Study of the crystal structures of materials with having regulated nano spaces

• Project Area: New Materials Science Using Regulated Nano Spaces －Strategy in Ubiquitous Elements
• Project/Area Number: 19051015
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Nagoya University
• Principal Investigator: SAWA Hiroshi 名古屋大学, 工学研究科, 教授 (50215901)
• Co-Investigator(Kenkyū-buntansha): AOYAGI Shinobu 名古屋市立大学, システム自然科学研究科, 准教授 (40360838) ; 西堀 英治 名古屋大学, 大学院・工学研究科, 准教授 (10293672)
• Co-Investigator(Renkei-kenkyūsha): NISHIBORI Eiji 名古屋大学, 工学研究科, 准教授 (10293672)
• Project Period (FY): 2007 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥42,500,000 (Direct Cost: ¥42,500,000); Fiscal Year 2011: ¥6,200,000 (Direct Cost: ¥6,200,000); Fiscal Year 2010: ¥8,900,000 (Direct Cost: ¥8,900,000); Fiscal Year 2009: ¥9,700,000 (Direct Cost: ¥9,700,000); Fiscal Year 2008: ¥10,600,000 (Direct Cost: ¥10,600,000); Fiscal Year 2007: ¥7,100,000 (Direct Cost: ¥7,100,000)
• Keywords: 放射光X線同折 / 配列ナノ空間物質 / 精密構造解析 / 電子密度解析 / フラーレン / 単結晶構造解析 / 放射光 / 放射光X線散乱 / 粉末回折 / 粉末構造決定 / 構造解析 / 放射光X線回折 / 粉末X線回折 / 金属内包フラーレン / 耕造解析 / ナノチューブ・フラーレン

Research Abstract

The precise structure analyses for the synthesized new materials in this project were performed using the synchrotron radiation X-rays diffraction technique at SPring-8. Electron density analysis using powder and single crystals diffraction were conducted for the purpose of clarifying the electronic state of functional materials, and for the revelation mechanism of quantum physical properties from a structural viewpoint. Especially we did the starting work of the single crystal diffractometer introduced on March 2008, and established measurement technology and the analysis technique. We performed the cooperative research such as the series of clathrate compounds and Li@C_<60> fullerene in this project.

Research Products

• [Journal Article] Spin-Orbital Short-Range Order on a Honeycomb-Based Lattice (2012)
  • Author(s): S. Nakatsuji, K. Kuga, K. Kimura, R. Satake, N. Katayama, F. Nishibori, H. Sawa, R. Ishii, M. Hagiwara, F. Bridges, T. U. Ito, W. Higemoto, Y. Karaki, M. Halim, A. A. Nugroho, J. A. Rodriguez-Rivera, M. A. Green, C. Broholm
  • Journal Title: Science Volume: vol. 336 no. 6081 Issue: 6081 Pages: 559-563
  • DOI: 10.1126/science.1212154
  • Peer Reviewed
• [Journal Article] Rock-salt of Thermally Contracted Cm with Mobile Lithium Cation inside (2012)
  • Author(s): Shinobu Aoyagi, Yuki Sado, Fiji Nishibori, Hiroshi Sawa, Hiroshi Okada, Hiromi Tobita, Yasuhiko Kasama, Ryo Kitaura, and Hisanori Shinohara
  • Journal Title: Angewandte Chemie International Edition Volume: 51 Issue: 14 Pages: 3377-3381
  • DOI: 10.1002/anie.201108551
  • Peer Reviewed
• [Journal Article] Single-component Layered Molecular Conductor, [Au(ptdt)(2)] (2012)
