| Budget Amount *help |
¥39,260,000 (Direct Cost: ¥30,200,000、Indirect Cost: ¥9,060,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2012: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2011: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2010: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
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| Research Abstract |
From an idea to create a molecular assembly with unprecedented properties, Prussian blue, one of the porous metal complexes, has been successfully incorporated in inner space of one-dimensional molecular assemblies generated in low molecular-weight gels. Tetrasubstituted ferrocene having pyridyl groups at 1,1 ', 3,3' positions was designed to form self-assembled nanotube structure with silver (I) and ions, which has a uniform diameter of about 9 nm. Once Ferrocenes in the nanotube structure were oxidized to form ferrocenium ions by adding a suitable oxidizing agent, the ring structure was cut from the tubular structure and the reverse transformation was possible by the reduction of the ferrocenium ions in the ring structure.
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