| Budget Amount *help |
¥39,520,000 (Direct Cost: ¥30,400,000、Indirect Cost: ¥9,120,000)
Fiscal Year 2015: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2012: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Fiscal Year 2011: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
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| Outline of Final Research Achievements |
Recent development of computational chemistry has now made theoretical approach a powerful tool to gain deep insights into the origins of chemo-, regio-, and stereoselectivities in asymmetric organocatalysis. Toward the rational design and development of high-performance organocatalysts, controlling systems in various asymmetric organocatalysis has been continuously investigated together with great collaborators. We herein elucidated that the major factors in controlling selectivities of asymmetric organocatalysis are the precised networks of multiple hydrogen bonds and attractive dispersion interactions between organocatalyst and substrates.
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