  • Author(s): B.Zhou, H.Yajima, Y.Idobata, A.Kobayashi, T.Kobayashi, E.Nishibori, H.Sawa, H.Kobayashi
  • Journal Title: Chemistry Letters Volume: 41 Issue: 2 Pages: 154-157
  • DOI: 10.1246/cl.2012.154
  • NAID: 10030223247
  • Peer Reviewed
• [Journal Article] A study of the α〓β transformation in the dimorphic clathrate Ba8Ga16Sn30 (2012)
  • Author(s): B.Dua, Y.Saigaa, K.Kajisaa, T.Takabatakea, E.Nishibori, H.Sawa
  • Journal Title: Philospphical Magazine B Volume: (印刷中)(in press)
  • Peer Reviewed
• [Journal Article] Magnetic and transport properties of the spin-state disordered oxide La_<0.8>Sr_<0.2>Co_<1-x>Rh_xO_<3-δ> (2011)
  • Author(s): Soichiro Shibasaki, Ichiro Terasaki, Eiji Nishibori, Hiroshi Sawa, Jenni Lybeck, Hisao Yamauchi, Maarit Karppinen
  • Journal Title: Physical Review B Volume: 83
  • Peer Reviewed
• [Journal Article] Crystallographic and superconducting properties of the fully gapped non centrosymmetric 5d-electron superconductors CaMSi_3 (M=Ir, Pt) (2011)
  • Author(s): G.Eguchi, D.C.Peets, M.Kriener, Y.Maeno, E.Nishibori, Y.Kumazawa, K.Banno, S.Maki, H.Sawa
  • Journal Title: Physical Review B Volume: 83
  • Peer Reviewed
• [Journal Article] Growth of Nanocrystals in a Single Crystal of Different Materials : A Way of Giving Function to Molecular Crystals (2011)
  • Author(s): Toshio Naito, Akihiro Kakizaki, Tamotsu Inabe, Riu Sakai, Eiji Nishibori, Hiroshi Sawa
  • Journal Title: Crystal Growth & Design Volume: 11 Pages: 501-506
  • Peer Reviewed
• [Journal Article] A layered ionic crystal of polar Li@C_<60> superatoms (2010)
  • Author(s): S. Aoyagi, E. Nishibori, *H. Sawa, K. Sugimoto, M. Takata, Y. Miyata, R. Kitaura, H. Shinohara, H. Okada, T. Sakai, Y. Ono, K. Kawachi, K. Yokoo, S. Ono, K. Omote, Y. Kasama, S. Ishikawa, T. Komuro, and H. Tobita
  • Journal Title: Nature Chem. Volume: 2 Issue: 8 Pages: 678-683
  • DOI: 10.1038/nchem.698
  • Peer Reviewed
• [Journal Article] Nitrated Benzne Derivatives of La@C_<82>: Addition of NO_2 and Its Positional Directing Effect on the Subsequent Addition of Benzynes (2010)
  • Author(s): X. Lu, H. Nikawa, T. Tsuchiya, *T. Akasaka, M. Toki, H. Sawa, N. Mizorogi, and *S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. Volume: 49 Issue: 3 Pages: 594-597
  • DOI: 10.1002/anie.200905024
  • Peer Reviewed
• [Journal Article] Nitrated Benzyne Derivatives of La@C82: Addition of NO2 and Its Positional Directing Effect on the Subsequent Addition of Benzynes. (2010)
  • Author(s): X. Lu, H. Nikawa, T. Tsuchiya, *T. Akasaka, M. Toki, H. Sawa, N. Mizorogi, *S. Nagase
  • Journal Title: Angew. Chem. Int. Ed. 49 Pages: 594-597
  • Peer Reviewed
• [Journal Article] Rotational Sublevels of an Ortho-Hydrogen Molecule Encapsulated in an Isotropic C60 Cage. (2009)
