Dithiane Derivatives: Case Study of the Nature of Ion-Pairing Interaction2018

    • Author(s)
      Li Feng、Korenaga Toshinobu、Nakanishi Taishi、Kikuchi Jun、Terada Masahiro
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 7 Pages: 2629-2642

    • DOI

      10.1021/jacs.7b13274

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Generation and Application of Homoenolate Equivalents Utilizing [1,2]-Phospha-Brook Rearrangement under Bronsted Base Catalysis2017

    • Author(s)
      Azusa Kondoh, Takuma Aoki, Masahiro Terada
    • Journal Title

      Chemistry A European Journal

      Volume: 23 Issue: 12 Pages: 2769-2773

    • DOI

      10.1002/chem.201605673

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Enantioenriched γ-Amino-α,β-unsaturated Esters Utilizing Palladium-Catalyzed Rearrangement of Allylic Carbamates for Direct Application to Formal [3 + 2] Cycloaddition2017

    • Author(s)
      Azusa Kondoh, Yuji Kamata, Masahiro Terada
    • Journal Title

      Organic Letters

      Volume: 印刷中 Issue: 7 Pages: 1682-1685

    • DOI

      10.1021/acs.orglett.7b00471

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Indolizine Derivatives Utilizing [1,2]-Phospha-Brook Rearrangement/Cycloisomerization Sequence2017

    • Author(s)
      Azusa Kondoh, Kazumi Koda, Yuji Kamata, Masahiro Terada
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 7 Pages: 1020-1023

    • DOI

      10.1246/cl.170377

    • NAID

      130005709526

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Enantioselective Substitution Reaction Catalyzed by Chiral Bronsted Acids2021

    • Author(s)
      Masahiro Terada
    • Organizer
      Pacifichem 2021 Symposium #379 “ New Aspects on Organocatalysts ”
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Chiral Organosuperbase Catalysts Consisting of Two Different Organobase Hybrid System2021

    • Author(s)
      Masahiro Terada
    • Organizer
      Pacifichem 2021 Symposium #358 “ Hybrid Catalysis ”
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水素結合を戦略的相互作用とする有機分子触媒の創製~強酸・強塩基への展開~2021

    • Author(s)
      寺田眞浩
    • Organizer
      第37回 有機合成化学セミナー
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 有機カチオンの高次制御に基づく光反応グリーン触媒プロセスの開拓2021

    • Author(s)
      寺田眞浩
    • Organizer
      グリーン触媒ワークショップ
    • Related Report
      2021 Annual Research Report
  • [Presentation] Enantioselective Catalysis by Chiral Higher Order Organosuperbase2021

    • Author(s)
      Masahiro Terada
    • Organizer
      23rd International Conference on Phosphorus Chemistry (ICPC23)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 超強塩基性有機分子触媒を用いた不斉合成2020

    • Author(s)
      寺田眞浩
    • Organizer
      第13回 有機触媒シンポジウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Recent Progress on Chiral Br&oslash;nsted Acid Catalysis2019

    • Author(s)
      Masahiro Terada
    • Organizer
      Lectureship Award from SUSTech, Department Seminal of Southern University of Science and Technology
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Chiral Br&oslash;nsted Acid Catalysis2019

    • Author(s)
      Masahiro Terada
    • Organizer
      Department Seminal of Wuhan University
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Chiral Br&oslash;nsted Acid Catalysis2019

    • Author(s)
      Masahiro Terada
    • Organizer
      Department Seminal of Dalian University of Technology
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enantioselective Nucleophilic Substitution Reactions Catalyzed by Chiral Br&oslash;nsted Acid2019

    • Author(s)
      Masahiro Terada
    • Organizer
      The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水素結合を戦略的相互作用として用いる有機分子触媒の創製2019

    • Author(s)
      寺田眞浩
    • Organizer
      第54回 有機反応若手の会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] キラルブレンステッド酸触媒による不斉置換反応2019

