Creation and Function of Spherical π-Space Encapsulating an Active Small Molecule

• Project Area: Emergence of highly elaborated pai-space and its function
• Project/Area Number: 20108003
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyoto University
• Principal Investigator: MURATA Yasujiro 京都大学, 化学研究所, 教授 (40314273)
• Co-Investigator(Renkei-kenkyūsha): MURATA Michihisa 京都大学, 化学研究所, 助教 (30447932)
• Project Period (FY): 2008 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥31,460,000 (Direct Cost: ¥24,200,000、Indirect Cost: ¥7,260,000); Fiscal Year 2012: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000); Fiscal Year 2011: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000); Fiscal Year 2010: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000); Fiscal Year 2009: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000); Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
• Keywords: フラーレン / 内包フラーレン / 開口フラーレン / 水素 / 水 / ヘリウム / 窒素 / π空間 / 活性小分子 / 三次元π共役系 / 三次元π共役 / C70 / 水素分子 / 平衡定数

Research Abstract

Synthetic methodologies were developed for endohedral fullerenes C_<60> and C_<70> encapsulating a helium atom, hydrogen molecules, or a water molecule, under mild conditions. The properties of a single molecule completely isolated from the out side world and outer fullerene cages were studied. Furthermore, open-cage fullerene derivatives were used for organic photovoltaic devices showing a high V_<oc> values.

Research Products

• [Journal Article] Synthesis and photovoltaic properties of acceptor materials based on the dimerization of fullerene C_60 for use in efficient polymer solar cells (2013)
  • Author(s): 森中裕太
  • Journal Title: Chemical Communications Volume: (印刷中) Issue: 35 Pages: 3670-3672
  • DOI: 10.1039/c3cc41084f
  • Peer Reviewed
• [Journal Article] X-ray observation of a helium atom and placing a nitrogen atom inside He＠C_60 and He＠C_70 (2013)
  • Author(s): 森中裕太
  • Journal Title: Nature Communications Volume: 4 Issue: 1 Pages: 1554-1554
  • DOI: 10.1038/ncomms2574
  • Peer Reviewed
• [Journal Article] Quantum Rotation of Ortho and Para-water Encapsulated in a Fullerene Cage, Beduz, C.; Carravetta (2012)
  • Author(s): Beduz, C.; Carravetta, M.; Chen, J. Y.-C.; Concistre, M.; Denning, M.; Frunzi, M.; Horsewill, A. J.; Johannessen, O. G.; Lawler, R.; Lei, X.; Levitt, M. H.; Li, Y.; Mamone, S.; Murata, Y.; Nagel, U.; Nishida, T.; Ollivier, J.; Rols, S.; Room, T.; Sarker, R.; Turro, N. J.; Yang, Y
  • Journal Title: Proc. Natl. Acad. Sci. USA Volume: 109 Issue: 32 Pages: 12894-12898
  • DOI: 10.1073/pnas.1210790109
  • Peer Reviewed
• [Journal Article] ENDOR Evidence of Electron-H_2 Interaction in a Fulleride Embedding H_2 (2012)
  • Author(s): Zoleo, A.; Lawler, R.; Lei, X.; Li, Y.; Murata, Y.; Komatsu, K.; Valentin, M. D.; Ruzzi, M.; Turro, N. J
  • Journal Title: J. Am. Chem. Soc Volume: 134 Issue: 31 Pages: 12881-12884
  • DOI: 10.1021/ja305704n
  • Peer Reviewed
• [Journal Article] Planarized Triarylboranes : Stabilization by Structural Constraint and Their Plane-to-Bowl Conversion (2012)
  • Author(s): Zhiguo Zhou, Atsushi Wakamiya, Tomokatsu Kushida, Shigehiro Yamaguchi
  • Journal Title: Journal of The American Chemical Society Volume: 134 Issue: 10 Pages: 4529-4532
  • DOI: 10.1021/ja211944q
  • Peer Reviewed
• [Journal Article] Comparison of Nuclear Spin Relaxation of H2O@C60 and H2@C60 and Their Nitroxide Derivatives (2012)
  • Author(s): Li, Y.; Chen, J.; Lei, X.; Lawler, R.; Murata, Y.; Komatsu, K.; Turro, N.
