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Dynamics of Shear-Induced Structural Transition in Ordered Lyotropic Systems

Planned Research

Project AreaCreation of non-equilibrium soft matter physics: Structure and dynamics of mesoscopic systems
Project/Area Number 18068016
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTokyo Metropolitan University

Principal Investigator

KATO Tadashi  Tokyo Metropolitan University, 大学院・理工学研究科, 教授 (30142003)

Co-Investigator(Kenkyū-buntansha) KOMURA Shigeyuki  首都大学東京, 大学院・理工学研究科, 准教授 (90234715)
KAWABATA Youhei  首都大学東京, 大学院・理工学研究科, 助教 (50347267)
FUJII Masatoshi  島根大学, 医学部, 准教授 (60183927)
Project Period (FY) 2006 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥68,600,000 (Direct Cost: ¥68,600,000)
Fiscal Year 2010: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 2009: ¥9,800,000 (Direct Cost: ¥9,800,000)
Fiscal Year 2008: ¥11,500,000 (Direct Cost: ¥11,500,000)
Fiscal Year 2007: ¥21,900,000 (Direct Cost: ¥21,900,000)
Fiscal Year 2006: ¥15,500,000 (Direct Cost: ¥15,500,000)
Keywordsリオトロピック相 / 秩序系 / 流動場 / 相転移 / レオロジー / X線小角散乱 / 小角光散乱 / 界面活性剤 / 中性子小角散乱
Research Abstract

Although it has been known that the shear flow induces structural transition in the lyotropic phase (self-assemblies with a long-range order) composed of amphiphiles, the transition mechanism remains still unclear. In this study, we have focused on the transformation of the surfactant lamellar phase into the onion phase where the multilamellar vesicles are close-packed. We have found for the first time the lamellar→onion and lamellar→onion→lamellar transition with increasing temperature under shear flow.

Report

(7 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (59 results)

All 2011 2010 2009 2008 2007 2006 Other

All Journal Article (36 results) (of which Peer Reviewed: 30 results) Presentation (14 results) Book (3 results) Remarks (6 results)

  • [Journal Article] Vesicle growth and deformation in a surfactant solution below the Krafft temperature2011

    • Author(s)
      Y.Kawabata, T.Shinoda, T.Kato
    • Journal Title

      Phys.Chem.Chem.Phys. 13

      Pages: 3484-3490

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrodynamic Coupling between Two Fluid Membranes2011

    • Author(s)
      S.Ramachandran, S.Komura
    • Journal Title

      J.Phys.: Condens.Matter 23

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Vesicle Growth and Deformation in a Surfactant Solution below the Krafft Temperature2011

    • Author(s)
      Y.Kawabata, T.Shinoda, T.Kato
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 13 Pages: 3484-3490

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrodynamic Coupling between Two Fluid Membranes2011

    • Author(s)
      S.Ramachandran, S.Komura
    • Journal Title

      J.Phys.: Condens.Matter

      Volume: 23

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Order-Disorder Transition of Nonionic Onions under Shear Flow2010

    • Author(s)
      Y.Suganuma, M.Imai, T.Kato, U.Olsson, T.Takahashi
    • Journal Title

      Langmuir 26

      Pages: 7988-7995

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lamellar-to-Onion Transition with Increasing Temperature under Shear Flow in a Nonionic Surfactant/Water System2010

    • Author(s)
      Y.Kosaka, M.Ito, Y.Kawabata, T.Kato
    • Journal Title

      Langmuir 26

      Pages: 3835-3842

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of an Embedding Bulk Fluid on Phase Separation Dynamics in a Thin Liquid Film2010

    • Author(s)
      S.Ramachandran, S.Komura, G.Gompper
    • Journal Title

      Europhys.Lett. 89

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Order-Disorder Transition of Nonionic Onions under Shear Flow2010

    • Author(s)
      Y.Suganuma, M.Imai, T.Kato, U.Olsson, T.Takahashi
    • Journal Title

      Langmuir

      Volume: 26 Pages: 7988-7995

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lamellar-to-Onion Transition with Increasing Temperature under Shear Flow in a Nonionic Surfactant/Water System2010

    • Author(s)
      Y.Kosaka, M.Ito, Y, Kawabata, T.Kato
    • Journal Title

      Langmuir 26

      Pages: 3835-3842

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation Process of Bilayer Gel Structure in a Nonionic Surfactant Solution2009

    • Author(s)
      Y.Kawabata, A.Matsuno, T.Shinoda, T.Kato
    • Journal Title

      J.Phys.Chem.B 17

      Pages: 5686-5689

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coupled Modulated Bilayers : A Phenomenological Model2009

