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Construction and properties of molecular systems inside the π-space

Planned Research

Project AreaEmergence of highly elaborated pai-space and its function
Project/Area Number 20108002
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionUniversity of Tsukuba

Principal Investigator

AKASAKA Takeshi  筑波大学, 数理物質系, 教授 (60089810)

Co-Investigator(Kenkyū-buntansha) TSUCHIYA Takahiro  筑波大学, 数理物質系, 講師 (10375412)
YAMADA Michio  東京学芸大学, 教育学部, 助教 (00583098)
Co-Investigator(Renkei-kenkyūsha) NAGASE Shigeru  京都大学, 福井謙一記念研究センター, シニアリサーチャー (30134901)
MAEDA Yutaka  東京学芸大学, 教育学部, 准教授 (10345324)
OINUMA Midori  筑波大学, 数理物質系, 講師 (20323256)
Project Period (FY) 2008 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥77,740,000 (Direct Cost: ¥59,800,000、Indirect Cost: ¥17,940,000)
Fiscal Year 2012: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2011: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2010: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2009: ¥27,560,000 (Direct Cost: ¥21,200,000、Indirect Cost: ¥6,360,000)
Fiscal Year 2008: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsフラーレン / 化学修飾 / 集積化 / FET / 金属内包フラーレン / π電子 / π曲面 / π空間
Research Abstract

Endohedral metallofullerenes have attracted special interest as building blocks of future nanoscale electronic devices and conducting materials because they have low oxidation and reduction potentials. Although the formation of crystals of endohedral Inetallofullerenes renlains difficult, chemical derivatization allows for their efficient crystallization. In this context, we investigated the charge-carrier mobilities of the single crystal of the La@C_<82>Ad derivative.

Report

(7 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (222 results)

All 2013 2012 2011 2010 2009 2008 Other

All Journal Article (117 results) (of which Peer Reviewed: 112 results) Presentation (78 results) (of which Invited: 4 results) Book (15 results) Remarks (8 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)-C822013

    • Author(s)
      S. Yang, C. Chen, F. Liu, Y. Xie, F. Li, M. Jiao, M. Suzuki, T. Wei, S. Wang, Z. Chen, X. Lu, T. Akasaka
    • Journal Title

      Scientific Reports

      Volume: 3 Issue: 1

    • DOI

      10.1038/srep01487

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-ray observation of a helium atom and placing a nitrogen atom inside He@C_60 and He@C_702013

    • Author(s)
      森中裕太
    • Journal Title

      Nature Communications

      Volume: 4 Issue: 1 Pages: 1554-1554

    • DOI

      10.1038/ncomms2574

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Endohedral Metallofullerene as a Pure Electron Donor: Intramolecular Electron Transfer in Donor-Acceptor Conjugates of La2@C80 and 11,11,12,12-tetracyano-9,10-anthra-p-quinodimethane (TCAQ),2012

    • Author(s)
      Takano, Y.; Obuchi, S.; Mizorogi, N.; Garcia, R.; Herranz, M. A.; Rudolf, M.; Guldi, D. M.; Martin, N.; Nagase, S.; Akasaka, T
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 47 Pages: 19401-19408

    • DOI

      10.1021/ja307341g

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Single Crystal X-ray Diffraction Study of Three Yb@C_<82> Isomers Cocrystallized with Ni^<II>(octaethylporphyrin)2012

    • Author(s)
      M. Suzuki, Z. Slanina, N. Mizorogi, X. Lu, S. Nagase, M. M. Olmstead, A. L. Balch, T. Akasaka
    • Journal Title

      J. Am. Chem. Soe

      Volume: 134 Issue: 45 Pages: 18772-18778

    • DOI

      10.1021/ja308706d

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of Functionalization Degree of Single-Walled Carbon Nanotubes Having Various Substituents2012

    • Author(s)
      Y. Maeda, K.Saito, N. Akanlatsu, Y. Chiba, S. Ohno, Y. Okui, M. Yamada, T. Hasegawa, M. Kako, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 43 Pages: 18101-18108

    • DOI

      10.1021/ja308969p

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stabilizing Ion and Radical Ion Pair States in a Paramagnetic Endohedral Metallofullerene and aπ-Extended Tetrathiafulvalene2012

    • Author(s)
      Y. Takano, S. Obuchi, N. Mizorogi, R. Garcia, M. A. Herranz, M. Rudolf, S. Wolfrum, D. M. Guldi, N. Martin,.S. Nagase, T. Akasaka
    • Journal Title

      J. Am. Chem

      Volume: 134 Issue: 39 Pages: 16103-16106

    • DOI

      10.1021/ja3055386

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a Silylene-Bridged Endohedral Metallofullerene Lu_ 3N@J_h-C_<80>2012

    • Author(s)
      K.Sato, M. Kako, M. Suzuki, N. Mizorogi, T. Tsuchiya, M. Olmstead, A. Balch, T, Akasaka, S., Nagasaki
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 38 Pages: 16033-16039

    • DOI

      10.1021/ja3073929

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Exceptional Chemical Properties of Sc@C_<2v>(9)-C_<82> Probed with Adamantylidine Carbene2012

    • Author(s)
      M. Hachiya, H. Nikawa, N. Mizorogi, T. Tsuchiya, X. Lu, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 37 Pages: 15550-15555

    • DOI

      10.1021/ja306890x

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Paradigmatic Change - Linking Fullerenes to Electron Acceptors2012

    • Author(s)
      L. Feng, M. Rudolf, S. Wolfrum, A. Troeger, Z. Slanina, T. Akasaka, S. Akasaka, S Nagase, N. Martin, T. Ameri, C. Brabec, D. Guldi
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 29 Pages: 12190-12197

    • DOI

      10.1021/ja3039695

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tunable Charge-transport Property of Ih-C80 Endohedral Metallofullerenes : Investigation of La2@C80, Sc3N@C80, and Sc3C2@C80.2012

    • Author(s)
      Satoru Sato
    • Journal Title

      Journal of American Chemical Society

      Volume: 134 Issue: 28 Pages: 11681-11686

    • DOI

      10.1021/ja303660g

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unexpected Formation of a Sc_3C_2@C_<80> Bisfulleroid Derivative2012

    • Author(s)
      H. Kurihara, Y. Iiduka, Y. Rubin, M. Waelchli, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. kasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 9 Pages: 4092-4095

    • DOI

      10.1021/ja300279x

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Understanding of Carbide Cluster Metallofullerenes: A Case Study on Sc_2C_2@C_<2v>(5)-C_<80> with Complete X-Ray Crystallographic Characterizations2012

    • Author(s)
      H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 6 Pages: 3139-3144

    • DOI

      10.1021/ja210101f

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Co-Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C_<82> and Nickel Porphyrin with High Electron Mobility2012

    • Author(s)
      Satoru Sato
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 51 Issue: 7 Pages: 1589-1591

    • DOI

      10.1002/anie.201106912

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] X-Ray Structures of Sc2C2@C2n (n=40, 41, 42): In-Depth Understanding of the Core-Shell Interplay in Carbide Cluster Metallofullerenes2012

    • Author(s)
      H. Kurihara, X. Lu, Y. Iiduka, H. Nikawa, M. Hachiya, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nlaga.sg, T. kasaka
    • Journal Title

      Inorg. Chem

      Volume: 51 Issue: 1 Pages: 746-750

    • DOI

      10.1021/ic202438u

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sc_2@C_<3v>(8)-C_<82> vs. Sc_2C_2@C_<3v>(8)-C_<82>: Drastic Effect of C_2 Capture on the Redox Properties of Scandium Metallofullerenes2012

    • Author(s)
      H. Kurihara, X. Lu, Y. Iiduka, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      Chem. Commmun

      Volume: 48 Issue: 9 Pages: 1290-1292

    • DOI

      10.1039/c2cc16422a

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Long-Believed S_<c2>@C_<2v>(17)-C_<84> is Actually S_<c2>C_2@C_<2v>(9)-C_<82>. Unambiguous Structure Assignment and Chemical Functionalization2012

    • Author(s)
      X. Lu, K. Nakajima, Y. Iiduka, H. Nikawa, T. Tsuchiya, N. Mizorogi, Z. Slanina, S. Nagase, T. Akasaka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 24 Pages: 5889-5892

    • DOI

      10.1002/anie.201201325

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Where Does the Metal Cation Stay in Gd@C_<2v>(9)-C_<82> A Single-Crystal X-Ray Diffraction Study2012

    • Author(s)
      M. Suzuki, X. Lu, S. Sato, H. Nikawa, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      Inorg. Chem.