  • Journal Title: J. Phys. Chem. Lett. Volume: 3 Issue: 9 Pages: 1165-1168
  • DOI: 10.1021/jz3002794
  • Peer Reviewed
• [Journal Article] A Single Molecule of Water Encapsulated in Fullerene C_<60> (2011)
  • Author(s): Kurotobi, K.; Murata, Y
  • Journal Title: Science Volume: 333 Issue: 6042 Pages: 613-616
  • DOI: 10.1126/science.1206376
  • Peer Reviewed
• [Journal Article] Modification of the σ-framework of [60]fullerene for bulk-heterojunction solar cells (2011)
  • Author(s): 村田理尚
  • Journal Title: Chemical Communications Volume: 47巻 Issue: 26 Pages: 7335-7337
  • DOI: 10.1039/c1cc12406d
  • Peer Reviewed
• [Journal Article] A Photochemical On-Off Switch for Tuning the Equilibrium Mixture of H_2 Nuclear Spin Isomers as a Function of Temperature (2011)
  • Author(s): Frunzi, M.; Jockusch, S.; Chen, J. Y.-C.; Calderon, R. K.; Lei, X.; Murata, Y.; Komatsu, K.; Guldi, D. M.; Lawler, R. G.; Turro, N. J
  • Journal Title: J. Am. Chem. Soc Volume: 133 Issue: 36 Pages: 14232-14235
  • DOI: 10.1021/ja206383n
  • Peer Reviewed
• [Journal Article] Indirect 1H NMR Characterization of H2@C60 Nitroxide Derivatives and Their Nuclear Spin Relaxation (2011)
  • Author(s): Li, Y.; Lei, X.; Li, X.; Lawler, R. G.; Murata, Y.; Komatsu, K.; Turro, N. J.
  • Journal Title: Chem. Commun. Volume: 47 Issue: 46 Pages: 12527-12529
  • DOI: 10.1039/c1cc15149e
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Bispyrrolidine Derivatives of H2@C60 : Differentiation of Isomers using 1H NMR Spectroscopy of Endohedral H2 (2011)
  • Author(s): Li, Y.; Lei, X.; Lawler, R.G.; Murata, Y.; Komatsu, K.; Turro, N.J.
  • Journal Title: Chem.Commun. Volume: 47 Pages: 2282-2284
  • Peer Reviewed
• [Journal Article] Microwave-Accelerated Ruthenium Catalyzed [2+2] Cycloadditions of Dimethylacetylene Dicarboxylate with Norbornenes (2011)
  • Author(s): Margetic, D.; Troselj, P.; Murata, Y.
  • Journal Title: Synthetic Commun. Volume: 41 Pages: 1239-1246
  • Peer Reviewed
• [Journal Article] Domino Diels-Alder Reactions of N-Methoxyethyl-7-oxanorbornadiene-2,3-dicarboximide : an Elusive, Highly Reactive Dienophile (2011)
  • Author(s): Margetic, D.; Butler, D.N.; Warrener, R.N.; Murata, Y.
  • Journal Title: Tetrahedron Volume: 67 Pages: 1580-1588
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of the Fullerene-Terthiophene Dyads (2011)
  • Author(s): Han, A.; Bai, J.; Murata, Y.; Komatsu, K.
  • Journal Title: Heteroatom Chem. Volume: 22 Pages: 72-78
  • Peer Reviewed
• [Journal Article] Manganese (III) Acetate-mediated Radical Reaction of [60] Fullerene with Phosphonate Esters Affording Unprecedented Separable Singly-bonded [60]Fullerene Dimers (2011)
  • Author(s): Wang, G.-W.; Wang, C.-Z.; Zhu, S.-E.; Murata, Y.
  • Journal Title: Chem.Commun. Volume: 47 Pages: 6111-6113
  • Peer Reviewed
• [Journal Article] Distance-dependent Para-H2→Ortho-H2 Conversion in H2@C60 Derivatives Covalently Linked to a Nitroxide Radical (2011)
  • Author(s): Li, Y.; Lei, X.-G.; Lawler, R.; Murata, Y.; Komatsu, K.; Turro, N
  • Journal Title: J.Phys.Chem.Lett. Volume: 2 Pages: 741-744
  • Peer Reviewed
• [Journal Article] Synthesis of Bis-peptides Attached on Poly [n] norbornane Molecular Scaffolds with Well-defined Relative Positions and Distances (2011)
  • Author(s): Shang, M.; Warrener, R.N.; Butler, D.N.; Murata, Y.; Margetic, D.
