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Sequence Control of π-Electronic Compounds

Planned Research

Project AreaEmergence of highly elaborated pai-space and its function
Project/Area Number 20108008
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionNational Institute for Materials Science

Principal Investigator

TASHIRO Kentaro  独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (40332598)

Project Period (FY) 2008 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥27,820,000 (Direct Cost: ¥21,400,000、Indirect Cost: ¥6,420,000)
Fiscal Year 2012: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2011: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2010: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2009: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2008: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Keywords異種多核金属錯体 / ペプチド固相合成 / 強磁性 / ヘテロジャンクション / 自己組織化 / ナノ材料 / シークエンス / π電子化合物 / 金属ポルフィリン / ターピリジン / 固相合成 / フラーレン
Research Abstract

The project focused on how to create novel methodologies to control the sequences of π-electronic molecules and apply them for several purposes. Representative fruits from this trial are such as new molecular design strategies for the spontaneous production of pn-heterojunctions or organic liquid crystalline semiconductors, spin sequence that exhibits ferromagnetic/ferrimagnetic switching, control of the molecular packing pattern by means of π-electronic surfaces, and solid-phase synthesis of π-electronic metal complex arrays.

Report

(7 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (59 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (17 results) (of which Peer Reviewed: 16 results) Presentation (29 results) Book (8 results) Remarks (2 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Selective Supramolecular Fullerene-Porphyrin Interactions and Switching in Surface-Confined C_<60>-Ce(TPP)_2 Dyads,2012

    • Author(s)
      S. Vijayaraghavan, D. Ecija, W. Auwarter, S. Joshi, K. Seufert, A. P. Seitsonen, K. Tashiro, J. V. Barth
    • Journal Title

      Nano Letters

      Volume: 12 Pages: 4077-4083

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Isomers of Metal-Organic Complex Arrays2012

    • Author(s)
      A. M. Fracaroli, K. Tashiro, O. M. Yaghi
    • Journal Title

      Inorg. Chem.

      Volume: 51 Pages: 6437-6439

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective Supramolecular Fullerene-Porphyrin Interactions and Switching in Surface-Confined C60-Ce(TPP)2 Dyads2012

    • Author(s)
      S. Vijayaraghavan, *D. &#201;cija, *W. Auw&#228;rter, S. Joshi, K. Seufert, A. P. Seitsonen, K. Tashiro, J. V. Barth
    • Journal Title

      Nano Letters

      Volume: 12 Issue: 8 Pages: 4077-4083

    • DOI

      10.1021/nl301534p

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Spin Coupling between Endohedral Metallofullerene La@C_<82> and a Cyclodimeric Copper Porphyrin upon Inclusion2011

    • Author(s)
      F. Hajjaj, K. Tashiro, H. Nikawa, N. Mizorogi, T. Akasaka, S. Nagase, K. Furukawa, T. Kato, T. Aida
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133 Pages: 9290-9292

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electron- or Hole-Transporting Nature Selected by Side-Chain-Directed π-Stacking Geometry: Liquid Crystalline Fused Metalloporphyrin Dimers2011

    • Author(s)
      T. Sakurai, K. Tashiro, Y. Honsho, A. Saeki, S. Seki, A. Osuka, A. Muranaka, M. Uchiyama, J. Kim, S. Ha, K. Kato, M. Takata, T. Aida
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133 Pages: 6537-6540

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Assembly and Manipulation of Rotatable Cerium Porphyrinato Sandwich Complexes on a Surface2011

    • Author(s)
      D. Ecija, W. Auwarter, S. Vijayaraghavan, K. Seufert, F. Bischoff, K. Tashiro, J. V. Barth
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 50 Pages: 3872-3877

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Metal-Organic Complex Arrays2011

    • Author(s)
      P. Vairaprakash, H. Ueki, K. Tashiro, O. M. Yaghi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133 Pages: 759-761

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Assembly and Manipulation of Rotatable Cerium Porphyrinato Sandwich Coraplexes on a Surface2011

    • Author(s)
      D.Ecija, W.Auwarter, S.Vijayaraghavan, K.Seufert, F.Bischoff, K.Tashiro, J.V.Barth
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50 Issue: 17 Pages: 3872-3877

    • DOI

      10.1002/anie.201007370

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron- or Hole-Transporting Nature Selected by Side-Chain-Directed π-stacking Geometry : Liquid Crystalline Fused Metalloporphyrin Dimers2011