      Volume: 51 Issue: 9 Pages: 5270-5273

    • DOI

      10.1021/ic300186y

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron transport through Single Endohedral Ce@C_82 Metallofullerenes2012

    • Author(s)
      Satoshi Kaneko, Lu Wang, Guangfu Luo, Ling Lu, Shigeru Nagase, Satoru Sato, Michio Yamada, Zdenek Slanina, Takeshi Akasaka, and Manabu Kiguchi
    • Journal Title

      Physical Review B

      Volume: 86 Issue: 15

    • DOI

      10.1103/physrevb.86.155406

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stability Computations for Isomers of La@C_n(n = 72, 74, 76)2012

    • Author(s)
      Z. Slanina, F. Uhlik, S.-L. Lee, L. Adamowicz, T. Akasaka, S. Nagase
    • Journal Title

      Molecules

      Volume: 17 Issue: 11 Pages: 13146-13156

    • DOI

      10.3390/molecules171113146

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis-Silylation of Lu_3N@I_h-C_<80> : Considerable Variation in the Electronic Structures2012

    • Author(s)
      K. Sato, M. Kako, N. Mizorogi, T. Tsuchiya, T. Akasaka
    • Journal Title

      Org. Lett

      Volume: 15 Issue: 23 Pages: 5908-5911

    • DOI

      10.1021/ol302832k

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diameter-Selective Purification of Carbon Nanotubes by Microwave-Assisted Acid Processing2012

    • Author(s)
      H. Qiu, Y. Maeda, T. Akasaka, J. Yang
    • Journal Title

      Sep. Purif. Technol.

      Volume: 96 Pages: 182-186

    • DOI

      10.1016/j.seppur.2012.06.001

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Elucidation and Regioselective Functionalization of an Unexplored Carbide Cluster Metallofullerene Sc_2C_2@C_s(6)-C_<82>2011

    • Author(s)
      X.Lu, K.Nakajima, Y.Iiduka, H.Nikawa, N.Mizorogi, Z.Slanina, T.Tsuchiya, S.Nagase, T.Akasaka
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 48 Pages: 19553-19558

    • DOI

      10.1021/ja208841w

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of Endohedral Metallofullerenes2011

    • Author(s)
      K.Sawai, Y.Takano, M.Izquierdo, S.Filippone, N.Martin, Z.Slanina, N.Mizorogi, M.Waelchli, T.Tsuchiya, T.Akasaka, S.Nagase
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 44 Pages: 17746-17752

    • DOI

      10.1021/ja2062727

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stable Radical Anions Inside Fullerene Cages-Formation of Reversible Electron Transfer Systems2011

    • Author(s)
      T.Tsuchiya, M.Wielopolski, N.Sakuma, N.Mizorogi, T.Akasaka, T.Kato, D.M.Guldi, S.Nagase
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 34 Pages: 13280-13283

    • DOI

      10.1021/ja205391v

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Charge-Transfer Chemistry of La_2@I_h-C_<80>/Sc_3N@I_h-C_<80>-Zinc Porphyrin Conjugates : Impact of Endohedral Cluster2011

    • Author(s)
      L.Feng, S.G.Radhakrishnan, N.Mizorogi, Z.Slanina, H.Nikawa, T.Tsuchiya, T.Akasaka, S.Nagase, N.Martin, D.Guldi
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 19 Pages: 7608-7618

    • DOI

      10.1021/ja202331r

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Bis-functionalization of Endohedral Dimetallofullerene, La_2@C_<80> : Extremal La-La Distance2011

    • Author(s)
      Midori O.Ishitsuka
    • Journal Title

      Jornal of the American Chemical Society

      Volume: 133 Issue: 18 Pages: 7128-7134

    • DOI

      10.1021/ja200903q

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Cycloaddition of La_2@I_h-C_<80> with Tetracyanoethylene Oxide : Formation of an Endohedral Dimetallofullerene Adduct Featuring Enhanced Electron-Accepting Character2011

    • Author(s)
      M.Yamada, M.Minowa, S.Sato, Z.Slanina, T.Tsuchiya, Y.Maeda, S.Nagase, T.Akasaka
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 28 Pages: 3796-3799

    • DOI

      10.1002/ange.201100961

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Semi-Metallic Single-Component Crystal of Soluble La@C_<82> Derivative with High Electron Mobility2011

    • Author(s)
      S.Sato, S.Seki, Y.Honsho, L.Wang, H.Nikawa, G.Luo, J.Lu, M.Haranaka, T.Tsuchiya, S.Nagase, T.Akasaka
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 8 Pages: 2766-2771

    • DOI

      10.1021/ja110465y

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sc_2C_2@C_<80> Rather than Sc_2@C_<82> : Templated Formation of Unexpected C_<2v>(5)-C_<80> and Temperature-Dependent Dynamic Motion of Internal Sc_2C_2 Cluster2011

    • Author(s)
      H.Kurihara, X.Lu, Y.Iiduka, N.Mizorogi, Z.Slanina, T.Tsuchiya, T.Akasaka, S.Nagase
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 8 Pages: 2382-2385

    • DOI

      10.1021/ja1107723

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Radical Derivatives of Insoluble La@C_74: X-ray Structures, Metal Positions and Isomerization2011

    • Author(s)
      X. Lu, H. Nikawa, T. Kikuchi, N. Mizorogi, Z. Slanina, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 50 Issue: 28 Pages: 6356-6359

    • DOI

      10.1002/anie.201100961

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Covalently Linked Porphyrin-La@C_<82> Hybrids : Structural Elucidation and Investigation of Intramolecular Interactions2011

    • Author(s)
      Lai Feng
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 50 Issue: 26 Pages: 5909-5912

    • DOI

      10.1002/anie.201100432

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallographic X-ray Analyses of Yb@C_<2v>(3)-C_<80> Reveal a Feasible Rule That Governs the Location of a Rare Earth Metal inside a Medium-Sized Fullerene2011

    • Author(s)
      X.Lu, Y.Lian, C.Beavers, N.Mizorogi, Z.Slanina, S.Nagase, T.Akasaka
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 28 Pages: 10772-10775

    • DOI

      10.1021/ja204653z

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Spin Coupling between Endohedral Metallofullerene La@C_<82> and a Cyclodimeric Copper Porphyrin upon Inclusion2011

    • Author(s)
      F.Hajjaj, K.Tashiro, H.Nikawa, N.Mizorogi, T.Akasaka, S.Nagase, K.Furukawa, T.Kato, T.Aida
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 24 Pages: 9290-9292

    • DOI

      10.1021/ja203491s

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Regioselective Synthesis of Bis-Aziridino[60]fullerene with Sulfilimine2011

    • Author(s)
      M.Okada, T.Nakahodo, M.O.Ishitsuka, H.Nikawa, T.Tsuchiya, T.Akasaka, T.Fujie, T.Yoshimura, Z.Slanina, S.Naga
    • Journal Title

      Chem.Asian J.

      Volume: 6 Issue: 2 Pages: 416-423

    • DOI

      10.1002/asia.201000244

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen Atom Transfer from Peroxide Intermediates to Fullerenes2011

    • Author(s)
      Y.Maeda, Y.Niino, T.Kondo, M.Yamada, T.Hasegawa, T.Akasaka
    • Journal Title

      Chem.Lett.

