| Budget Amount *help |
¥121,680,000 (Direct Cost: ¥93,600,000、Indirect Cost: ¥28,080,000)
Fiscal Year 2013: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2012: ¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2011: ¥22,750,000 (Direct Cost: ¥17,500,000、Indirect Cost: ¥5,250,000)
Fiscal Year 2010: ¥22,230,000 (Direct Cost: ¥17,100,000、Indirect Cost: ¥5,130,000)
Fiscal Year 2009: ¥42,640,000 (Direct Cost: ¥32,800,000、Indirect Cost: ¥9,840,000)
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| Research Abstract |
Three vanadyl ring compounds, hexanuclear, heptanuclear, and octanuclear complexes, were synthesized using alpha, beta, and gamma-cyclodextrins as capping ligands. They show specific magnetic properties derived from their ring-shaped structures. The odd membered ring shows unusual magnetic steps.
Multi-bistable molecules were investigated. Hybrid systems of iron(II) spin crossover complexes and organic radicals were synthesized. Cyanide bridged Co2Fe2 square molecules were prepared, and their light- and thermally induced phase transitions were investigated.
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