| Budget Amount *help |
¥79,560,000 (Direct Cost: ¥61,200,000、Indirect Cost: ¥18,360,000)
Fiscal Year 2021: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2020: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2019: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2018: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2017: ¥21,320,000 (Direct Cost: ¥16,400,000、Indirect Cost: ¥4,920,000)
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| Outline of Final Research Achievements |
This project aimed to develop new catalysts, new reactions and new functional materials superior or complementary to those existing. By using half-sandwich rare-earth catalysts, we have achieved for the first time the terpolymerization of ethylene and two different methoxyaryl-substituted propylenes in a controlled domino reaction fashion, which afforded a new family of functional polyolefins with excellent self-healing property. We have synthesized a series of chiral half-sandwich rare-earth alkyl complexes that show excellent enantioselectivity and activity in various transformations such as asymmetric dearomative annulation of quinolines with alkynes and asymmetric exo-selective annulation of imidazoles with 1,1-disubstituted alkenes via C－H activation. We have achieved efficient and selective difunctionalization of imines via CO2 activation by an N/B Lewis pair under copper catalysis.
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