  • Journal Title: Mol.Divers. Volume: 15 Pages: 541-560
  • Peer Reviewed
• [Journal Article] S Modification of σ-Framework of [60] Fullerene for Bulk-heterojunction Solar Cells (2011)
  • Author(s): Murata, M.; Morinaka, Y.; Murata, Y.; Yoshikawa, O.; Sagawa, T.; Yoshikawa, S.
  • Journal Title: Chem.Commun. Volume: 47 Pages: 7335-7337
  • Peer Reviewed
• [Journal Article] A Photochemical On-Off Switch for Tuning the Equilibrium Mixture of H2 Nuclear Spin Isomers as a Function of Temperature (2011)
  • Author(s): Frunzi, M.; Jockusch, S.; Chen, J.Y.-C.; Calderon, R.K.; Lei, X.; Murata, Y.; Komatsu, K.; Guldi, D.M.; Lawler, R.G.; Turro, N.J.
  • Journal Title: J.Am.Chem.Soc. Volume: 133 Pages: 14232-14235
  • Peer Reviewed
• [Journal Article] Infrared Spectroscopy of Endohedral HD and D2 in C60 (2011)
  • Author(s): Ge, M.; Nagel, U.; Huvonen, D.; Room, T.; Mamone, S.; Levitt, M.; Carravetta, M.; Murata, Y.; Komatsu, K.; Lei, X.; Turro, N.
  • Journal Title: J.Chem.Phys. Volume: 135
  • Peer Reviewed
• [Journal Article] A Magnetic Switch for Spin Catalyzed Interconversion of Nuclear Spin Isomers (2010)
  • Author(s): Li, Y.; Lei, X.; Jockusch, S.; Chen, J. Y.-C.; Frunzi, M.; Johnson, J. A. ; Lawler, R. G.; Murata, Y.; Murata, M.; Komatsu, K.; Turro, N
  • Journal Title: J. Am. Chem. Soc Volume: 132 Issue: 12 Pages: 4042-4043
  • DOI: 10.1021/ja910282p
  • Peer Reviewed
• [Journal Article] The Spin Chemistry and Magnetic Resonance of H_2@C_<60>. From the Pauli Principle to Trapping a Long Lived Nuclear Excited Spin State Inside a Buckyball (2010)
  • Author(s): Turro, N.; Chen, J. Y.-C.; Satori, E.; Ruzzi, M.; Marti, A.; Lawler, R.; Jockusch, S.; Lopez-Gejo, J.; Komatsu, K.; Murata, Y
  • Journal Title: Acc. Chem. Res Volume: 43 Issue: 2 Pages: 335-345
  • DOI: 10.1021/ar900223d
  • Peer Reviewed
• [Journal Article] Rational Synthesis, Enrichment, and 13C NMR Spectra of Endohedral C60 and C70 Encapsulating a Helium Atom, Morinaka (2010)
  • Author(s): Y.; Tanabe, F.; Murata, M.; Murata, Y.; Komatsu, K.
  • Journal Title: Chem.Commun. 46 Pages: 4532-4534
• [Journal Article] A Magnetic Switch for Spin Catalyzed Interconversion of Nuclear Spin Isomers, Li (2010)
  • Author(s): Y.; Lei, X.; Jockusch, S.; Chen, J.Y.-C.; Frunzi, M.; Johnson, J.A.; Lawler, R.G.; Murata, Y.; Murata, M.; Komatsu, K. ; Turro, N.
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 4042-4043
• [Journal Article] The Spin Chemistry and Magnetic Resonance of H2@C60. From the Pauli Principle to Trapping a Long Lived Nuclear Excited Spin State Inside a Buckyball (2010)
  • Author(s): Turro, N.; Chen, J.Y.-C.; Satori, E.; Ruzzi, M.; Marti, A.; Lawler, R.; Jockusch, S.; Lopez-Gejo, J.; Komatsu, K.; Murata, Y.
  • Journal Title: Acc.Chem.Res. 43 Pages: 335-345
  • Peer Reviewed
• [Journal Article] A Magnetic Switch for Spin Catalyzed Interconversion of Nuclear Spin Isomers (2010)
  • Author(s): Li, Y.; Lei, X.; Jockusch, S.; Judy, C.; Frunzi, M.; Johnson, J.; Lawler, R.; Murata, Y.; Murata, M.; Komatsu, K.; Turro, N.