      Volume: 40 Pages: 1431-1433

    • NAID

      10030221607

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of Transparent and Conductive Thin Films of Single-Walled Carbon Nanotubes2011

    • Author(s)
      Y.Maeda, K.Komoriya, K.Sode, J.Higo, T.Nakamura, M.Yamada, T.Hasegawa, T.Akasaka, T.Saito, J.Lu, S.Nagase
    • Journal Title

      Nanoscale

      Volume: 3 Issue: 4 Pages: 1904-1909

    • DOI

      10.1039/c0nr00940g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition2011

    • Author(s)
      M.Yamada, C.I.Someya, T.Nakahodo, Y.Maeda, T.Tsuchiya, T.Akasaka
    • Journal Title

      Molecules

      Volume: 16 Issue: 11 Pages: 9495-9504

    • DOI

      10.3390/molecules16119495

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Introduction of Azetidinimine Skeleton on C_<60>2011

    • Author(s)
      N.Ueda, H.Nikawa, Y.Takano, M.O.Ishitsuka, T.Tsuchiya, T.Akasaka
    • Journal Title

      Heteroat.Chem.

      Volume: 2 Pages: 426-431

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organosulfur-based Fullerene Materials2011

    • Author(s)
      T.Nakahodo, M.O.Ishitsuka, Y.Takano, T.Tsuchiya, T.Akasaka, A.Herranz, N.Martin, D.M.Guldi, S.Nagase
    • Journal Title

      Phosphorus, Sulfur, Silicon Relat.Elem.

      Volume: 186 Issue: 5 Pages: 1308-1311

    • DOI

      10.1080/10426507.2010.523033

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 金属内包フラーレン:その構造と電子的特性を制御する2011

    • Author(s)
      山田道夫、佐藤悟、赤阪健、永瀬茂
    • Journal Title

      化学

      Volume: 66 Pages: 68-69

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Current Progress on the Chemical Functionalization and Supramolecular Chemistry of M@C_<82>2011

    • Author(s)
      Y.Maeda, T.Tsuchiya, X.Lu, Y.Takano, T.Akasaka, S.Nagase
    • Journal Title

      Nanoscale

      Volume: 3 Issue: 6 Pages: 2421-2429

    • DOI

      10.1039/c0nr00968g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemistry of endohedral metallofullerenes : the role of metals2011

    • Author(s)
      X.Lu, T.Akasaka, S.Nagase
    • Journal Title

      Chem.Commun.

      Volume: 47 Issue: 21 Pages: 5942-5957

    • DOI

      10.1039/c1cc10123d

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 常磁性金属内包フラーレン誘導体電荷輸送特性2011

    • Author(s)
      佐藤悟、関修平、永瀬茂、赤阪健
    • Journal Title

      PEN

      Volume: 1 Pages: 13-13

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Thermal Carbosilylation of Endohedral Dimetallofullerene La_2@I_h-C_<80> with Silirane2010

    • Author(s)
      M. Yamada, M. Minowa, S. Sato, M. Kako, Z. Slanina, N. Mizorogi, T. Tsuchiya, Y. Maeda, S. Nagase, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Issue: 50 Pages: 17953-17960

    • DOI

      10.1021/ja108671b

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photochemical Addition of C_<60> with Siliranes: Synthesis and Characterization of Carbosilylated and Hydrosilylated C_<60> Derivatives2010

    • Author(s)
      J. Nagatsuka, S. Sugitani, M. Kako, T. Nakahodo, N. Mizorogi, M.0. Ishitsuka, Y. Maeda, T. Tsuchiva, T. Akasaka, X. Gao, S. Nagase
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Issue: 34 Pages: 12106-12120

    • DOI

      10.1021/ja1049719

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Molecular Ce_2@I_h-C_<80> Switch - Unprecedented Oxidative Pathway in Photoinduced Charge Transfer Reactivity2010

    • Author(s)
      D. M. Guldi, L. Feng, S. G. Radhakrishnan, H. Nikawa, M. Yamada, N. Mizorogi, T. Tsuchiya, T. Akasaka, S. Nagase, M. A. Herranz, N. Martin
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Issue: 26 Pages: 9078-9086

    • DOI

      10.1021/ja101856j

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Donor-Acceptor Conjugates of Lanthanum Endohedral Metallofullerene and π-Extended Tetrathiafulvalene2010

    • Author(s)
      Y. Takano, M. A. Herranz, N. Martin, S. G. Radhakrishnan, D. M. Guldi, T. Tsuchiya, S. Nagase, T. Akasaka
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Issue: 23 Pages: 8048-8055

    • DOI

      10.1021/ja100665q

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Yb@C_<2n> (n=40, 41, 42):New Fullerene Allotropes with Unexplored Electrochemical Properties2010

    • Author(s)
      X. Lu, Z. Slanina, T. Akasaka, T. Tsuchiya, N. Mizorogi, S. Nagase
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Issue: 16 Pages: 5896-5905

    • DOI

      10.1021/ja101131e

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitrated Benzne Derivatives of La@C_<82>: Addition of NO_2 and Its Positional Directing Effect on the Subsequent Addition of Benzynes2010

    • Author(s)
      X. Lu, H. Nikawa, T. Tsuchiya, *T. Akasaka, M. Toki, H. Sawa, N. Mizorogi, and *S. Nagase
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 49 Issue: 3 Pages: 594-597

    • DOI

      10.1002/anie.200905024

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Effect of Atomic Nitrogen on the C_<60> Cage2010

    • Author(s)
      H. Nikawa, Y. Araki, Z. Slanina, T. Tsuchiya, T. Akasaka, T. Wada, 0. Ito, K.-P. Dinse, M. Ata, T. Kato, S. Nagase
    • Journal Title

      Chem. Commun

      Volume: 46 Issue: 4 Pages: 631-633

    • DOI

      10.1039/b914624e

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermal Carbosilylation of Endohedral Dimetallofullerene La_2@I_h-C_(80) with Silirane2010

    • Author(s)
      M.Yamada, M.Minowa, S.Sato, M.Kako, Z.Slanina, N.Mizorogi, T.Tsuchiya, Y.Maeda, S.Nagase, T.Akasaka
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 17953-17960

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Photochemical Addition of C_(60) with Siliranes : Synthesis and Characterization of Carbosilylated and Hydrosilylated C_(60) Derivatives2010

    • Author(s)
      J.Nagatsuka, S.Sugitani, M.Kako, T.Nakahodo, N.Mizorogi, M.O.Ishitsuka, Y.Maeda, T.Tsuchiya, T.Akasaka, X.Gao, S.Nagase
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 12106-12120

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] A Molecular Ce_2@I_h-C_(80) Switch-Unprecedented Oxidative Pathway in Photoinduced Charge Transfer Reactivity2010

    • Author(s)
      D.M.Guldi, L.Feng, S.G.Radhakrishnan, H.Nikawa, M.Yamada, N.Mizorogi, T.Tsuchiya, T.Akasaka, S.Nagase, M.A.Herranz, N.Martin
    • Journal Title

      J.Am.Chem.Soc 132

      Pages: 9078-9086

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Donor-Acceptor Conjugates of Lanthanum Endohedral Metallofullerene and p-Extended Tetrathiafulvalene2010

    • Author(s)
      Y.Takano, M.A.Herranz, N.Martin, S.G.Radhakrishnan, D.M.Guldi, T.Tsuchiya, S.Nagase, T.Akasaka
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 8048-8055

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Yb@C_(2n)(n=40,41,42) : New Fullerene Allotropes with Unexplored Electrochemical Properties2010

    • Author(s)
      X.Lu, Z.Slanina, T.Akasaka, T.Tsuchiya, N.Mizorogi, S.Nagase
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 5896-5905

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Thermal Carbosilylation of Endohedral Dimetallofullerene La_2@I_h-C_<80> with Silirane2010

    • Author(s)
      M.Yamada, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 17953-17960

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochemical Addition of C_<60> with Siliranes : Synthesis and Characterization of Carbosilylated and Hydrosilylated C_<60> Derivatives2010

    • Author(s)
      J.Nagatsuka, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 12106-12120

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Molecular Ce_2@I_h-C_<80> Switch-Unprecedented Oxidative Pathway in Photoinduced Charge Transfer Reactivity2010

    • Author(s)
      D.M.Guldi, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 9078-9086

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Donor-Acceptor Conjugates of Lanthanum Endohedral Metallofullerene and π-Extended Tetrathiafulvalene2010

    • Author(s)
      Y.Takano, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 8048-8055

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Yb@C_<2n>(n=40,41,42) : New Fullerene Allotropes with Unexplored Electrochemical Properties2010

    • Author(s)
      X.Lu, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 12106-12120

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Endohedral Metal Atoms in Pristine and Functionalized Fullerene Cages2010

    • Author(s)
      M.Yamada, et al.
    • Journal Title

      Acc.Chem.Res.