  • Author(s): Y. Kohama, T. Rachi, J. Jing, Z. Li, J. Tang, R. Kumashiro, S. Izumisawa, H. Kawaji, T. Atake, H. Sawa, Y. Murata, K. Komatsu, K. Tanigaki
  • Journal Title: Phys. Rev. Lett. 103 Pages: 073001-4
  • NAID: 120002086073
  • Peer Reviewed
• [Journal Article] Rotational Sublevels of an Ortho-Hydrogen Molecule Encapsulated in an Isotropic C-60 Cage (2009)
  • Author(s): Kohama Y (Kohama, Yoshimitsu)1, Rachi T (Rachi, Takeshi)2, Jing J (Ding, Ju)2, Li ZF (Li, Zhaofei)2, Tang J (Tang, Jun)2, Kumashiro R (Kumashiro, Ryotaro)2, Izumisawa S (Izumisawa, Satoru) 1, Kawaji H (Kawaji, Hitoshi)1, Atake T (Atake, Tooru) 1, Sawa H (Sawa, Hiroshi)3, Murata Y (Murata, Yasujiro)4, Komatsu K (Komatsu, Koichi)5, Tanigaki K (Tanigaki, Katsumi)2
  • Journal Title: PHYSICAL REVIEW LETTERS 103(7)
  • NAID: 120002086073
  • Peer Reviewed
• [Journal Article] Size of orbital-ordering domain controlled by the itinerancy of the 3d electrons in a manganite thin film (2009)
  • Author(s): Y.Wakabayashi, H.Sagayama, T.Arima, M.Nakamura^*, Y.Ogimoto, Y.Kubo, K.Miyano, H.Sawa
  • Journal Title: Physical Review B 79
  • Peer Reviewed
• [Journal Article] In situ observation of eutectoid reaction forming a PbTe-Sb_2Te_3 thermoelectric nanocomposite by synchrotron X-ray diffraction (2009)
  • Author(s): Teruyuki Ikeda, Eric S. Toberer, Vilupanur A. Ravi, G Jeffrey Snyder, Shinobu Aoyagi, Eiji Nishibori, Makoto Sakata
  • Journal Title: Scripta Materialia 60 Pages: 321-324
  • Peer Reviewed
• [Journal Article] In situ observation of eutectoid reaction forming a PbTe-Sb_2Te_3 thermoelectric nanocomposite by synchrotron X-ray diffraction. (2009)
  • Author(s): Teruyuki Ikeda, Eric S.Toberer, Vilupanur A.Ravi, G.Jeffrey Snyder, Shinobu Aoyagi, Eiji Nishibori, Makoto Sakata
  • Journal Title: Scripta Materialia 60 Pages: 321-324
  • Peer Reviewed
• [Journal Article] Bis-Carbene Adducts of Non-IPR La_2@C_<72>: Localization of High Reactivity around Fused Pentagons and Electrochemical Properties (2008)
  • Author(s): X. Lu, H. Nikawa, T. Tsuchiya, Y. Maeda, M. 0. Ishitsuka, T. Akasaka, M. Toki, H. Sawa, Z. Slanina, N. Mizorogi, and S. Nagase
  • Journal Title: Bis-Carbene Angew. Chem. Int. Ed. Volume: 47 Issue: 45 Pages: 8642-8645
  • DOI: 10.1002/anie.200803529
  • Peer Reviewed
• [Journal Article] Ab-initio structure determination and refinements for a pharmaceutical, Prednisolone Succinate, by the combination of Genetic Algorithm and Maximum Entropy Method from Synchrotron powder data. (2008)
  • Author(s): E. Nishibori, T. Ogura, S. Aoyagi, M. Sakata
  • Journal Title: J. Appl. Cryst. 41 Pages: 292-301
  • Peer Reviewed
• [Journal Article] Bis-Carbene Adducts of Non-IPR La 2 @ C 72 : Localization of High Reactivity around Fused Pentagons and Electrochemical Properties (2008)