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 4042-4043
  • Peer Reviewed
• [Journal Article] Rotational Sub-level of Ortho-Hydrogen Molecule Encapsulated in Isotropic C60 Fullerene Cages (2009)
  • Author(s): Yoshimitsu Kohama, Takeshi Rachi, Ju Jing, Zhaofei Li, Jun Tang, Ryotaro Kumashiro, Satoru Izumisawa, Hitoshi Kawaji, Tooru Atake, Hiroshi Sawa, Yasujiro Murata, Koichi Komatsu, and Katsumi Tanigaki
  • Journal Title: Phys. Rev. Lett Volume: 103 Issue: 7 Pages: 73001-73001
  • DOI: 10.1103/physrevlett.103.073001
  • Peer Reviewed
• [Journal Article] Quantum Translator-Rotator: Inelastic Neutron Scattering of Dihydrogen Molecules Trapped inside Anisotropic Fullerene Cages (2009)
  • Author(s): Horsewill,A. J.; Panesar, K. S.; Rols, S.; Johnson, M. R.; Murata, Y.; Komatsu, K.; Mamone, S.; Danquigny, A.; Cuda, F.; Maltsev, S.; Grossel, M. C.; Carravetta, M.; Levitt, M. H
  • Journal Title: Phys. Rev. Lett Volume: 102 Issue: 1
  • DOI: 10.1103/physrevlett.102.013001
  • Peer Reviewed
• [Journal Article] Quantum Translator-Rotator : Inelastic Neutron Scattering of Dihydrogen Molecules Trapped inside Anisotropic Fullerene Cages (2009)
  • Author(s): A.J. ; Panesar, K.S. ; Rols, S. ; Johnson, M.R. ; Murata, Y. ; Komatsu, K. ; Mamone, S. ; Danquigny, A. ; Cuda, F. ; Maltsev, S. ; Grossel, M.C. ; Carravetta, M. ; Levitt, M.H.
  • Journal Title: Horsewill, Phys.Rev.Lett. 102
• [Journal Article] Rigid Alicyclic Molecules from Bicyclo[2.2.1]hept-2-enes (=8,9,10-Trinorbornenes) and 1,4-Dipyridin-2-ylphthalazines as Stereoselective Coupling Agents (2009)
  • Author(s): Margetic, D.; Murata, Y.; Komatsu, K.; Marinic, Z.
  • Journal Title: Helv.Chim.Acta 92 Pages: 298-312
  • Peer Reviewed
• [Journal Article] Quantum Translator-Rotator : Inelastic Neutron Scattering of Dihydrogen Molecules Trappedinside Anisotropic Fullerene Cages (2009)
  • Author(s): Horsewill, A.J.; Panesar, K.S.; Rols, S.; Johnson,- M.R.; Murata, Y.; Komatsu, K.; Mamone, S.; Danquigny, A.; Cuda, F.; Maltsev, S.; Grossel, M.C.; Carravetta, M.; Levitt, M.H.
  • Journal Title: Phys.Rev.Lett. 102
  • Peer Reviewed
• [Journal Article] Rotor in a Cage : Infrared Spectroscopy of an Endohedral Hydrogen-fullerene Complex (2009)
  • Author(s): Mamone, S.; Ge, M.; Huevonen, D.; Nagel, U.; Danquigny, A.; Cuda, F.; Grossel, M.C.; Murata, Y.; Komatsu, K.; Levitt, M.H.; Room, T.; Caravetta, M.
  • Journal Title: J.Chem.Phys. 130
  • Peer Reviewed
• [Journal Article] Rotational Sublevels of an Ortho-Hydrogen Molecule Encapsulated in an Isotropic C60 Cage (2009)
  • Author(s): Kohama, Y.; Rachi, T.; Jing, J.; Li, Z.; Tang, J.; Kumashiro, R.; Izumisawa, S.; Kawaji, H.; Atake, T.; Sawa, H.; Murata, Y.; Komatsu, K.; Tanigaki, K.
  • Journal Title: Phys.Rev.Lett. 103
  • NAID: 120002086073
  • Peer Reviewed
• [Journal Article] Reaction of Cage-Opened Fullerene Derivative with Grignard Reagents and Subsequent Transannular Cyclization (2009)
  • Author(s): Murata, M.; Morinaka, Y.; Kurotobi, K.; Komatsu, K.; Murata, Y.
