Budget Amount *help |
¥82,420,000 (Direct Cost: ¥63,400,000、Indirect Cost: ¥19,020,000)
Fiscal Year 2014: ¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2013: ¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2012: ¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2011: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2010: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
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Outline of Final Research Achievements |
In this project, we have embarked on the development of new enantioselective synthetic methods based on cleavage of C-C bonds by transition metal catalysis. For example, we have developed (1) reactions to insert unsaturated molecules into a C-C bond in an enantioselective manner, (2) methods to reconstruct carbon frameworks enantioselectively through cleavage and formation of C-C bonds. These new synthetic reactions offer efficient ways to construct complex organic skeletons that are otherwise difficult to access.
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