| Budget Amount *help |
¥54,860,000 (Direct Cost: ¥42,200,000、Indirect Cost: ¥12,660,000)
Fiscal Year 2013: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Fiscal Year 2012: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Fiscal Year 2011: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Fiscal Year 2010: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Fiscal Year 2009: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
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| Research Abstract |
On the basis of the concept of "space-and-time-integration," we developed a methodology to synthesize selectively and effciently aromatic compounds, which are difficult to obtain by conventional synthetic methods, having novel structures and electronic properties by transannular and/or tandem cyclization reactions using highly reactive acetylenic substrates having closely located alkynyl groups. In addition, the reactive intermediates generated during the course of the reactions were furhter transformed into more elaborated products in some cases. The structures, physical properties, and optoelectronic applications of newly synthesized aromatic compounds were investigated including photovoltaic applications of some products.
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