  • Journal Title: Chem.Lett. 39 Pages: 298-299
  • NAID: 10027178725
  • Peer Reviewed
• [Journal Article] Synthesis and Reaction of Fullerene C_<70> Encapsulating Two Molecules of H_2 (2008)
  • Author(s): Murata, M.; Maeda, S.; Morinaka, Y.; Murata, Y.; Komatsu, K
  • Journal Title: J. Am. Chem. Soc Volume: 130 Issue: 47 Pages: 15800-15801
  • DOI: 10.1021/ja8076846
  • Peer Reviewed
• [Journal Article] Encapsulation and Dynamic Behavior of Two H_2 Molecules in an Open-Cage C_<70> (2008)
  • Author(s): Murata, Y.; Maeda, S.; Murata, M.; Komatsu, K
  • Journal Title: J. Am. Chem. Soc Volume: 130 Issue: 21 Pages: 6702-6703
  • DOI: 10.1021/ja801753m
  • Peer Reviewed
• [Journal Article] Encapsulation and Dynamic Behavior of Two H2 Molecules in an Open-Cage C70 (2008)
  • Author(s): Murata, Y. ; Maeda, S. ; Murata, M. ; Komatsu, K.
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 6702-6703
• [Journal Article] Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2 (2008)
  • Author(s): Murata, M. ; Maeda, S. ; Morinaka, Y. ; Murata, Y. ; Komatsu, K.
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 15800-15801
• [Journal Article] Paramagnet Enhanced Nuclear Relaxation of H2 in Organic Solvents and in H2@C60 (2008)
  • Author(s): Sartori, E. ; Ruzzi, M. ; Turro, N. J. ; Komatsu, K. ; Murata, Y. ; Lawler, R. G. ; Buchachenko, A. L.
  • Journal Title: J. Am. Chem. Soc 130 Pages: 2221-2225
  • Peer Reviewed
• [Journal Article] Encapsulation and Dynamic Behavior of Two H2 Molecules in an Open-Cage C70 (2008)
  • Author(s): Murata, Y. ; Maeda, S. ; Murata, M. ; Komatsu, K.
  • Journal Title: J. Am. Chem. Soc 130 Pages: 6702-6703
  • Peer Reviewed
• [Journal Article] Demonstration of a Chemical Transformation Inside a Fullerene. The Reversible Conversion of th e Allotropes of H2@C60 (2008)
  • Author(s): Tun-o, N. J. ; Marti, A. A. ; Chen, J. Y.-C. ; Jockusch, S. ; Lawler, R. G. ; Ruzzi, M. ; Satori, E. ; Chuang, S.-C. ; Komatsu, K. ; Murata, Y.
  • Journal Title: J. Am. Chem. Soc 130 Pages: 10506-10507
  • Peer Reviewed
• [Presentation] ヘリウム原子と窒素原子を内包したフラーレンの発生 (2013)
  • Author(s): 森中裕太、佐藤悟、若宮淳志、二川秀史、溝呂木直美、田辺史行、村田理尚、小松紘一、古川貢、加藤立久、永瀬茂、赤阪健、村田靖次郎
  • Organizer: 新学術領域研究「高次π空間の創発と機能開発」第９回公開シンポジウム
  • Place of Presentation: シーサイドホテル舞子ビラ神戸
  • Year and Date: 2013-03-13
• [Presentation] フラーレンを用いた基礎科学、材料化学 (2012)
  • Author(s): 村田靖次郎
  • Organizer: 岡山大学大学院自然科学研究科講演会
  • Place of Presentation: 工学部1号館第2講義室、岡山大学
  • Year and Date: 2012-09-25
• [Presentation] 17員環開口部をもつ新規フラーレン誘導体の合成と性質 (2012)
  • Author(s): 桜井悠子、二子石師、村田理尚、黒飛敬、若宮淳志、村田靖次郎
  • Organizer: 新学術領域研究「高次π空間の創発と機能開発」第８回公開シンポジウム
  • Place of Presentation: ホテルアローレ、加賀
  • Year and Date: 2012-07-19
• [Presentation] Synthesis of Endohedral C60 Encapsulating a Water Molecule (2012)
  • Author(s): Yasujiro Murata, Kei Kurotobi, Tomoko Nishida
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Obaku Plaza, Kyoto University
  • Year and Date: 2012-05-20
• [Presentation] 水分子内包フラーレンの合成 (2012)
  • Author(s): 村田靖次郎
  • Organizer: 熊本大学拠点形成B「ソフト溶液プロセスをベースとした階層的ナノ組織集積材料の創成」特別講演会「ナノ構造制御された高次構造体の新展開」
  • Place of Presentation: 熊本大学工学部
  • Year and Date: 2012-01-27
• [Presentation] 小分子内包フラーレンの有機合成 (2012)
  • Author(s): 村田靖次郎
  • Organizer: 奈良先端未来開拓コロキウム2012～分子、超分子から分子技術の時代へ～