      Volume: 43 Pages: 92-102

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dichlorophenyl Derivatives of La@C_<3v>(7)-C_<82> : Endohedral Metal Induced Localization of Pyramidalization and Spin on a Triple-Hexagon Junction2010

    • Author(s)
      T.Akasaka, et al.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 9715-9719

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitrated Benzyne Derivatives of La@C_<82> : Addition of NO_2 and Its Positional Directing Effect on the Subsequent Addition of Benzynes2010

    • Author(s)
      X.Lu, et al.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 594-597

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Retro-reaction of Singly Bonded La@C_<82> Derivatives2010

    • Author(s)
      Y.Takano, et al.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 8035-8036

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Effect of Atomic Nitrogen on the C_<60> Cage2010

    • Author(s)
      H.Nikawa, et al.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 631-633

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlled Dispersion and Purification of Protein-Carbon Nanotube Conjugates Using Guanidine Hydrochloride2010

    • Author(s)
      A.Hirano, et al.
    • Journal Title

      Chem.Eur.J.

      Volume: 16 Pages: 12221-12228

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron Donor-Acceptor Interactions in Regioselectively Synthesized exTTF_2-C_<70>(CF_3)_<10> Dyads2010

    • Author(s)
      Y.Takano, et al.
    • Journal Title

      Chem.Eur.J.

      Volume: 16 Pages: 5343-5353

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Exohedral Functionalization of La@C_<82> and its 1,2,3,4,5-pentamethylcyclopentadiene and Adamantylidene Adducts2010

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      Chem.Eur.J.

      Volume: 16 Pages: 2193-2197

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-step Alkylation of Singlewalled Carbon Nanotubes : Substituent Effect on Sidewall Functionalization2010

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      Org.Lett.

      Volume: 12 Pages: 996-999

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-depth Understanding of π-Electron Systems : New Vistas in Fullerene Endohedrals2010

    • Author(s)
      M.Yamada, et al.
    • Journal Title

      Pure Appl.Chem.

      Volume: 82 Pages: 757-767

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Vistas in Fullerene Endohedrals : Functionalization with Compounds from Main Group Elements2010

    • Author(s)
      T.Tsuchiya, et al.
    • Journal Title

      Pure Appl.Chem.

      Volume: 82 Pages: 505-521

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Modification of Endohedral Metallofullerene La@C_<82> with 3-Chloro-3-phenyldiazirine2010

    • Author(s)
      M.O.Ishitsuka, et al.
    • Journal Title

      Phosphorus, Sulfur, and Silicon and the Related Elements

      Volume: 185 Pages: 1124-1130

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and crystal structures of [ClPh_2Sn{E(Ph_2SN)_2}] (E=CH,N)2010

    • Author(s)
      T.Fujii, et al.
    • Journal Title

      Phosphorus, Sulfur, and Silicon and the Related Elements

      Volume: 185 Pages: 1046-1053

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Half-Metallic Sandwich Molecular Wires with Negative Differential Resistance and Sign-Reversible High Spin-filter Efficiency2010

    • Author(s)
      L.Wang, et al.
    • Journal Title

      J.Phys.Chem.C

      Volume: 114 Pages: 21893-21899

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-Dimensional Protein-Based Nanoparticles Induce Lipid Bilayer Disruption : Carbon Nanotube Conjugates and Amyloid Fibrils2010

    • Author(s)
      A.Hirano, et al.
    • Journal Title

      Langmuir

      Volume: 26 Pages: 17256-17259

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of Enhanced Dispersion of Single-Walled Carbon Nanotubes with Proteins by Alcohols and Chaotropes2010

    • Author(s)
      A.Hirano, et al.
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile and Scalable Route for Highly Efficient Enrichment of Semiconducting Single-Walled Carbon Nanotubes2009

    • Author(s)
      H.Qiu, et al
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 131 Pages: 16529-16533

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Location of the Yttrium Atom in Y@C_<82> and Its Influence on the Reactivity of Cage Carbons2009

    • Author(s)
      X.Lu, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 131 Pages: 12066-12067

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Missing metallofullerene with C_<80> Cage2009

    • Author(s)
      H.Nikawa, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 131 Pages: 10950-10954

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Magnetic Behavior of Anionic Ce@C_<82> Carbene Adducts2009

    • Author(s)
      Y.Takano, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 131 Pages: 9340-9346

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two Regioisomers of Endohedral Pyrrolidinodimetallofullerene M_2@I_h-C_<80>(CH_2)_2NTrt (M=La and Ce, Trt=trityl) : Control of the Metal Positions by Addition Positions2009

    • Author(s)
      M.Yamada, et al.
    • Journal Title

      Chem.Eur.J.

      Volume: 15 Pages: 10533-10542

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synergistically Enhanced Dispersion of Native Protein-Carbon Nanotube Conjugates by Fluoroalcohols in Aqueous Solution2009

    • Author(s)
      A.Hirano, et al.
    • Journal Title

      Chem.Eur.J.

      Volume: 15 Pages: 9905-9910

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of the D_<5h> Isomer of Endohedral Dimetallofullerene Ce_2@C_<80> : Two-Dimensional Circulation of Encapsulated Metal Atoms Inside a Fullerene Cage2009

    • Author(s)
      M.Yamada, et al.
    • Journal Title

      Chem.Eur.J.

      Volume: 15 Pages: 9486-9493

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Regioselective [4+2] Cycloaddition of o-Quinodimethane to C_<70>(CF_3)_<10>2009

    • Author(s)
      Y.Takano, et al.
    • Journal Title

      J.Org.Chem.

      Volume: 74 Pages: 6902-6905

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning of Electronic Properties of Single-Walled Carbon Nanotubes under Homogenous Conditions2009

    • Author(s)
      Y.Maeda, et al.
    • Journal Title

      ChemPhysChem.

      Volume: 10 Pages: 926-930

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Type- and Diameter-Dependent Reduction of Single-Walled Carbon Nanotubes Induced by Adsorption of Electron Donor Molecules2009

    • Author(s)
      J.Zhou, et al.
    • Journal Title

      Small

      Volume: 5 Pages: 244-255

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen Atom Transfer from Carbonyl Oxide to Alkane Catalyzed by Metalloporphyrin2009

    • Author(s)
      M.Haranaka, et al.
    • Journal Title

      Tetrahedron Lett.

      Volume: 50 Pages: 3585-3587

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective and Convenient Separation Method for D_<2d>-C_<84>(84:23) using Diels-Alder Reaction2009

    • Author(s)
      M.Hachiya, et al.
    • Journal Title

      ITE-IBA Lett.

      Volume: 2 Pages: 40-45

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Characterization and Electrochemical Property of Selenylfullerenes2009

    • Author(s)
      T.Nakahodo, et al.
    • Journal Title

      Phosphorus, Sulfur, and Silicon

      Volume: 184 Pages: 1523-1540

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regiospecific Addition of La@C_<82> with Alkylidene, Alkyl Radical and Carbanion : Prediction of Regioisomers by Using "Paired Interacting Orbitals" (PIO) Analysis2009

    • Author(s)
      A.Shiga, et al.
    • Journal Title

      J.Comput.Chem.Jpn

      Volume: 8 Pages: 105-112

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Transparent and Conductive Thin Films of Carbon Nanotubes Using a Spreading/Coating Technique2009

    • Author(s)
      T.Kitano, et al.
    • Journal Title

      Carbon

      Volume: 47 Pages: 3559-3565

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Method for Separating the D_3 and C_<2v> Isomers of C_<78>2009

    • Author(s)
      A.Hong, et al.
    • Journal Title

      New J.Chem.