  • Author(s): Xing Lu, Hidefumi Nikawa, Takahiro Tsuchiya, Yutaka Maeda, Midori O. Ishitsuka,Takeshi Akasaka,* Makoto Toki, Hiroshi Sawa, Zdenek Slanina, Naomi Mizorogi, and Shigeru Nagase
  • Journal Title: Angew. Chem. Int. Ed 47 Pages: 8642-8645
  • Peer Reviewed
• [Journal Article] Orbital Ordering Structures in (Nd, Pr) 0.5 Sr 0.5 Mn0 3 Manganite Thin Films on Perovskite (011) Substrates (2008)
  • Author(s): Yusuke Wakabayashi, Daisuke Bizen, Yugo Kubo, Hironori Nakao, Youichi Murakami, Masao Nakamura, Yasushi Ogimoto, Kenjiro Miyano, and Hiroshi Sawa
  • Journal Title: J. Phys. Soc. Jpn 77
  • Peer Reviewed
• [Journal Article] Charge density distribution of KMnF_3 under high pressure (2008)
  • Author(s): S. Aoyagi, S. Toda, E. Nishibori, Y. Kuroiwa, Y. Ohishi, M. Takata, M. Sakata
  • Journal Title: Physical Review B 78
  • Peer Reviewed
• [Journal Article] Bis-Carbene Adducts of Non-IPR La2@C72 : Localization of High Reactivity around Fused Pentagons and Electrochemical Properties (2008)
  • Author(s): Xing Lu, Hidefumi Nikawa, Takahiro Tsuchiya, Yutaka Maeda, Midori O.Ishitsuka, Takeshi Akasaka,* Makoto Toki, Hiroshi Sawa, Zdenek Slanina, Naomi Mizorogi, Shigeru Nagase
  • Journal Title: Angew.Chem.Int.Ed 47 Pages: 8642-8645
  • Peer Reviewed
• [Journal Article] Orbital Ordering Structures in (Nd,Pr)0.5Sr0.5MnO3 Manganite Thin Films on Perovskite (011) Substrates (2008)
  • Author(s): Yusuke Wakabayashi, Daisuke Bizen, Yugo Kubo, Hironori Nakao, Youichi Murakami, Masao Nakamura, Yasushi Ogimoto, Kenjiro Miyano, Hiroshi Sawa
  • Journal Title: J.Phys.Soc.Jpn 77
  • NAID: 130005436095
  • Peer Reviewed
• [Journal Article] Charge density distribution of KMnF_3 under high pressure. (2008)
  • Author(s): S.Aoyagi, S.Toda, E.Nishibori, Y.Kuroiwa, Y.Ohishi, M.Takata, M.Sakata
  • Journal Title: Physical Review B. 78
  • Peer Reviewed
• [Journal Article] Charge ordering inα-(BEDT-TTF)2I3 by synchrotron X-ray diffraction. (2007)
  • Author(s): T. Kakiuchi, Y. Wakabayashi, H. Sawa, T. Takahashi, T. Nakamura
  • Journal Title: J. Phys. Soc. Jpn. 76 Pages: 113702-113702
  • Peer Reviewed
• [Presentation] [Li@C60](PF6)の構造と相転移 (2012)
  • Author(s): 青柳忍, 佐道祐貴, 西堀英治, 澤博, 岡田洋史, 飛田博実, 笠間泰彦, 北浦良, 篠原久典
  • Organizer: 日本物理学会
  • Place of Presentation: 関西学院大学(兵庫県)
  • Year and Date: 2012-03-27
• [Presentation] 異形クフスレートBa_8Ga16Sn30のI型とVIII型の相転移 (2012)
  • Author(s): 高畠敏郎, DU Baoli, 才賀裕太, 加治佐洸介, 西堀英治, 澤博
  • Organizer: 日本物理学会
  • Place of Presentation: 関西学院大学(兵庫県)
  • Year and Date: 2012-03-24
• [Presentation] 異形クラスレートBa8Ga16Sn30のI型とVIII型の相転移に伴う構造変化 (2012)
  • Author(s): 西堀英治, 河野晃啓, 澤博, Du Baoli, 高畠敏郎
  • Organizer: 日本物理学会
  • Place of Presentation: 関西学院大学(兵庫県)
  • Year and Date: 2012-03-24
• [Presentation] 放射光による電荷分布解析 (2012)
  • Author(s): 澤博
  • Organizer: 日本物理学会第67回年次大会