  • Place of Presentation: 学際融合領域研究棟1号館1階「交流・カンファレンスルーム」、奈良先端科学技術大学院大学、奈良
• [Presentation] 17員環開口部をもつ新規フラーレン誘導体の合成と性質 (2012)
  • Author(s): 桜井悠子、村田理尚、黒飛敬、若宮淳志、村田靖次郎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学日吉キャンパス・矢上キャンパス
• [Presentation] 水素結合をもたない水単分子の実現 (2011)
  • Author(s): 村田靖次郎
  • Organizer: 第26回有機合成化学研究所講演会
  • Place of Presentation: 京都大学桂キャンパス
  • Year and Date: 2011-11-24
• [Presentation] フラーレンの構造変換に関する研究 (2011)
  • Author(s): 村田靖次郎
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場
• [Presentation] Organic Synthesis of Endohedral C60 Encapsulating a Water Molecule (2011)
  • Author(s): Yasujiro Murata, Kei Kurotobi
  • Organizer: 14th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: Eugene, Oregon, USA
• [Presentation] 水を内包したフラーレンC60の有機合成 (2011)
  • Author(s): 村田靖次郎、黒飛敬
  • Organizer: 第2回統合物質シンポジウム
  • Place of Presentation: 名古屋大学
• [Presentation] A Single Molecule of Water Encapsulated in Fullerene C60 (2011)
  • Author(s): Yasujiro Murata
  • Organizer: 3rd International Symposium on Emergence of Highly Elaborated Pi-Space and Its Function
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Organic Synthesis of Endohedral Fullerenes (2011)
  • Author(s): Yasujiro Murata
  • Organizer: Japan-Taiwan Joint Symposium on Organic Chem istryramolecular Architectures
  • Place of Presentation: Kyoto University
• [Presentation] Organic Synthesis of Endohedral Fullerenes (2010)
  • Author(s): Yasujiro Murata
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, USA (invited)
  • Year and Date: 2010-12-15
• [Presentation] σ-Framework Transformation of Fullerenes (2010)
  • Author(s): Yasujiro Murata
  • Organizer: Fullerene Silver Anniversary Symposium
  • Place of Presentation: Crete, Greece (invited)
  • Year and Date: 2010-10-09
• [Presentation] Synthesis of Endohedral Fullerenes Encapsulating a Small Molecule (2010)
  • Author(s): Yasujiro Murata
  • Organizer: The 1st China-Japan Young Scientist Forum
  • Place of Presentation: Xiamen, China (invited)
  • Year and Date: 2010-06-20
• [Presentation] Organic Synthesis of an Endohedral C60 Encapsulating a Small (2010)
  • Author(s): Molecule, Kei Kurotobi, Yasujiro Murata
  • Organizer: 217th ECS Meeting
  • Place of Presentation: Vancouver, Canada (invited)
  • Year and Date: 2010-04-28
• [Presentation] 水分子内包フラーレンC60の有機合成 (2010)
  • Author(s): 黒飛敬、村田靖次郎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-28
• [Presentation] チオフェンをもつ新規π共役拡張型開口フラーレンの合成 (2010)
  • Author(s): 保井秀文、黒飛敬、村田靖次郎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-28
• [Presentation] グリニャール試薬を用いた開口フラーレンの構造変換 (2010)
  • Author(s): 森中裕太、村田理尚、黒飛敬、小松紘一、村田靖次郎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-28
• [Presentation] フラーレンC70の二価アニオン種の発生と骨格内の磁気的性質 (2010)
  • Author(s): 登政博、村田理尚、小松紘一、村田靖次郎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-28
• [Presentation] ピロール環が直結したアザフラーレン誘導体の合成と性質 (2010)
  • Author(s): 勝谷郷史、村田理尚、村田靖次郎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-28
• [Presentation] 小分子内包フラーレンの有機合成 (2010)
  • Author(s): 村田靖次郎
  • Organizer: 第38回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名城大学 依頼講演
  • Year and Date: 2010-03-03
• [Presentation] Organic Synthesis of Endofullerenes Encapsulating a Small Molecule (2010)