    • Author(s)
      寺田眞浩
    • Organizer
      慶應義塾大学・理工学部・講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Recent Progress on Chiral Br&oslash;nsted Acid Catalysis: Enantio-Convergent Nucleophilic Substitution Reaction of Racemic Substrates2018

    • Author(s)
      Masahiro Terada
    • Organizer
      Catalysis & Fine Chemical 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Enantioselective Catalysis by Chiral Br&oslash;nsted Acids & Bases2018

    • Author(s)
      Masahiro Terada
    • Organizer
      Department Seminal of Guangzhou University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Enantioselective Catalysis by Chiral Br&oslash;nsted Acids & Bases2018

    • Author(s)
      Masahiro Terada
    • Organizer
      Department Seminal of Fudan University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Enantioselective Catalysis by Chiral Br&oslash;nsted Acids & Bases2018

    • Author(s)
      Masahiro Terada
    • Organizer
      Department Seminal of East China Normal University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Enantioselective Catalysis by Chiral Br&oslash;nsted Acids & Bases2018

    • Author(s)
      Masahiro Terada
    • Organizer
      Department Seminal of Shanghai Jiao Tong University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enantioselective Intramolecular Nicholas Reaction Catalyzed by Chiral Phosphoric Acid: Enantio-convergent Synthesis of Seven-membered Cyclic Ethers from Racemic Diols2018

    • Author(s)
      Masahiro Terada, Yusuke Ota, Azusa Kondoh
    • Organizer
      The 14th International Kyoto Conference of Organic Chemistry (IKCOC-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] New Aspects of Enantioselective Catalysis by Chiral Br&oslash;nsted Acids2018

    • Author(s)
      Masahiro Terada
    • Organizer
      The 8th Spanish-Portuguese-Japanese Organic Chemistry Symposium (8th SPJ-OCS)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Efficient Asymmetric Synthesis of Enantio-Enriched Compounds2018

    • Author(s)
      Masahiro Terada
    • Organizer
      BIO-FORUM 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] キラルリン酸触媒によるエナンチオ制御機構の解明2018

    • Author(s)
      寺田眞浩
    • Organizer
      新学術領域研究「分子合成オンデマンドを実現するハイブリッド触媒系の創製」第2回公開シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 金属錯体触媒と有機分子触媒の立体化学制御を利用した高選択的分子変換反応の開発2018

    • Author(s)
      寺田眞浩
    • Organizer
      新学術領域研究 第1回公開シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 「金属錯体/キラルブレンステッド酸」ハイブリッド触媒による効率的物質変換系の開拓2017

    • Author(s)
      寺田眞浩
    • Organizer
      新学術領域研究 キックオフミーティング
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 光学活性ペルフルオロビナフトールの合成とそのキラルリン酸誘導体を用いた不斉触媒反応の開発2017

    • Author(s)
      寺田眞浩
    • Organizer
      第40回フッ素化学討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Remarks] 新学術領域研究「ハイブリッド触媒」ホームページ

    • URL

      http://hybridcatalysis.jp/

    • Related Report
      2021 Annual Research Report 2018 Annual Research Report
  • [Remarks] 反応有機化学研究室ホームページ

    • URL

      http://www.orgreact.sakura.ne.jp/

    • Related Report
      2021 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.orgreact.sakura.ne.jp/index.html

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] 所属専攻ホームページ

    • URL

      http://www.chem.tohoku.ac.jp/

    • Related Report
      2020 Annual Research Report
  • [Remarks] 新学術領域研究ホームページ

    • URL

      http://hybridcatalysis.jp/

    • Related Report
      2020 Annual Research Report
  • [Remarks] 化学専攻ホームページ

    • URL

      http://www.chem.tohoku.ac.jp/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 新学術領域「ハイブリッド触媒」ホームページ

    • URL

      http://hybridcatalysis.jp/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 東北大学 大学院理学研究科 化学専攻 ホームページ

    • URL

      http://www.chem.tohoku.ac.jp/

    • Related Report
      2018 Annual Research Report

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Published: 2017-07-04   Modified: 2023-12-25  

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