Development of synthetic methods for particle size controlled element-blocks based on silsesquioxanes

• Project Area: Creation of Element-Block Polymer Materials
• Project/Area Number: 24102003
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyoto Institute of Technology
• Principal Investigator: Naka Kensuke 京都工芸繊維大学, 分子化学系, 教授 (70227718)
• Project Period (FY): 2012-06-28 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥48,880,000 (Direct Cost: ¥37,600,000、Indirect Cost: ¥11,280,000); Fiscal Year 2016: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000); Fiscal Year 2015: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000); Fiscal Year 2014: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000); Fiscal Year 2013: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000); Fiscal Year 2012: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
• Keywords: シルセスキオキサン / POSS / 無機高分子 / 光学的透明膜 / 二官能性モノマー / 有機ヒ素化合物 / 高分子合成 / 有機無機ハイブリッド高分子 / かご型シルセスキオキサン / 透明膜 / 耐熱性 / 屈折率 / ナノ材料 / 自己組織化 / 分子性固体 / ポリイミド / 有機ヒ素化学

Outline of Final Research Achievements

Thermoplastic optically transparent silsesquioxane materials derived from a single caged silsesquioxane compound can be achieved by dumbbell- and star-shaped caged structures, which can precisely design their structures for tuning their properties. Well-defined caged silsesquioxane monomers having two polymerizable functional groups were prepared by a selective corner-opening reaction of monofunctional caged silsesquioxanes and a subsequent corner-capping reaction. Polymerization of the difunctional caged silsesquioxane monomers with appropriate co-monomers resulted in transparent self-standing films. The present monomers would contribute to design novel element-block polymeric materials with well-defined properties. Novel element-blocks based on organoarsenic compounds were also prepared by newly developed practical synthetic methods to stimulate the field of organoarsenic chemistry as well as enlarging library of element-blocks.

Research Products

• [Journal Article] Synthesis of bi-functional terminal octasilicate-core dendrimer containing fluorocarbon and hydrocarbon chains (2017)
  • Author(s): Irie, Y.; Yuasa, S.; Imoto, H.; Naka, K.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. Volume: 55 Issue: 5 Pages: 912-918
  • DOI: 10.1002/pola.28451
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Practical screening strategy of arsenic ligands for a transition metal-catalyzed reaction (2017)
  • Author(s): Imoto, H.; Yamazawa, C.; Tanaka, S.; Kato, T.; *Naka, K.
  • Journal Title: Chem. Lett Volume: 46 Issue: 6 Pages: 821-823
  • DOI: 10.1246/cl.170163
  • NAID: 130005689351
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Rh-Catalyzed Direct Arylation of a Polyhedral Oligomeric Silsesquioxane (2017)
  • Author(s): Imoto, H.; Wada, S.; Naka, K.
  • Journal Title: Dalton Trans. Volume: 46 Issue: 19 Pages: 6168-6171
  • DOI: 10.1039/c7dt01106g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis of single component element-block materials based on siloxane-based caged frameworks (2017)
  • Author(s): Naka, K.; Irie, Y.
  • Journal Title: Polym. Int. Volume: 66 Issue: 2 Pages: 187-194
  • DOI: 10.1002/pi.5121
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Practical Method for the Generation of Organoarsenic Nucleophiles towards the Construction of a Versatile Arsenic Library (2016)
  • Author(s): Tanaka, S.; Imoto, H.; Kato, T.; Naka, K.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 19 Pages: 7937-7940
  • DOI: 10.1039/c6dt00723f
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Experimental Study on Arsoles; Structural Variation, Optical and Electronic Properties, and Emission Behavior (2016)
  • Author(s): Ishidoshiro, M.; Imoto, H.; Tanaka, S.; Naka, K.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 21 Pages: 8717-8723
  • DOI: 10.1039/c6dt01010e
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Metal-organic framework containing arsenic atoms with a free lone pair (2016)
  • Author(s): Ishidoshiro, M.; Imoto, H.; Naka, K.