  • Author(s): Yasujiro Murata
  • Organizer: The 38th Fullerenes-Nanotube General Symposium
  • Place of Presentation: 名城大学
  • Year and Date: 2010-03-03
• [Presentation] Organic Synthesis of Endohedral Fullerenes (2010)
  • Author(s): Yasujiro Murata
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, Hawaii
• [Presentation] σ-Framework Transformation of Fullerenes (2010)
  • Author(s): Yasujiro Murata
  • Organizer: Fullerene Silver Anniversary Symposium
  • Place of Presentation: Crete, Greece
• [Presentation] Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2 (2009)
  • Author(s): Michihisa Murata, Shuhei Maeda, Yuta Morinaka, Yasujiro Murata, Koichi Komatsu
  • Organizer: The 11th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-11)
  • Place of Presentation: Rihga Royal Hotel Kyoto
  • Year and Date: 2009-11-12
• [Presentation] Synthesis and Properties of Novel Open-Cage C60 Derivatives (2009)
  • Author(s): Kei Kurotobi, Michihisa Murata, Yasujiro Murata
  • Organizer: The 11th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-11)
  • Place of Presentation: Rihga Royal Hotel Kyoto
  • Year and Date: 2009-11-12
• [Presentation] 水素分子を2個内包したフラーレンC70の[4+2]環化付加反応 (2009)
  • Author(s): 森中裕太、村田理尚、村田靖次郎、小松紘一
  • Organizer: 第20回基礎有機化学討論会
  • Place of Presentation: 群馬大学工学部桐生キャンパス
  • Year and Date: 2009-09-29
• [Presentation] Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2 (2009)
  • Author(s): Michihisa Murata, Shuhei Maeda, Yuta Morinaka, Yasujiro Murata, Koichi Komatsu
  • Organizer: 第37回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: つくば国際会議場
  • Year and Date: 2009-09-03
• [Presentation] Synthesis and Properties of Novel Open-Cage C60 Derivatives (2009)
  • Author(s): Kei Kurotobi, Michihisa Murata, Yasujiro Murata
  • Organizer: 第37回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: つくば国際会議場
  • Year and Date: 2009-09-03
• [Presentation] 水素分子を2個内包したフラーレンC70フラーレンC70の[4+2]環化付加反応 (2009)
  • Author(s): 森中裕太、村田理尚、村田靖次郎、小松紘一
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学船橋キャンパス
  • Year and Date: 2009-03-27
• [Presentation] 水素結合をもたない水単分子の実現
  • Author(s): 村田靖次郎
  • Organizer: 第２６回有機合成化学研究所講演会
  • Place of Presentation: 京都大学桂キャンパス
  • Invited
• [Book] 分子内包フラーレンのπ電子科学, CSJカレントレビュー「未来材料を創出するπ電子系の科学」 (2013)
  • Author(s): 村田靖次郎
  • Publisher: 化学同人
• [Book] 活性小分子の内包された球状π空間の創製と物性制御, 高次π空間の創発と機能開発 (2013)
  • Author(s): 村田靖次郎
  • Publisher: シーエムシー出版
• [Book] Molecular Surgery toward Organic Synthesis of Endohedral Fullerenes, Chemistry of Nanocarbons, F. Wudl, S. Nagase, T. Akasaka, Eds (2010)
  • Author(s): Michihisa Murata, Yasujiro Murata, Koichi Komatsu
  • Publisher: Wiley-Blackwell, Oxford
• [Book] Chemistry of Nanocarbons(Molecular Surgery toward Organic Synthesis of Endohedral Fullerenes)(F.Wudl, S.Nagase, T.Akasaka, Eds.) (2010)
  • Author(s): Michihisa Murata, Yasujiro Murata, Koichi Komatsu
  • Publisher: Wiley-Blackwell, Oxford
• [Remarks]
  • URL: http://www.scl.kyoto-u.ac.jp/~kouzou/index.html
• [Patent(Industrial Property Rights)] Novel Open-cage Fullerenes and a Method for Preparing the Same (2012)
  • Inventor(s): Yasujiro Murata, Michihisa Murata, Atsushi Wakamiya
  • Industrial Property Rights Holder: Kyoto University
  • Filing Date: 2012-03-05
  • Overseas