    • Author(s)
      Tsuneaki Sakurai, Kentaro Tashiro, Yoshihito Honsho, Akinori Saeki, Shu Seki, Atsuhiro Osuka, Atsuya Muranaka, Masanobu Uchiyama, Jungeun Kim, Sunyeo Ha, Kenichi Kato, Masaki Takata, Takuzo Aida
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Issue: 17 Pages: 6537-6540

    • DOI

      10.1021/ja201272t

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Spin Coupling between Endohedral Metallofullerene La@C_<82> and a Cyclodimeric Copper Porphyrin upon Inclusion2011

    • Author(s)
      F.Hajjaj, K.Tashiro, H.Nikawa, N.Mizorogi, T.Akasaka, S.Nagase, K.Furukawa, T.Kato, T.Aida
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 24 Pages: 9290-9292

    • DOI

      10.1021/ja203491s

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron-or Hole-Transporting Nature Selected by Side-Chain-Directedπ-Stacking Geometry : Liquid Crystalline Fused Metalloporphyrin Dimers2011

    • Author(s)
      T.Sakurai, K.Tashiro, Y.Honsho, A.Saeki, S.Seki, A.Osuka, A.Muranaka, M.Uchiyama, J.Kim, S.Ha, K.Kato, M.Takata, T.Aida
    • Journal Title

      J.Am.Chem.Soc. 133

      Pages: 6537-6540

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Assembly and Manipulation of Rotatable Cerium Porphyrinato Sandwich Complexes on a Surface2011

    • Author(s)
      D.Ecija, W.Auwarter, S.Vijayaraghavan, K.Seufert, F.Bischoff, K.Tashiro, J.V.Barth
    • Journal Title

      Angew.Chem.Int.Ed. 50

      Pages: 3872-3877

    • Related Report
      2010 Self-evaluation Report
  • [Journal Article] Synthesis of Metal-Organic Complex Arrays2011

    • Author(s)
      P.Vairaprakash, H.Ueki, K.Tashiro, O.M.Yaghi
    • Journal Title

      J.Am.Chem.Soc. 133

      Pages: 759-761

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Metal-Organic Complex Arrays2011

    • Author(s)
      P.Vairaprakash, H.Ueki, K.Tashiro, O.M.Yaghi
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Pages: 759-761

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiroselective Assembly of a Chiral Porphyrin-Fullerene Dyad: Photoconductive Nanofiber with a Top-class Ambipolar Charge-Carrier Mobility2010

    • Author(s)
      Y. Hizume, K. Tashiro, R. Charvet, Y. Yamamoto, A. Saeki, S. Seki, T. Aida
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 132 Pages: 6628-6629

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiroselective Assembly of a Chiral Porphyrin-Fullerene Dyad : Photoconductive Nanofiber with a Top-class Ambipolar Charge-Carrier Mobility2010

    • Author(s)
      Y.Hizume, K.Tashiro, R.Charvet, Y.Yamamoto, A.Saeki, S.Seki, T.Aida
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 6628-6629

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Chiroselective Assembly of a Chiral Porphyrin-Fullerene Dyad : Photoconductive Nanofiber with a Top-class Ambipolar Charge-Carrier Mobility2010

    • Author(s)
      Y.Hizume, K.Tashiro, R.Charvet, Y.Yamamoto, A.Saeki, S.Seki, T.Aida
    • Journal Title

      Journal of the American Chemical Society

      Volume: 132 Pages: 6628-6629

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Networking of Metal Complexes2013

    • Author(s)
      K. Tashiro
    • Organizer
      Second International Workshop on Advanced Functional Nanomaterials
    • Place of Presentation
      Chennai, India
    • Year and Date
      2013-01-29
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Networking of Metal Complexes2012

    • Author(s)
      K. Tashiro
    • Organizer
      International Conference on Emerging Advanced Nanomaterials
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      2012-10-24
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Sequential Isomers of Metal-Organic Complex Arrays2012

    • Author(s)
      K. Tashiro
    • Organizer
      MANA International Symposium 2012
    • Place of Presentation
      Tsukuba
    • Year and Date
      2012-03-01
    • Related Report
      2012 Final Research Report
  • [Presentation] Sequential Isomers of Metal-Organic Complex Arrays2012

    • Author(s)
      K.Tashiro
    • Organizer
      the MANA International Symposium 2012
    • Place of Presentation
      エポカルつくば(茨城県)(招待講演)
    • Year and Date
      2012-03-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Challenges at Boundaries2011