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 89 Issue: 9 Pages: 1057-1062
  • DOI: 10.1246/bcsj.20160120
  • NAID: 130006770697
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Chemical Functionalization and Photoluminescence of Graphene Quantum Dots (2016)
  • Author(s): Ryo Sekiya, Yuichiro Uemura, Hiroyoshi Naito, Kensuke Naka, Takeharu Haino
  • Journal Title: Chemistry A European Journal Volume: 22 Issue: 24 Pages: 8198-8206
  • DOI: 10.1002/chem.201504963
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Facile synthesis and properties of dithieno[3,2-b:2’,3’-d]arsoles (2016)
  • Author(s): Kato, T.; Imoto, H.; Tanaka, S.; Ishidoshiro, M.; Naka, K.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 28 Pages: 11338-11345
  • DOI: 10.1039/c6dt02034h
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Fabrication of polymer-calcite composite thin films by phase transition of vaterite composite particles with octacarboxy-terminated T8-caged silsesquioxane (2016)
  • Author(s): Miyauchi, S.; Imoto, H.; *Naka, K.
  • Journal Title: Polym. J. Volume: 48 Issue: 10 Pages: 1019-1027
  • DOI: 10.1038/pj.2016.69
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis of Silsesquioxane-Based Element-Block Amphiphiles and Their Self-Assembly in Water (2016)
  • Author(s): *Yusa, S.; Ohno, S,; Imoto, H.; Nakao, Y.; Naka, K.; Nakamura, Y.; *Fujii, S.
  • Journal Title: RSC Adv. Volume: 6 Issue: 77 Pages: 73006-73012
  • DOI: 10.1039/c6ra13995g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Efficient Isolation of Completely Decorated Polyhedral Oligomeric Silsesquioxanes by Utilizing Imine Bond Formation (2016)
  • Author(s): Imoto, H.; Wada, S.; *Naka, K.
  • Journal Title: Chemistry Letters Volume: 45 Issue: 11 Pages: 1256-1258
  • DOI: 10.1246/cl.160679
  • NAID: 130005509387
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Arsole-containing π-conjugated polymer by post-element-transformation technique (2016)
  • Author(s): Matsumura, Y.; Ishidoshiro, M.; Irie, Y.; Imoto, H.; Naka, K.; Tanaka, K.; Inagi, S.; Tomita, I.
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 48 Pages: 15040-15043
  • DOI: 10.1002/anie.201608404
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Molecular shape recognition by using a switchable luminescent nonporous molecular crystal (2016)
  • Author(s): Hiroaki Imoto, Susumu Tanaka, Takuji Kato, Takashi Yumura, Seiji Watase, Kimihiro Matsukawa, Kensuke Naka
  • Journal Title: Organometallics Volume: 35 Issue: 21 Pages: 3647-3650
  • DOI: 10.1021/acs.organomet.6b00614
  • Peer Reviewed
• [Journal Article] Conductive casting films based on an octasilicate-core dendrimer containing the mixed-valence state TCNQ on the periphery (2016)
  • Author(s): Irie, Y.; Li, L.; Imoto, H.; Komada, M.; Nishino, T.; Naka, K.
  • Journal Title: RSC Adv. Volume: 6 Issue: 115 Pages: 114513-114518
  • DOI: 10.1039/c6ra21636f
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Preparation of Photo-Responsive Hybrid Materials Based on Hydrogel Involving Imidazolium-Presenting Gold Nanoparticles (2016)
  • Author(s): Tanaka, K.; Naka, K; Miyoshi, E.; Narita, A.; Chujo, Y.
  • Journal Title: Polym. J. Volume: 48 Issue: 2 Pages: 177-181
  • DOI: 10.1038/pj.2015.89
  • NAID: 40020720119
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Design of low-crystalline and -density isobutyl-substituted caged silsesquioxane derivatives by star-shaped architectures linked with short aliphatic chains (2016)
  • Author(s): Yasumoto, Y.; Yamanaka, T.; Sakurai, S.; Imoto, H.; Naka, K.
  • Journal Title: Polym. J. Volume: 48 Issue: 3 Pages: 281-287
  • DOI: 10.1038/pj.2015.114
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Solid-State Emission of Platinum Dihalide Complexes with 9-Phenyl-9-Arsafluorene (2016)
  • Author(s): Imoto, H.; Tanaka, S.; Kato, T.; Watase, S.; Matsukawa, K.; Yumura, T.; Naka, K.
  • Journal Title: Organometallics Volume: 35 Issue: 3 Pages: 364-369
  • DOI: 10.1021/acs.organomet.5b00944
  • Peer Reviewed
• [Journal Article] Synthesis and Properties of Polyimides Containing Hexaisobutyl-Substituted T8 Cages in Their Main Chains (2016)
  • Author(s): Maegawa, T.; Miyashita, O.; Irie, Y.; Imoto, H.; Naka, K.