    • Author(s)
      Hirose, S.Komura, D.Andelman
    • Journal Title

      Chem Phys Chem 10

      Pages: 2839-2846

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Coupled Modulated Bilayers : A Phenomenological Model2009

    • Author(s)
      Y.Hirose, S.Komura, D.Andelman
    • Journal Title

      ChemPhysChem 10

      Pages: 2839-2846

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of Order-Order Phase Separation2008

    • Author(s)
      Yamada, S.Komura
    • Journal Title

      J.Phys.: Condens.Matter 20

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] On the Concentration-Induced Growth of Nonionic Wormlike Micelles2008

    • Author(s)
      S.Bulut, J.Hamit, U.Olsson, T.Kato
    • Journal Title

      Eur.Phys.J.E 27

      Pages: 261-273

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-linear Rheology of Lamellar Liquid Crystals2008

    • Author(s)
      C.-Y.D.Lu, P.Chen, Y.Ishii, S.Komura, T.Kato
    • Journal Title

      Eur.Phys.J.E 25

      Pages: 91-101

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface Force of Polystyrene Latex Particles in Aqueous Anionic Amphipathic Solutions2008

    • Author(s)
      M.Fuiii, N.Hamochi, T.Kato
    • Journal Title

      Jpn.J.Appl.Phys. 47

      Pages: 6146-6148

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of Order-Order Phase Separatio2008

    • Author(s)
      K.Yamada and S.Komura
    • Journal Title

      J.Phys.:Condens.Matter 20

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] On the Concentration-Induced Growth of Nonionic Wormlike Micelles2008

    • Author(s)
      S. Bulut, J. Hamit, U. Olsson, and T. Kato
    • Journal Title

      Eur. Phys. J. E 27

      Pages: 261-273

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of Order-Order Phase Separation2008

    • Author(s)
      K. Yamada and S. Komura
    • Journal Title

      Soft Materilas 6

      Pages: 85-95

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-linear Rheology of Lamellar Liquid Crystal2008

    • Author(s)
      C.-Y. D. Lu, P. Chen, Y. Ishii, S. Komura, and T. Kato
    • Journal Title

      Eur. Phys. J. E 25

      Pages: 91-101

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-Linear Rheology of Lamellar Liquid Crystals2008

    • Author(s)
      C.-Y.D.Lu, P.Chen, Y.Ishii, S.Komura. and T.Kato
    • Journal Title

      Eur.Phys.J.E, 18

      Pages: 343-358

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shear-Induced Structural Transition in the Lamellar Phase of C_16E_7/D_2O System.Time Evolution of Small-Angle Neutron Scattering at a Constant Shear Rate2007

    • Author(s)
      K.Miyazaki, Y.Kosaka, Y.Kawabata, S.Komura, T.Kato
    • Journal Title

      J.Appl.Cryst. 40

      Pages: 5332-5334

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Micelle structures in aqueous solutions of glucose-based surfactants having an isoprenoid-type hydrophobic chain2007

    • Author(s)
      T.Kato, Y.Kawabata, M.Fujii, T.Kato, M.Hato, H.Minamikawa
    • Journal Title

      J.Colloid Interface Sic. 312

      Pages: 122-129

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shear-Induced Structural Transition in the Lamellar Phase of C_<16>E_7/D_2O System. Time Evolution of Small-Angle Neutron Scattering at a Constant Shear Rate2007

    • Author(s)
      K.Miyazaki, Y.Kosaka, Y.Kawabata, S.Komura, and T.Kato
    • Journal Title

      J.Appl.Cryst. 40

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Micelle structures in aqueous solutions of glucose-based surfactants having an isoprenoid-type hydrophobic chain2007

    • Author(s)
      T.Kato, Y.Kawabata, M.Fujii, T.Kato, M.Hato, and H.Minamikawa
    • Journal Title

      J.Colloid Interface Sic. 312

      Pages: 122-129

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Shear-Induced Structural Transition in the Lamellar Phase of C_<16>E_7/D_2O System.Time Evolution of Small-Angle Neutron Scattering at a Constant Shear Rate2007

    • Author(s)
      K.Miyazaki, Y Kosaka, Y.Kawabata, S.Komura, and T.Kato
    • Journal Title

      J.Appl.Cryst 40

      Pages: 332-334

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth Dynamics of Domains in Ternary Fluid Vesicles2007

    • Author(s)
      M.Yanagisawa, M.Imai, T.Masui, S.Komura. and T.Ohta
    • Journal Title