    • Author(s)
      K. Tashiro
    • Organizer
      1st International Symposium on Creation of Functional Materials
    • Place of Presentation
      Tsukuba
    • Year and Date
      2011-12-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Challenges at Boundaries2011

    • Author(s)
      K.Tashiro
    • Organizer
      1st International Symposium on Creation of Functional Materials
    • Place of Presentation
      筑波大学大学会館国際会議室(茨城県)(招待講演)
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Networking of Metal Complexes2011

    • Author(s)
      K.Tashiro
    • Organizer
      The International Conference on Advanced Materials and Nanotechnology for Sustainable Development
    • Place of Presentation
      Kathmandu, Nepal(招待講演)
    • Year and Date
      2011-10-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Networking of Metal Complexes2011

    • Author(s)
      K. Tashiro
    • Organizer
      The International Conference on Advanced Materials and Nanotechnology for Sustainable Development
    • Place of Presentation
      Kathmandu, Nepal
    • Year and Date
      2011-08-23
    • Related Report
      2012 Final Research Report
  • [Presentation] Solid Phase Synthesis of Metal-Organic Complex Arrays2011

    • Author(s)
      K.Tashiro
    • Organizer
      ACS 241st National Meeting
    • Place of Presentation
      Anaheim, USA
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Metal-Organic Complex Arrays2011

    • Author(s)
      K. Tashiro
    • Organizer
      VNUHCM-UCLA MOF Symposium
    • Place of Presentation
      Ho Chi Minh City, Viet Nam
    • Year and Date
      2011-03-21
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Metal-Organic Complex Arrays2011

    • Author(s)
      K.Tashiro
    • Organizer
      VNUHCM-UCLA MOF Symposium
    • Place of Presentation
      Ho Chi Minh City, Viet Nam.
    • Year and Date
      2011-03-21
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] MOCAs2011

    • Author(s)
      K. Tashiro
    • Organizer
      MANA International Symposium 2011
    • Place of Presentation
      Tsukuba
    • Year and Date
      2011-03-02
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] MANA2011

    • Author(s)
      MOCAs, K.Tashiro
    • Organizer
      International Symposium 2011
    • Place of Presentation
      Tsukuba
    • Year and Date
      2011-03-02
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Precise Control of Supramolecular Interactions between Fullerenes and Metalloporphyrins: Applications for Molecular and Materials Sciences of Carbon Nanoclusters2010

    • Author(s)
      K. Tashiro
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-16
    • Related Report
      2012 Final Research Report
  • [Presentation] Precise Control of Supramolecular Interactions between Fullerenes and Metalloporphyrins : Applications for Molecular and Materials Sciences of Carbon Nanoclusters2010

    • Author(s)
      K.Tashiro
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] Host-Guest Chemistry for the Separation of Fullerenes2010

    • Author(s)
      K. Tashiro
    • Organizer
      Fullerene Silver Anniversary Symposium
    • Place of Presentation
      Hersonissos, Greece
    • Year and Date
      2010-10-09
    • Related Report
      2012 Final Research Report 2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] Supramolecular Chemistry of Metal Bisporphyrinate Double-Decker Complexes with Fullerenes2010

    • Author(s)
      K. Tashiro
    • Organizer
      Sixth International Conference on Porphyrins and Phthalocyanines
    • Place of Presentation
      Santa Ana Pueblo, USA
    • Year and Date
      2010-07-08
    • Related Report
      2012 Final Research Report 2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] 固相合成を用いた金属錯体アレイの構築2010

    • Author(s)
      田代健太郎
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] シークエンスの制御と金属錯体2010

    • Author(s)
      田代健太郎
    • Organizer
      09-2超分子研究会
    • Place of Presentation
      慶応大学
    • Year and Date
      2010-01-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Novel Approaches for Sequence Control in Covalent and Supramolecular Arrays2009

    • Author(s)
      K. Tashiro
    • Organizer
      International Conference on Polymers and Advanced Materials
    • Place of Presentation
      Huatulco, Mexico
    • Year and Date
      2009-11-23
    • Related Report
      2012 Final Research Report 2010 Self-evaluation Report 2009 Annual Research Report
  • [Presentation] 固相合成を用いた金属イオンアレイのシークエンス制御2009

    • Author(s)
      田代健太郎
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] キラルな両親媒性ドナー・アクセプターダイアッドの自己組織化による光導電性材料の創成2009