  • Place of Presentation: 関西学院大学
• [Presentation] 放射光単結晶X線回折による有機半導体NT3GaCl4の電子状態の観測 (2010)
  • Author(s): 溝口裕二, 小山英之, 奥健太, 真木祥千子, 青柳忍, 西堀英治, 澤博, 阿波賀邦夫
  • Organizer: 日本物理学会
  • Place of Presentation: 大阪府立大学(大阪府)
  • Year and Date: 2010-09-26
• [Presentation] 放射光X線回折実験による分子性導体α-(BEDT-TTF)_2I_3の電子状態の観測 (2010)
  • Author(s): 小山英之, 澤博, 西堀英治, 青柳忍, 真木祥子, 酒井理宇, 熊沢雄介, 坂野翔, 中村敏和, 木野日織
  • Organizer: 日本物理学会
  • Place of Presentation: 大阪府立大学(大阪府)
  • Year and Date: 2010-09-26
• [Presentation] (TMTTF)_2PF_6の電荷秩序相における放射光X線精密構造解析 (2010)
  • Author(s): 真木祥千子, 西堀英治, 酒井理宇, 青柳忍, 澤博, 古川貢, 中村敏和
  • Organizer: 日本物理学会
  • Place of Presentation: 大阪府立大学(大阪府)
  • Year and Date: 2010-09-24
• [Presentation] 放射光X線精密構造解析によるTi酸化物の軌道秩序の直接観測 (2010)
  • Author(s): 澤博
  • Organizer: 日本物理学会第65回年次大会
  • Place of Presentation: 岡山大学津島キャンパス
  • Year and Date: 2010-03-19
• [Presentation] 放射光単結晶X線で見たクラスレート化合物Ba_8Ga_<16>Sn_<30>とBa_8Ga_<16>Ge_<30>のカゴ構造のn型p型の差 (2010)
  • Author(s): 澤博
  • Organizer: 日本物理学会第65回年次大会
  • Place of Presentation: 岡山大学津島キャンパス
  • Year and Date: 2010-03-19
• [Presentation] パイロクロア酸化物Pr_2Ir_2O_7におけるPrとIrの組成比変化および元素置換に伴う構造変化 (2010)
  • Author(s): 澤博
  • Organizer: 日本物理学会第65回年次大会
  • Place of Presentation: 岡山大学津島キャンパス
  • Year and Date: 2010-03-19
• [Presentation] X線精密構造解析による(DBr-DCNQI)_2Cuの電子状態の研究 (2010)
  • Author(s): 澤博
  • Organizer: 日本物理学会第65回年次大会
  • Place of Presentation: 岡山大学津島キャンパス
  • Year and Date: 2010-03-19
• [Presentation] ナノ空間を有する[RuII(Hbim)3]Co(Cp)2の構造 (2010)
  • Author(s): 澤博
  • Organizer: 第23回日本放射光学会年会 放射光科学合同シンポジウム
  • Place of Presentation: 兵庫県姫路市イーグレひめじ
  • Year and Date: 2010-01-08
• [Presentation] GPUを用いた文末未知構造高速決定システム (2010)
  • Author(s): 澤博
  • Organizer: 第23回日本放射光学会年会 放射光科学合同シンポジウム
  • Place of Presentation: 兵庫県姫路市イーグレひめじ
  • Year and Date: 2010-01-08
• [Presentation] BL02B1大型湾曲IPカメラを用いた単結晶高分解能電子密度分布解析の現状 (2010)
  • Author(s): 澤博
  • Organizer: 第23回日本放射光学会年会 放射光科学合同シンポジウム
  • Place of Presentation: 兵庫県姫路市イーグレひめじ
  • Year and Date: 2010-01-08
• [Presentation] 放射光X線回折を用いた分子性導体(DBr-DCNQI) _3cuの電子密度解析 (2010)
  • Author(s): 澤博
  • Organizer: 第23回日本放射光学会年会 放射光科学合同シンポジウム
  • Place of Presentation: 兵庫県姫路市イーグレひめじ
  • Year and Date: 2010-01-08
• [Presentation] 放射光構造解析による格子構造とラットリング (2010)
  • Author(s): 澤博
  • Organizer: 日本物理学会2010年秋季大会
  • Place of Presentation: 大阪府立大学
• [Presentation] 2次元検出器を用いた単結晶X線精密構造解析のための測定及び強度積分のアルゴリズムの開発 (2009)
  • Author(s): 澤博
  • Organizer: 日本結晶学会2009年年会
  • Place of Presentation: 関西学院大学西宮上ヶ原キャンパス
  • Year and Date: 2009-12-05
• [Presentation] SPring-8放射光X線IPカメラによる軌道電子可視化の試み (2009)
  • Author(s): 澤博
  • Organizer: 日本結晶学会2009年年会
  • Place of Presentation: 関西学院大学西宮上ヶ原キャンパス
  • Year and Date: 2009-12-05
• [Presentation] Challenge to Atomic Orbital Visualization by 0.2A Resolution Synchrotron Radiation Single Crystal Experiment (2009)