      Volume: 33 Pages: 497-500

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polymorphic Relation between Cavansite and Pentagonite : Genetic Implications of Oxonium in Cavansite2009

    • Author(s)
      N.Ishida, et al.
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 104 Pages: 241-252

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 金属性単層カーボンナノチューブの分離と製膜2009

    • Author(s)
      前田優, 他
    • Journal Title

      コンバーテック

      Volume: 3 Pages: 127-131

    • Related Report
      2009 Annual Research Report
  • [Journal Article] 新規フラーレン、カーボンナノチューブ系機能性材料の基礎研究2009

    • Author(s)
      土屋敬広, 他
    • Journal Title

      触媒

      Volume: 51 Pages: 20-26

    • NAID

      10023985369

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Construction of Supramolecular System Based on Endohedral Metallofullerenes2009

    • Author(s)
      T.Tsuchiya, et al.
    • Journal Title

      Bull.Chem.Soc.Jpn

      Volume: 82 Pages: 171-181

    • NAID

      10025115569

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Radical Coupling Reaction of Paramagnetic Endohedral Metallofullerene La@C_<82>2008

    • Author(s)
      Y. Takano, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 16224-16230

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Does Gd@C_<82> Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct2008

    • Author(s)
      T. Akasaka, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 12840-12841

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical Understanding of a Non-IPR Metallofullerene : Stabilization of Encaged Metals on Fused-pentagon Bonds in La_2@C_<72>2008

    • Author(s)
      X. Lu, et.al
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 9129-9136

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal Atoms Collinear with the Spiro Carbon of 6, 6-Open Adducts, M_2@C_<80>(Ad) (M = La and Ce, Ad = Adamantylidene)2008

    • Author(s)
      M. Yamada, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 1171-1176

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Addition of Adamantylidene to La_2@C_<78> : Isolation and Single-Crystal X-ray Structural Determination of the Monoadducts2008

    • Author(s)
      B. Cao, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 983-989

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanorods of Endohedral Metallofullerene Derivative2008

    • Author(s)
      T. Tsuchiya, et.al.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 450-451

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis-carbene Adducts of Non-IPR La2@C72 : Localization of High Reactivi ty around Fused-pentagons and Toward Controllable Tuning of Electroc hemical Properties of Metallofullerenes2008

    • Author(s)
      X. Lu, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 8642-8645

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of ^<13>C NMR Chemical Shifts of Metal Carbides Encapsulate d in Fullerenes : Sc_2C_2@C_<82>, Sc_2C_2@C_<84>, and Sc_3C_2@C_<80>2008

    • Author(s)
      Y. Yamazaki, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 7905-7908

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] [2+1]-Cycloaddition of Nitrene onto C_<60> Revisited : Interconversion between Aziridinofullerene and Azafulleroid2008

    • Author(s)
      T. Nakahodo, et.al.
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 1298-1300

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Excited-State and Photoelectrochemical Behavior of Pyrene-Linked Phen yleneethynylene Oligomer2008

    • Author(s)
      Y. Matsunaga, et.al.
    • Journal Title

      J. Phys. Chem. B 112

      Pages: 14539-14547

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic and Theoretical Study of Endohedral Dimetallofullerene Having a Non-IPR Fullerene Cage : Cc_2@C_<72>2008

    • Author(s)
      NI. Yamada, et.al.
    • Journal Title

      J. Phys. Chem. A 112

      Pages: 7627-7631

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isolation and Characterization of Carbene Derivatives of La@C_<82>(Cs)2008

    • Author(s)
      T. Akasaka, et.al.
    • Journal Title

      J. Phys. Chem. A 112

      Pages: 1294-1297

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simple Purification and Selective Enrichment of Metallic SWCNTs Produced Using the Arc-discharge Method2008

    • Author(s)
      Y. Maeda, et.al.
    • Journal Title

      Carbon 46

      Pages: 1563-1569

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Transparent and Conductive Thin Films of Metallic Single-walled Carbon Nanotubes2008

    • Author(s)
      Y. Maeda, et.al.
    • Journal Title

      J. Mater. Chem. 18

      Pages: 4189-4192

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Selenylfullerene with Seleniumcontaining Dibenzo[b, g]cyclooctane Moiety2008

    • Author(s)
      T. Nakahodo, et.al.
    • Journal Title

      Tetrahedron Lett 49

      Pages: 2302-2305

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Location of the Metal Atoms in Ce_2@C_<78> and its Bis-silylated Derivative2008

    • Author(s)
      M. Yamada, et.al.
    • Journal Title

      Chem. Commun. 2008

      Pages: 558-560

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Generation of Nitrene by the Photolysis of N-substituted Iminodibenzothiophene2008

    • Author(s)
      H. Morita, et.al.
    • Journal Title

      J. Org. Chem. 73

      Pages: 7159-7163

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Adsorption of Cations on Single-walled Carbon Nanotubes : A Density Functional Theory Study2008

    • Author(s)
      D. Wang, et.al.
    • Journal Title

      Computational Materials Science 43

      Pages: 886-891

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Co(II), Ni(II), and Cu(II) Complexes Containing an Eightmembered Disulfanenitrile Chelating Ring2008

    • Author(s)
      T. Fujii, et.al.
    • Journal Title

      Inorganica Chimica Acta 361

      Pages: 2540-2546

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C_<60>(OH)_n Assisted dispersion of single-walled carbon nanotubes2008

    • Author(s)
      Y. Maeda, et.al.
    • Journal Title

      Nano 3

      Pages: 455-459

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 金属性単層カーボンナノチューブの分離法の開拓2008

    • Author(s)
      前田優、長谷川正、赤阪健、永瀬茂
    • Journal Title

      ケミカルエンジニアリング 53

      Pages: 363-369

    • Related Report
      2008 Annual Research Report
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2013

    • Author(s)
      赤阪健
    • Organizer
      科研費新学術領域研究「融合マテリアル」第6回公開シンポジウム
    • Place of Presentation
      仙台市
    • Year and Date
      2013-01-28
    • Related Report
      2012 Final Research Report
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2013

    • Author(s)
      赤阪 健
    • Organizer
      科研費新学術領域研究「融合マテリアル」第6回公開シンポジウム
    • Place of Presentation
      TKPガーデンシティ仙台、仙台市
    • Year and Date
      2013-01-28
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2012

    • Author(s)
      赤阪健
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      道後温泉茶波瑠、松山市
    • Year and Date
      2012-12-14
    • Related Report
      2012 Final Research Report
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2012

    • Author(s)
      赤阪 健
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      道後温泉 茶波瑠、松山市
    • Year and Date
      2012-12-14
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Chemistry of Nanocarbons: Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      The Symposium on Material Chemistry in Heilongjiang University
    • Place of Presentation
      Harbin, China
    • Year and Date
      2012-09-14
    • Related Report
      2012 Final Research Report
  • [Presentation] New Vistas in Chemistry of Nanocarbons: Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      The Symposium on Material Chemistry in Heilongjiang University
    • Place of Presentation
      Harbin, China
    • Year and Date
      2012-09-14
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] New Vistas in fullerene Endohedrals2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      XXIst International Symposium on Jahn-Teller Effect
    • Place of Presentation
      Univ. of Tsukuba, Japan
    • Year and Date
      2012-08-26
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] New Vistas in Chemistry of Nanocarbons: Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      赤阪健
    • Organizer
      岡山大学異分野研究連携コア講演会
    • Place of Presentation
      岡山大学、岡山
    • Year and Date
      2012-08-07
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotropes: Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      9th International Conference on Nanosciences & Nanotechnologies
    • Place of Presentation
      Thessaloniki, Greece
    • Year and Date
      2012-07-03
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotropes: Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      49th Outstanding Scholors Forum in Huazhong University of Science and Technology
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2012-06-05
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 開口部を有する金属内包フラーレン誘導体の合成2012

    • Author(s)
      栗原広樹・飯塚裕子・イヴ ルービン・マーカス ヴェルヒリ・溝呂木直美・ズデネク スラニナ・土屋敬広・永瀬茂・赤阪健
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属内包フラーレンLa_2@C_<80>ラジカル誘導体の合成とキャラクタリゼーション2012

    • Author(s)
      齋藤正義・栗原広樹・相澤俊博・加藤立久・ズデネク スラニナ・永瀬茂・赤阪健
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属クラスター内包フラーレン誘導体の合成と構造解析2012