    • Author(s)
      田代健太郎
    • Organizer
      第37回フラーレン・ナノチューブ総合シンポジウム
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2009-09-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固相合成を用いた金属イオンアレイ構築用テンプレートの設計と応用2009

    • Author(s)
      田代健太郎
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Controlled Self-Assembly of π-Electronic Moieties for Materials Engineering2009

    • Author(s)
      K. Tashiro
    • Organizer
      International Symposium for Young Organic Chemists
    • Place of Presentation
      Tsukuba
    • Year and Date
      2009-03-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Controlled Self-Assembly ofπ-Electronic Moieties for Materials Engineering2009

    • Author(s)
      K.Tashiro
    • Organizer
      International Symposium for Young Organic Chemists
    • Place of Presentation
      Tsukuba
    • Year and Date
      2009-03-06
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Controlled Self-Assembly of Jt-Electronic Moieties for Materials Engineering2009

    • Author(s)
      田代健太郎
    • Organizer
      International Symposium for Young Organic Chemists
    • Place of Presentation
      物質・材料研究機構
    • Year and Date
      2009-03-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Molecular Beyonds2009

    • Author(s)
      K. Tashiro
    • Organizer
      MANA International Symposium 2009
    • Place of Presentation
      Tsukuba
    • Year and Date
      2009-02-25
    • Related Report
      2012 Final Research Report 2010 Self-evaluation Report
  • [Presentation] Molecular Beyonds2009

    • Author(s)
      田代健太郎
    • Organizer
      MANA International Symposium 2009
    • Place of Presentation
      Tsukuba Intemational Congress Center
    • Year and Date
      2009-02-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] π電子化合物のシークエンス制御2009

    • Author(s)
      田代健太郎
    • Organizer
      新学術領域研究「高次π空間の創発と機能開発」第1回公開シンポジウム
    • Place of Presentation
      東京国際交流館
    • Year and Date
      2009-01-31
    • Related Report
      2008 Annual Research Report
  • [Book] π電子化合物のシークエンス制御2013

    • Author(s)
      田代健太郎
    • Publisher
      高次π空間の創発と機能開発
    • Related Report
      2012 Final Research Report
  • [Book] 高次π空間の創発と機能開発2013

    • Author(s)
      田代健太郎
    • Total Pages
      5
    • Publisher
      シーエムシー出版
    • Related Report
      2012 Annual Research Report
  • [Book] ポルフィリン超分子レセプタ2009

    • Author(s)
      田代健太郎
    • Publisher
      超分子サイエンス
    • Related Report
      2012 Final Research Report
  • [Book] パイ電子空間2009

    • Author(s)
      田代健太郎
    • Publisher
      ナノ空間材料の創成と応用
    • Related Report
      2012 Final Research Report
  • [Book] 超分子サイエンス(ポルフィリン超分子レセプタ)2009

    • Author(s)
      田代健太郎
    • Related Report
      2010 Self-evaluation Report
  • [Book] パイ電子空間(ナノ空間材料の創成と応用)2009

    • Author(s)
      田代健太郎
    • Related Report
      2010 Self-evaluation Report
  • [Book] 超分子サイエンス2009

    • Author(s)
      田代健太郎
    • Total Pages
      7
    • Publisher
      エヌティーエス
    • Related Report
      2009 Annual Research Report
  • [Book] ナノ空間材料の創成と応用2009

    • Author(s)
      田代健太郎
    • Total Pages
      6
    • Publisher
      フロンティア出版
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.nims.go.jp/reticular/Japanese.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属錯体アレイとその製造法及び材料2010

    • Inventor(s)
      田代 健太郎、Pothiappan Vairaprakash, 植木久憲, Omar M. Yaghi
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Filing Date
      2010-02-24
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 金属錯体アレイとその製造法及び材料2010

    • Inventor(s)
      田代健太郎、Pothiappan Vairaprakash, 植木久憲, Omar M.Yaghi
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Filing Date
      2010-02-24
    • Related Report
      2010 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 金属錯体アレイとその製造法及び材料2010

    • Inventor(s)
      田代健太郎, ポティアパンバイラプラカシュ, 植木久憲, オマールヤギ
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Number
      2010-038460
    • Filing Date
      2010-02-24
    • Related Report
      2009 Annual Research Report

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Published: 2008-04-01   Modified: 2018-03-28  

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