  • Journal Title: RSC Adv. Volume: 6 Issue: 38 Pages: 31751-31757
  • DOI: 10.1039/c6ra04860a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Tripodal Polyhedral Oligomeric Silsesquioxanes as Novel Class of Three-Dimensional Emulsifiers (2015)
  • Author(s): H. Imoto, Y. Nakao, N. Nishizawa, S. Fujii, Y. Nakamura, K. Naka
  • Journal Title: Polym. J. Volume: 47 Issue: 9 Pages: 609-615
  • DOI: 10.1038/pj.2015.38
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] As-Stereogenic C2-Symmetric Organoarsines: Synthesis and Enantioselective Self-Assembly into Dinuclear Triple-Stranded Helicate with Copper Iodide (2015)
  • Author(s): Hiroki Adach, Hiroaki Imoto, Seiji Watase, Kimihiro Matsukawa, Kensuke Naka
  • Journal Title: Dalton Transactions Volume: 44 Issue: 35 Pages: 15372-15376
  • DOI: 10.1039/c5dt01490e
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Control of Interparticle Spacing in Stable Aggregates of Gold Nanoparticles by Light Irradiation (2015)
  • Author(s): Chujo, Y.; Naka, K; Miyoshi, E.; Narita, A.; Tanaka, K.
  • Journal Title: Polym. J. Volume: 47 Issue: 11 Pages: 747-752
  • DOI: 10.1038/pj.2015.56
  • NAID: 40020633247
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] In-situ Iodination of Organoarsenic Homocycles: Facile Synthesis of 9-Arsafluorene (2015)
  • Author(s): Kato, T.; Tanaka, S.; Naka, K.
  • Journal Title: Chem. Lett. Volume: 44 Issue: 11 Pages: 1476-1478
  • DOI: 10.1246/cl.150657
  • NAID: 130005108072
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Practical Synthesis and Properties of 2,5-Diarylarsoles (2015)
  • Author(s): Makoto Ishidoshiro, Yoshimasa Matsumura, Hiroaki Imoto, Yasuyuki Irie, Takuji Kato, Seiji Watase, Kimihiro Matsukawa, Shinsuke Inagi, Ikuyoshi Tomita, Kensuke Naka
  • Journal Title: Organic Letters Volume: 17 Issue: 19 Pages: 4854-4857
  • DOI: 10.1021/acs.orglett.5b02416
  • Peer Reviewed
• [Journal Article] para-Bisvinylhexaisobutyl-Substituted T8 Caged Monomer: Synthesis and Hydrosilylation Polymerization (2015)
  • Author(s): Maegawa, T.; Irie, Y. Imoto, H.; Fueno, H.; Tanaka, K.; Naka, K.
  • Journal Title: Polym. Chem. Volume: 6 Issue: 43 Pages: 7500-7504
  • DOI: 10.1039/c5py01262g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Amphiphilic POSS-Core Dendrons for Optically Transparent Thermoplastic Films with Tunable Wettability (2015)
  • Author(s): Ogi, K.; Miyauchi, S.; Naka, K.
  • Journal Title: Polym. J. Volume: 47 Issue: 3 Pages: 259-266
  • DOI: 10.1038/pj.2014.119
  • NAID: 40020380600
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Bendable, Free-Standing Calcite Thin Films (2015)
  • Author(s): Nakamura, S.; Naka, K.
  • Journal Title: Langmuir Volume: 31 Issue: 6 Pages: 2014-2018
  • DOI: 10.1021/la504075p
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Spontaneous Formation of Gold Nanoparticles with Octa(3-aminopropyl) Polyhedral Oligomeric Silsesquioxane (2015)
  • Author(s): Imoto, H.; Ishida, K.; Sasaki, A.; Irie, Y. Itoh, H.; Naka, K.; Chujo, Y.
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 印刷中 Issue: 5 Pages: 653-656
  • DOI: 10.1246/bcsj.20150009
  • NAID: 130005069503
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Surface Modification and Aggregation Control of Gold Nanoparticles via Multi-Functional Stabilizer Based on Polyhedral Oligomeric Silsesquioxane (2015)
  • Author(s): Imoto, H.; Suzuki, S.; Naka, K.