    • Author(s)
      阿部玄之・佐藤悟・齋藤千春・SLANINA Z.・土屋敬広・赤阪健・永瀬茂
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] ラジカル付加反応によるLa@C82の可逆的電子状態制御2012

    • Author(s)
      高野勇太・生沼みどり・スラニナズデネク・赤阪健・加藤立久・永瀬茂
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Structures and Chemical Properties of Carbide Cluster Fullerenes2012

    • Author(s)
      Xing Lu, Hiroki Kurihara, Koji Nakajima, Naomi Mizorogi, Takeshi Akasaka, Shigeru Nagase
    • Organizer
      第42回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2012-03-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Nanocarbons : Organic Nanomaterials Based on Endohedral Metallofullerenes2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      Forum for Nano-Materials Science 2012
    • Place of Presentation
      Xi'an Jiaotong University, Xi'an, China(招待講演)
    • Year and Date
      2012-01-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Vistas in Fullerene Chemistry: Oraganosulfur Compounds Expand the Performance of Carbon Nanomaterials2012

    • Author(s)
      Takeshi Akasaka
    • Organizer
      25th International Symposium on the Organic Chemistry of Sulfur
    • Place of Presentation
      Czestochowa, Poland
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 金属内包フラーレンを鍵物質とした有機ドナー分子との超分子系の構築2011

    • Author(s)
      土屋敬広・青山亮・佐久間理子・溝呂木直美・赤阪健・Dirk M. Guldi・加藤立久・永瀬_茂
    • Organizer
      第38回有機典型元素化学討論会
    • Place of Presentation
      石川県立音楽堂邦楽ホール
    • Year and Date
      2011-12-09
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属内包フラーレンを鍵物質とした有機ドナー分子との超分子系の構築2011

    • Author(s)
      土屋敬広・青山亮・佐久間理子・溝呂木直美・赤阪健・DirkM.Guldi・加藤立久・永瀬茂
    • Organizer
      第38回有機典型元素化学討論会
    • Place of Presentation
      石川県立音楽堂(金沢)
    • Year and Date
      2011-12-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] 化学修飾によるLa_2@C_<80>の電子アクセプター性制御2011

    • Author(s)
      山田道夫・美野輪まり・佐藤悟・溝呂木直美・Zdenek Slanina・前田優・加固昌寛・永瀬茂・赤阪健
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場(つくば)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属内包フラーレンSc_2C_<82>の構造決定とキャラクタリゼーション2011

    • Author(s)
      栗原広樹・山崎裕子・溝呂木直美・Zdenek Slanina・土屋敬広・赤阪健・永瀬茂
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場(つくば)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 常磁性金属内包フラーレン多付加体の合成2011

    • Author(s)
      阿部玄之・佐藤悟・田邊由紀子・溝呂木直美・前田優・土屋敬広・赤阪健・永瀬茂
    • Organizer
      日本化学会第5回関東支部大会(2011)
    • Place of Presentation
      東京農工大(東京)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] La内包フラーレン/有機ドナー連結系の構築2011

    • Author(s)
      中田輝・土屋敬広・赤阪健・永瀬茂
    • Organizer
      日本化学会第5回関東支部大会(2011)
    • Place of Presentation
      東京農工大(東京)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属内包フラーレンの骨格変換2011

    • Author(s)
      武藤康弘・栗原広樹・Zdenek Slanina・土屋敬広・赤阪健・永瀬茂
    • Organizer
      日本化学会第5回関東支部大会(2011)
    • Place of Presentation
      東京農工大(東京)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属内包フラーレンGd@C_<2v>-C_<82>のX線構造解析2011

    • Author(s)
      鈴木光明・佐藤悟・Lu Xing・二川秀史・土屋敬広・溝呂木直美・Zdenek Slanina・赤阪健・永瀬茂
    • Organizer
      日本化学会第5回関東支部大会(2011)
    • Place of Presentation
      東京農工大(東京)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Fullerenes : Organic Nanomaterials based on Endohedral Metallofullerenes2011

    • Author(s)
      Takeshi Akasaka
    • Organizer
      43rd IUPAC World Chemistry Congress
    • Place of Presentation
      San Juan, Puerto Rico(招待講演)
    • Year and Date
      2011-07-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electronic Modulation of Endohedral Metallofullerenes by Chemical Functionalization2011

    • Author(s)
      T. Akasaka, M. Yamada, M. Minowa, S. Sato, N. Mizorogi, Z. Slanina, T. Tsuchiya, Y. Maeda, S. Nagase
    • Organizer
      14th International Synlposium on Novel Aromatic Compounds (ISNA-14)
    • Place of Presentation
      Oregon, USA
    • Year and Date
      2011-07-24
    • Related Report
      2012 Final Research Report
  • [Presentation] Electronic Modulation of Endohedral Metallofullerenes by Chemical Functionalization2011

    • Author(s)
      Takeshi Akasaka, Mihico Yamada, Mari Minowa, Satoru Sato, Naomi Mizorogi, Zdenek Slanina, Takahiro Tsuchiya, Yutaka Maeda, Shigeru Nagase
    • Organizer
      14th International Symposium on Novel Aromatic Compounds (ISNA-14)
    • Place of Presentation
      Oregon, USA
    • Year and Date
      2011-07-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Vistas in Chemistry of Synthetic Carbon Allotopes : Organic Nanomaterials based on Endohedral Metallofullerenes2011

    • Author(s)
      Takeshi Akasaka
    • Organizer
      The First Symposium on "Carbon Nanoforms" at Nanoscience, Nanotechnology and Molecular Materials Institute (INAMOL-UCLM)
    • Place of Presentation
      Toledo, Spain(招待講演)
    • Year and Date
      2011-06-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Tuning of electronic properties of endohedral dimetallofullerene La_2@C_<80> by exohedral chemical functionalization2011

    • Author(s)
      Michio Yamada, Mari Minowa, Satoru Sato, Naomi Mizorogi, Zdenek Slanina, Takahiro Tsuchiya, Yutaka Maeda, Shigeru Nagase, Takeshi Akasaka
    • Organizer
      The First Symposium on "Carbon Nanoforms" at Nanoscience, Nanotechnology and Molecular Materials Institute (INAMOL-UCLM)
    • Place of Presentation
      Toledo, Spain
    • Year and Date
      2011-06-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Characterization of the Conjugates Based on La_2@C_<80> and pi-Extended Tetrathiafulvalene2011

    • Author(s)
      Yuta Takano, Lai Feng, Maria Angeles Herranz, Nazario Martin, Shankara Gayathri Radhakrishnan, Dirk M.Guldi, Takeshi Akasaka
    • Organizer
      The First Symposium on "Carbon Nanoforms" at Nanoscience, Nanotechnology and Molecular Materials Institute (INAMOL-UCLM)
    • Place of Presentation
      Toledo, Spain
    • Year and Date
      2011-06-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] The Role that Internal Metals Play in Endohedral Metallofullerenes2011

    • Author(s)
      Xing Lu, Hidefumi Nikawa, Naomi Mizorogi, Zdenek Slanina, Takeshi Akasaka, Shigeru Nagase
    • Organizer
      219th ECS Meeting
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2011-05-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Derivatization of the Insoluble La@C_<3v>(7)-C_<82> : Anomalous Reactivity of Cage Carbons Dictated by the Internal Metal2011

    • Author(s)
      LU, Xing
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Photophysical Properties of Metallofullerenes-Zinc Porphyrin Conjugates : Impact of Endohedral Clusters2011

    • Author(s)
      Lai Feng
    • Organizer
      第40回記念フラーレン・ナノチューブ総合シンポジウム
    • Place of Presentation
      名城大学(愛知県)
    • Year and Date
      2011-03-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Donor-Acceptor conjugates of lanthanum endohedral metallofullerene, La2@C80, and p-Extended Tetrathiafulvalene2010

    • Author(s)
      T.Akasaka
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu, Hawaii, U.S.A.
    • Year and Date
      2010-12-15
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Donor-Acceptor conjugates of lanthanum endohedral metallofullerene, La_2@C_<80>, and π-Extended Tetrathiafulvalene2010