      Biophys.J. 92

      Pages: 115-125

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Micelle structures in aqueous solutions of glucose-based surfactants having an isoprenoid-type hydrophobic chain2007

    • Author(s)
      T.Kato, Y.Kawabata, M.Fujii, T.Kato, M.Hato. and H.Minamikawa
    • Journal Title

      J.Colloid Interface Sic. 812

      Pages: 122-129

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Concentration Fluctuations in Binary Fluid Membranes2007

    • Author(s)
      K Seki, S Komura and M Imai
    • Journal Title

      J.Phys.:Condens.Matter 19

      Pages: 721018-721018

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mesoscale Structures in Microemulsions2007

    • Author(s)
      S.Komura
    • Journal Title

      J.Phys.:Condens.Matter 19

      Pages: 46310130-46310130

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shear-Induced Structural Transition in the Lamellar Phase of C_<16>E_7/D_2O System. Time Evolution of Small-Angle Neutron Scattering at a Constant Shear Rate.2007

    • Author(s)
      K.Miyazaki, Y.Kosaka, Y.Kawabata, S.Komura, T.Kato
    • Journal Title

      J.Appl.Cryst. 40

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Concentration fluctuations in binary fluid membranes2007

    • Author(s)
      K.Seki, S.Komura, M.Imai
    • Journal Title

      J.Phys. : Condens.Matter 19

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Tension-induced morphological transition in mixed lipid bilayers2006

    • Author(s)
      S.Komura, N.Shimokawa, D.Andelman
    • Journal Title

      Langmuir 22

      Pages: 6771-6774

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Adsorption of colloidal particles to curved interfaces2006

    • Author(s)
      S.Komura, Y.Hirose, Y.Nonomura
    • Journal Title

      J.Chem.Phys. 124

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Relocation and Upgrade of Neutron Spin Echo Spectrometer, iNSE2006

    • Author(s)
      M.Nagao, N.L.Yamada, Y.Kawabata, H.Seto, H.Yoshizawa, T.Takeda
    • Journal Title

      Physica B 385-386

      Pages: 1118-1121

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Pressure-dependence of the bending modulus of surfactant monolayers in ternary microemulsion systems observed by neutron spin echo2006

    • Author(s)
      H.Seto, M.Nagao, Y.Kawabata
    • Journal Title

      Colloid and Surfaces A : Physicochemical and Engineering Aspects 284-285

      Pages: 430-433

    • Related Report
      2006 Annual Research Report
  • [Presentation] Reentrant Lamellar/Onion Transition with Varying Temperature under Shear Flow in Nonionic Surfactant Systems2010

    • Author(s)
      T.Kato, K.Takahashi, M.Ito, K.Obara, M.Okamoto, Y.Kawabata, M.Iwahashi
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      ホノルル
    • Year and Date
      2010-12-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Reentrant Lamellar-Onion Transition with Varying Temperature under Shear Flow in Nonionic Surfactant/Water Systems2010

    • Author(s)
      T.Kato, K.Obara, M.Okamoto, D.Sato, Y.Kawabata, M.Iwahashi
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science
    • Place of Presentation
      幕張
    • Year and Date
      2010-09-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Lamellar-to-Onion Transitions with Increasing Temperature under Shear Flow in Nonionic Surfactant Systems2010

    • Author(s)
      T.Kato
    • Organizer
      ISSP International Workshop on Soft Matter Physics
    • Place of Presentation
      柏
    • Year and Date
      2010-08-12
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 非イオン界面活性剤/水系濃厚ミセルのレオロジー的性質2009

    • Author(s)
      嶋田由佳、川端庸平、加藤直
    • Organizer
      第62回コロイドおよび界面化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2009-09-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非イオン界而活性剤/水系におけるラメラ/オニオン相転移過程の時間追跡2009

    • Author(s)
      伊藤真紀子、川端庸平、加藤直
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      東京
    • Year and Date
      2009-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Rheo-SAXSを用いた非イオン界面活性剤系におけるラメラ/オニオン相転移の研究2008

    • Author(s)
      伊藤真紀子、川端庸平、加藤直
    • Organizer
      第61回コロイドおよび界面化学討論会
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-08
    • Related Report
      2010 Final Research Report
  • [Presentation] Lamellar-Th-Onion Transitions with Increasing Temperature under Shear Flow Studied by Rheo-SALS and Rheo-SAXS2008