  • Author(s): 澤博
  • Organizer: 第9回アジア結晶学会連合会議
  • Place of Presentation: 中国・北京
  • Year and Date: 2009-10-23
• [Presentation] 内包C60の精密構造解析 (2009)
  • Author(s): 澤博
  • Organizer: 第37回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: つくば国際会議場
  • Year and Date: 2009-09-02
• [Presentation] α-(ET)2I3の常圧下での構造解析による電荷不均化の観測 (2009)
  • Author(s): 澤博
  • Organizer: 京都大学基礎物理学研究所研究会「分子性導体における質量ゼロのディラック粒子とその新展開」
  • Place of Presentation: 京都大学基礎物理学研究所
  • Year and Date: 2009-07-03
• [Presentation] Challenge to Atomic Orbital Visualization by 0.2 A^^0 Resolution Synchrotron Radiation Single Crystal Experiment (2009)
  • Author(s): H. Sawa, E. Nishibori, and S. Aoyagi
  • Organizer: AsCA'09
  • Place of Presentation: Beijing, China (oral)
• [Presentation] 内包C_<60>の精密構造解析 (2009)
  • Author(s): 澤博
  • Organizer: 第37回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: つくば国際会議場(エポカルつくば)
• [Presentation] Challenge to Atomic Orbital Visualization by 0. 2 A Resolution Synchrotron Radiation Single Crystal Experiment. (2009)
  • Author(s): H. Sawa, E. Nishibori, S. Aoyagi
  • Organizer: AsCA'09
  • Place of Presentation: Beijing, China (oral)
• [Presentation] 放射光による単結品C_<60>の精密構造解析 (2007)
  • Author(s): 澤博、土岐睦、村田靖次朗
  • Organizer: 日本物理学会2007、第62同年次大会
  • Place of Presentation: 北海道大学
• [Book] 物質科学の基礎 (2012)
  • Author(s): 那須奎一郎、澤博、門野良典
  • Publisher: 共立出版
• [Book] 物質科学の基礎 (2012)
  • Author(s): 那須奎一郎, 澤博, 門野良典
  • Publisher: 共立出版
• [Book] Molecular Electronic and Related Materials- Control and Probe with Light (2010)
  • Author(s): H. Sawa, T. Kakiuchi
  • Publisher: Transworld Research Networ
• [Book] Molecular Electronic and Related Materials- Control and Probe with Light 2010(5.Study of the novel aharge ordering state in molecular conductors using synchrotron radiation X-ray diffraction) (2010)
  • Author(s): Editor: Toshio Naito, Hiroshi Sasa, Toru Kakiuchi
  • Publisher: TRANSWORLD RESEARCH NETWORK
• [Book] 固体物理(放射光を用いた精密電子密度解析の現状と実際) (2009)
  • Author(s): 西堀英治、澤博
• [Book] 配位空間の化学-最新技術と応用-(水素吸蔵体の構造決定) (2009)
  • Author(s): 監修:北川進、澤博
  • Publisher: シーエムシー出版
• [Book] 熱電変換技術ハンドブック、梶川武信監修、2章、2節、2,亜鉛アンチモン化合物、2,1結晶構造. (2008)
  • Author(s): 西堀英治
  • Publisher: 株式会社エヌ・ティー・エス
• [Remarks]
  • URL: http://www.mcr.nuap.nagoya-u.ac.jp/
• [Remarks]
  • URL: http://www.mcr.nuap.nagoya-u.acjp/index.html
• [Remarks]
  • URL: http://www.mcr.nuap.nagoya-u.ac.jp/index.html
• [Patent(Industrial Property Rights)] 含ホウ素化合物、電解質材料、及びリチウムイオン電池 (2009)
  • Inventor(s): 守谷誠、余語利信、橋本渉、北口比呂、渥壇、西堀英治
  • Industrial Property Rights Holder: 国立大学法人名古屋大学
  • Industrial Property Number: 2009-194588
  • Filing Date: 2009-08-25
• [Patent(Industrial Property Rights)] 蛍光体 (2008)
  • Inventor(s): 大長久芳、岩崎剛、榎本公典、四ノ宮裕、青柳忍
  • Industrial Property Rights Holder: 株式会社小糸製作所
  • Acquisition Date: 2008-11-13