    • Author(s)
      Y.Takano, et al
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Vistas in Fullerene Worlds : Endohedral Metallofullerenes2010

    • Author(s)
      T.Akasaka
    • Organizer
      International Symposium : The Chemistry of Synthetic Carbon Allotropes
    • Place of Presentation
      Erlangen, Germany.
    • Year and Date
      2010-11-25
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] New Vistas in Fullerene Worlds : Endohedral Metallofullerenes2010

    • Author(s)
      T.Akasaka
    • Organizer
      International Symposium : The Chemistry of Synthetic Carbon Allotropes
    • Place of Presentation
      Erlangen, Germany
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属内包フラーレンLa_2@C_<80>とπ共役拡張型テトラチアフルバレンを用いたドナー・アクセプター連結型分子の合成と構造解析2010

    • Author(s)
      高野勇太
    • Organizer
      第37回典型元素化学討論会
    • Place of Presentation
      室蘭市民会館(北海道)
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Organic Nanomaterials based on Endohedral Metallofullerenes2010

    • Author(s)
      赤阪健
    • Organizer
      H22年度日本化学会関東支部群馬地区地域懇談会
    • Place of Presentation
      日本原子力研究開発機構 高崎量子応用研究所(群馬県)
    • Year and Date
      2010-11-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Vistas in Endohedral Metallofullerenes2010

    • Author(s)
      T.Akasaka
    • Organizer
      Fullerene Silver Anniversary Symposium-FSAS 2010
    • Place of Presentation
      Heraklion, Greek
    • Year and Date
      2010-10-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] フラーレンを鍵物質とする高次π空間の創発と機能開拓2010

    • Author(s)
      赤阪健
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2010-09-09
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] フラーレンを鍵物質とする高次Π空間の創発と機能開拓2010

    • Author(s)
      赤阪健
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 異なる2つの置換基を有する金属内包フラーレンの位置選択的合成2010

    • Author(s)
      佐藤悟
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] The Role that Internal Metal(s) Play in Endohedral Metallofullerenes as Probed by Exohedral Functionalization2010

    • Author(s)
      Xing Lu
    • Organizer
      第39回フラーレン・ナノチューブ総合シンポジウム
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2010-09-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属内包フラーレンを鍵物質とした超分子系の構築2010

    • Author(s)
      土屋敬広・横澤裕也・赤阪健・DirkM.Guldi・永瀬二茂
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      筑波大学
    • Year and Date
      2010-08-30
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属内包フラーレンを鍵物質とした超分子系の構築2010

    • Author(s)
      土屋敬広
    • Organizer
      日本化学会第4回関東支部大会(2010)
    • Place of Presentation
      筑波大学(茨城県)
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Organosulfur-based Fullerene Materials2010

    • Author(s)
      T.Nakahodo, et al
    • Organizer
      24th International Conference on the Organic Chemistry of Sulfur (ISOCS-24)
    • Place of Presentation
      Florence, Italy
    • Year and Date
      2010-07-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Creation of Cage-like Carbon π-Electron Molecules with Novel Structures and Properties : New Vistas in Fullerene Endohedrals2010

    • Author(s)
      赤阪健
    • Organizer
      大阪大学産業科学研究所セミナー
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2010-06-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Bis-carbene adduct of La_2@C_<80>2010

    • Author(s)
      M.O.Ishitusuka, et al
    • Organizer
      217th ECS Meeting
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-04-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Creation of Cage-like Carbon pi-Electron Molecules with Novel Structures and Properties : New Vistas in Fullerene Endohedrals2010

    • Author(s)
      T.Akasaka
    • Organizer
      The commemorative lecture for the accession to Adjunct Professor of Heilongjiang University
    • Place of Presentation
      Harbin, China
    • Year and Date
      2010-02-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Dispersion, Separation, and reaction of single-walled carbon nanotubes2010

    • Author(s)
      Y.Maeda, et al
    • Organizer
      IWEPNM 2010
    • Place of Presentation
      Kirchberg, Austria
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属内包フラーレンとπ共役拡張型テトラチアフルバレンを用いたドナー・アクセプター連結型分子の合成2010

    • Author(s)
      高野勇太, 他
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学(東大阪)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Carbosilylation of La_2@C_<80> with Silacyclopropane2010

    • Author(s)
      美野輪まり, 他
    • Organizer
      第38回フラーレンナノチューブ総合シンポジウム
    • Place of Presentation
      名城大学(名古屋)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Emergence of Highly Elaborated pi-Space : Endohedral Metallofullerenes2009

    • Author(s)
      T. Akasaka
    • Organizer
      College of Chemistry and Molecular Engineering, Peking University
    • Place of Presentation
      Beijing, China
    • Year and Date
      2009-03-23
    • Related Report
      2008 Annual Research Report
  • [Presentation] In-depth Understanding of pi-Electron Systems : New Vistas in Fullerene Endohedrals2009

    • Author(s)
      T.Akasaka
    • Organizer
      Theoretical Organic Chemistry Workshop, The 100th Anniversary of Lan Zhou University
    • Place of Presentation
      Lan Zhou, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] In-depth Understanding of pi-Electron Systems : New Vistas in Fullerene Endohedrals2009

    • Author(s)
      T.Akasaka
    • Organizer
      13th International Symposium on Novel Aromatic Compounds (ISNA-13)
    • Place of Presentation
      Luxembourg, Luxembourg
    • Related Report
      2009 Annual Research Report
  • [Presentation] New Vistas in Fullerene Endohedrals : Functionalization with Compounds from Main Group Elements2009

    • Author(s)
      T.Akasaka
    • Organizer
      9th International Conference on Heteroatom Chemistry (ICHAC-9)
    • Place of Presentation
      Oviedo, Spain
    • Related Report
      2009 Annual Research Report
  • [Presentation] Dispersion, Separation, and Reaction of Single-walled Carbon Nanotubes2009

    • Author(s)
      Y.Maeda, et al
    • Organizer
      Cnano'09
    • Place of Presentation
      Santorini, Greece
    • Related Report
      2009 Annual Research Report
  • [Presentation] Construction of Supramolecular System Based on Endohedral Metallofullerene2009

    • Author(s)
      T.Tsuchiya, et al
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2009 Annual Research Report
  • [Presentation] A new exTTF/C_<70>(CF_3)_<10> hybrid for photo-functional molecular systems from Main Group Elements2009

    • Author(s)
      Y.Takano, et al
    • Organizer
      215th ECS Meeting
    • Place of Presentation
      San Francisco, USA
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ce@C_<82>カルベン付加体アニオンの合成と磁気異方性観測2009

    • Author(s)
      高野勇太, 他
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      群馬大学(桐生市)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属内包フラーレンのシラシクロプロパンによる化学修飾2009

    • Author(s)
      美野輪まり, 他
    • Organizer
      第3回日本化学会関東支部大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属内包フラーレン配位子の合成と性質2009

    • Author(s)
      青山亮, 他
    • Organizer
      第3回日本化学会関東支部大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 異なる2つの置換基によるLa@C_<82>の化学修飾における位置選択性2009

    • Author(s)
      佐藤悟, 他
    • Organizer
      第3回日本化学会関東支部大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ce@C_<82>カルベン付加体アニオンの合成と磁気異方性観測2009

    • Author(s)
      高野勇太, 他
    • Organizer
      第3回日本化学会関東支部大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属内包フラーレンSc_2C_<82>の構造解析と分子変換2009

    • Author(s)
      栗原広樹, 他
    • Organizer
      第3回日本化学会関東支部大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 幻の金属内包フラーレン誘導体の抽出と化学修飾2009

    • Author(s)
      伊藤剛, 他
    • Organizer
      第3回日本化学会関東支部大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Pioneering Research on the Properties and the Methods for Chemical Modification of Paramagnetic Endohedral Metallofullerenes2009

    • Author(s)
      高野勇太, 他
    • Organizer
      第37回フラーレンナノチューブ総合シンポジウム
    • Place of Presentation
      つくば国際会議場(茨城)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Two Step Regioselective Exohedral Functionalization of Endohedral Metallofullerene2009