    • Author(s)
      T.Kato
    • Organizer
      17th International Symposium on Surfactants in Solution
    • Place of Presentation
      ベルリン(ドイツ)
    • Year and Date
      2008-08-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Lamellar-To-Onion Transitions with Increasing Temperature under Shear Flow Studied by Rheo-SALS and Rheo-SAXS2008

    • Author(s)
      T. Kato
    • Organizer
      17th International Symposium on Surfactants in Solution
    • Place of Presentation
      Berlin
    • Year and Date
      2008-08-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] 非イオン界面活性剤系におけるラメラ/オニオンずり流動場誘起相転移2008

    • Author(s)
      伊藤真紀子、川端庸平、加藤直
    • Organizer
      第88回日本化学会春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Structural Transition Induced by Shear Flow and Temperature Variation in the Lamellar Phase of Nonionic Surfactant/Water Systems2008

    • Author(s)
      T.Kato
    • Organizer
      International Symposium on Engineering Micro-/Nano-Materials Based on Self-Assembling and Self-Organization
    • Place of Presentation
      東京
    • Year and Date
      2008-03-03
    • Related Report
      2010 Final Research Report
  • [Presentation] Lamellar-To-Onion Transitions with Increasing Temperature under Shear Flow Studied by Rheo-SALS and Rheo-SAXS2008

    • Author(s)
      T.Kato
    • Organizer
      17th International Symposium on Surfactants in Solution
    • Place of Presentation
      Berlin, Germany
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Lamellar to Onion Transitions with Increasing Temperature Under Shear Flow in a Nonionic Surfactant/Water System2007

    • Author(s)
      Y.Kosaka, M.Ito, Y.Kawabata, T.Kato
    • Organizer
      International Soft Matter Conference 2007
    • Place of Presentation
      アーヘン(ドイツ)
    • Year and Date
      2007-10-11
    • Related Report
      2010 Final Research Report 2007 Annual Research Report
  • [Presentation] Hydrodynamics in multicomponent biomembranes2007

    • Author(s)
      S.Komura
    • Organizer
      International Soft Matter Conference 2007
    • Place of Presentation
      アーヘン(ドイツ)
    • Year and Date
      2007-10-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] 非イオン界而活性剤ラメラ相におけるずり流動場誘起構造転移-小角散乱法による温度依存性の解析-2007

    • Author(s)
      小阪有里子, 伊藤真紀子, 川端庸平, 加藤直
    • Organizer
      日本物理学会2007年春季大会
    • Place of Presentation
      鹿児島
    • Year and Date
      2007-03-18
    • Related Report
      2010 Final Research Report
  • [Book] in Sugar-Based Surfactants(Sugar-Based Surfactants with Isoprenoid-type Hydrophobic Chains-Physicochemical and Biophysical Aspects)(C.C.Ruiz, Ed.)2008

    • Author(s)
      M.Hato, H.Minamikawa, T.Kato
    • Publisher
      CRC Press
    • Related Report
      2010 Final Research Report
  • [Book] "Sugar-Based Surfactants with Isoprenoid-type Hydrophobic Chains - Physicochemical and Biophysical Aspects" in "Sugar-Based Surfactants", C.C.Ruiz, Ed.2008

    • Author(s)
      M.Hato, H.Minamikawa, and T.Kato
    • Publisher
      CRC Press
    • Related Report
      2008 Self-evaluation Report
  • [Book] Sugar-Based Surfactants with Isoprenoid-type Hydrophobic Chains - Physico-Chemical and Biophysical Aspects, in "Sugar-Based Surfactants", C. C. Ruiz, Ed.2008

    • Author(s)
      M. Hato, H. Minamikawa, and T. Kato
    • Total Pages
      50
    • Publisher
      CRC Press
    • Related Report
      2008 Annual Research Report
  • [Remarks] 特定領域webページ

    • URL

      http://softmatter.jp/

    • Related Report
      2010 Final Research Report
  • [Remarks] 特定領域webページ

    • URL

      http://softmatter.jp/

    • Related Report
      2010 Annual Research Report
  • [Remarks] 特定領域webページ

    • URL

      http://softmatter.jp/

    • Related Report
      2009 Annual Research Report
  • [Remarks] 特定領域webページ

    • URL

      http://softmatter.jp

    • Related Report
      2008 Self-evaluation Report
  • [Remarks] 特定領域webページ

    • URL

      http://softmatter.jp/

    • Related Report
      2008 Annual Research Report
  • [Remarks] 特定領域webページ

    • URL

      http://softmatter.Jp/

    • Related Report
      2007 Annual Research Report

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Published: 2006-04-01   Modified: 2018-03-28  

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