    • Author(s)
      佐藤悟, 他
    • Organizer
      第37回フラーレンナノチューブ総合シンポジウム
    • Place of Presentation
      つくば国際会議場(茨城)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高次π空間の創発2009

    • Author(s)
      T. Akasaka
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      船橋市
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Progress in Nanocarbon Science : Endohedral Metallofullerene2008

    • Author(s)
      T. Akasaka
    • Organizer
      The Yong Hae Kim Lectureship, Korean Institute of Science and Technology
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2008-12-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Fullerene World Opened by Functionalization with Main Group Element Compounds2008

    • Author(s)
      T. Akasaka
    • Organizer
      Polish Academy of Sciences
    • Place of Presentation
      Lodz, Poland
    • Year and Date
      2008-11-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] ナノカーボンの新展開 : 金属内包フラーレン2008

    • Author(s)
      T. Akasaka
    • Organizer
      有機金属部会平成20年度第3回例会
    • Place of Presentation
      仙台市
    • Year and Date
      2008-10-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Progress in Nanocarbon Science : Endohedral Metallofullerene2008

    • Author(s)
      T. Akasaka
    • Organizer
      Plenary Lecture at Faculty of Chemical Engineering, Nanjing University of Science and Technology
    • Place of Presentation
      Nanjing, China
    • Year and Date
      2008-09-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] A New Approach for Nano-Device Applications -More is Different in Metallofullerenes2008

    • Author(s)
      T. Akasaka
    • Organizer
      NIMS Week 2008
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2008-07-15
    • Related Report
      2008 Annual Research Report
  • [Presentation] A New Approach for Nano-Device Applications -More is Different in Metallofullerenes2008

    • Author(s)
      T. Akasaka
    • Organizer
      University of California at Davis
    • Place of Presentation
      Davis, USA
    • Year and Date
      2008-07-01
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Progress in Chemistry of Nanocarbons : Endohedral Metallofullerpnes2008

    • Author(s)
      T. Akasaka
    • Organizer
      Department of Chemistry, University of Compultense at Madrid
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2008-06-09
    • Related Report
      2008 Annual Research Report
  • [Book] Stability Computations for Fullerenes and Metallofullerenes2012

    • Author(s)
      Z. Slanina, F. Uhlik, S-L. Lee, T. Akasaka and S. Nagase
    • Publisher
      In "Handbook of Carbon Nano Materials" F. D'Souza & K. M. Kadish, Eds.; World Scientific
    • Related Report
      2012 Final Research Report
  • [Book] Stability Computations for Fullerenes and Metallofullerenes In "Handbook of Carbon Nano Materials2012

    • Author(s)
      Z. Slanina, F. Uhlik, S-L. Lee, T. Akasaka, S. Nagase
    • Total Pages
      49
    • Publisher
      World Scientific
    • Related Report
      2012 Annual Research Report
  • [Book] Endohedral Metallofullerene Functionalization, In "Advances in Carbon Nanomaterials: Science and Applications2012

    • Author(s)
      Y. Maeda, T. Akasaka, S. Nagase
    • Total Pages
      30
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2012 Annual Research Report
  • [Book] カーボンナノチューブへのカルボキシル基導入とその官能基変換2011

    • Author(s)
      前田優、赤阪健、山田道夫、長谷川正
    • Publisher
      技術情報協会出版
    • Related Report
      2011 Annual Research Report
  • [Book] アミンによる単層カーボンナノチューブの分散と分離2011

    • Author(s)
      前田優、赤阪健、山田道夫、長谷川正
    • Publisher
      技術情報協会出版
    • Related Report
      2011 Annual Research Report
  • [Book] Chemistry of Nanocarbons2010

    • Author(s)
      T. Akasaka, F. Wudl, amd .S. Nagase Eds
    • Total Pages
      498
    • Publisher
      Wiley-Blackwell, Chichester
    • Related Report
      2012 Final Research Report
  • [Book] Chemistry of Nanocarbons(Recent Progress in Chemistry of Endohedral Metallofullerenes)(T.Akasaka, F.Wudl, and S.Nagase Eds)2010

    • Author(s)
      T.Tsuchiya, T.Akasaka, S.Nagase
    • Publisher
      Wiley-Blackwell, London
    • Related Report
      2010 Self-evaluation Report
  • [Book] Carbon Nanotubes and Related Structures(Endohedrals)(D.Guldi and N.Martin Eds.)2010

    • Author(s)
      L.Feng, T.Akasaka, S.Nagase
    • Publisher
      Wiley-VCH, Verlag GmbH & Co.KGaA, Weinheim
    • Related Report
      2010 Self-evaluation Report
  • [Book] Rare Earth Coordination Chemistry-Fundamentals and Applications(Rare Earth Metals Trapped inside Fullerenes-Endohedral Moallofullerenes)(C.H.Huang Ed.)2010

    • Author(s)
      X.Lu, T.Akasaka, S.Nagase
    • Publisher
      John Wiley & Sons, Singapore
    • Related Report
      2010 Self-evaluation Report
  • [Book] Chemistry of Nanocarbons, "Recent Progress in Chemistry of Endohedral Metallofullerenes"2010

    • Author(s)
      T. Akasaka, et al
    • Total Pages
      26
    • Publisher
      Wiley-Blackwell, London
    • Related Report
      2010 Annual Research Report
  • [Book] Chemistry of Nanocarbons, "Dispersion, Separation of Single-walled Carbon Nanotubes"2010

    • Author(s)
      T. Akasaka, et al
    • Total Pages
      19
    • Publisher
      Wiley-Blackwell, London
    • Related Report
      2010 Annual Research Report
  • [Book] Carbon Nanotubes and Related Structures "Carbon Nanostructures : Calculations of Their Energetics, Thermodynamics, and Stability"2010

    • Author(s)
      T. Akasaka, et al
    • Total Pages
      33
    • Publisher
      Wiley-VCH, Verlag GmbH & Co.KGaA, Weinheim
    • Related Report
      2010 Annual Research Report
  • [Book] Carbon Nanotubes and Related Structures "Endohedrals"2010

    • Author(s)
      T. Akasaka, et al
    • Total Pages
      36
    • Publisher
      Wiley-VCH, Verlag GmbH & Co.KGaA, Weinheim
    • Related Report
      2010 Annual Research Report
  • [Book] Rare Earth Coordination Chemistry-Fundamentals and Applications "Rare Earth Metals Trapped inside Fullerenes-Endohedral Moallofullerenes"2010

    • Author(s)
      T. Akasaka, et al
    • Total Pages
      36
    • Publisher
      John Wiley & Sons, Singapore
    • Related Report
      2010 Annual Research Report
  • [Book] カーボンナノチューブの精製・前処理と分散・可溶化技術、第二章、第二節 有機溶媒系におけるカーボンナノチューブの分離精製2009

    • Author(s)
      前田優, 他
    • Publisher
      (株)技術情報協会
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • Related Report
      2012 Final Research Report
  • [Remarks] 赤阪研究室HP

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.pi-space.jp/

    • Related Report
      2011 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2010 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.tara.tsukuba.ac.jp/~akasaka-lab/

    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属内包フラーレンイオン2011

    • Inventor(s)
      赤阪健
    • Industrial Property Rights Holder
      国立大学法人筑波大学
    • Acquisition Date
      2011-02-04
    • Related Report
      2010 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 有機修飾カーボンナノチューブの製造方法2009

    • Inventor(s)
      前田 優・赤阪 健
    • Industrial Property Rights Holder
      独立行政法人科学技術振興機構
    • Filing Date
      2009-03-12
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 水系媒体中へのカーボンナノチューブの分散方法2009

    • Inventor(s)
      平野篤、前田優、赤阪健、白木賢太郎
    • Industrial Property Rights Holder
      筑波大学
    • Filing Date
      2009-10-26
    • Related Report
      2010 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 水系媒体中へのカーボンナノチューブの分散方法2009

    • Inventor(s)
      平野篤、前田優、赤阪健、白木賢太郎
    • Industrial Property Rights Holder
      筑波大学
    • Industrial Property Number
      2009-245773
    • Filing Date
      2009-10-26
    • Related Report
      2009 Annual Research Report

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Published: 2008-04-01   Modified: 2018-03-28  

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