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 印刷中 Issue: 5 Pages: 693-697
  • DOI: 10.1246/bcsj.20150016
  • NAID: 130005069504
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Syntheses of Biphenyl-Terminated Polyhedral Oligomeric Octasilicate-Core Dendrimers and Their Single Component Optical Transparent Free-Standing Thermoplastic Films (2015)
  • Author(s): Irie, Y.; Naka, K.
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. Volume: 印刷中 Issue: 12 Pages: 1437-1443
  • DOI: 10.1002/pola.27583
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and polymerization of a para-disubstituted T8-caged hexaisobutyl-POSS monomer (2014)
  • Author(s): Maegawa, T.; Irie, Y.; Fueno, H.; Tanaka, K.
  • Journal Title: Chem. Lett Volume: 43 Issue: 10 Pages: 1532-1534
  • DOI: 10.1246/cl.140515
  • NAID: 130004693821
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Polymorph Control of Luminescence Properties in Molecular Crystals of a Platinum and Organoaresenic Complex and Formation of Stable One-Dimensional Nanochannel (2014)
  • Author(s): Unesaki, H.; Kato, K.; Watase, S.; Matsukawa, K.; Naka, K.
  • Journal Title: Inorg. Chem. Volume: 53 Issue: 16 Pages: 8270-8277
  • DOI: 10.1021/ic500550y
  • Peer Reviewed
• [Journal Article] Synthesis of Imidazolium Salt-Terminated Poly(amidoamine)-Typed POSS-Core Dendrimers and Their Solution and Bulk Properties (2014)
  • Author(s): Naka, K.; Shinke, R.; Yamada, M.; Belkada, F.; Aijo, Y.; Irie, Y. Shankar, S. R.; Smaran, K. S.; Matsumi, N.; Tomita, S.; Sakurai, S.
  • Journal Title: Polym. J. Volume: 46 Issue: 1 Pages: 42-51
  • DOI: 10.1038/pj.2013.60
  • NAID: 40019921434
  • Peer Reviewed
• [Journal Article] Synthesis of imidazole-terminated hyperbranched polymers with POSS-branching points and their pH responsive and coordination properties (2013)
  • Author(s): Irie, Y.; Naka, K.
  • Journal Title: J. Polym. Scie., Part A: Polym. Chem. Volume: 51 Issue: 12 Pages: 2695-2701
  • DOI: 10.1002/pola.26664
  • Peer Reviewed
• [Journal Article] Size-Controlled Vaterite Composite Particles with POSS-Core Dendrimer for Fabrication of Calcite Thin Films by Phase Transition (2013)
  • Author(s): Nakamura, S.; Naka, K.
  • Journal Title: Langmuir Volume: 29 Issue: 51 Pages: 15888-15897
  • DOI: 10.1021/la403193e
  • Peer Reviewed
• [Journal Article] 新規有機ヒ素化合物の合成と金属錯体 (2013)
  • Author(s): 中 建介
  • Journal Title: 有機合成化学協会誌 Volume: 71 Pages: 880-890
  • NAID: 10031196510
  • Peer Reviewed
• [Journal Article] Organic Vapor Triggered Repeatable On-Off Crystalline-State Luminescence Switching (2012)
  • Author(s): Kensuke Naka, Takuji Kato, Seiji Watase, Kimihiro Matsukawa
  • Journal Title: Inorganic Chemistry Volume: 51 Issue: 8 Pages: 4420-4422
  • DOI: 10.1021/ic300173t
  • Peer Reviewed
• [Journal Article] Syntheses and Properties of Dumbbell-Shaped POSS Derivatives Linked by Luminescent π-Conjugated Units (2012)
  • Author(s): Araki, H.; Naka, K
  • Journal Title: J. Polym. Scie., Part A: Polym. Chem. Volume: 50 Issue: 20 Pages: 4170-4181
  • DOI: 10.1002/pola.26241
  • Peer Reviewed
• [Journal Article] Arylaminomaleimide as a new class of aggregation-induced emission active molecule obtained from organoarsenic compounds (2012)
  • Author(s): Kato, T.; Naka, K.
  • Journal Title: Chem. Lett. Volume: 41 Issue: 11 Pages: 1445-1447
  • DOI: 10.1246/cl.2012.1445
  • NAID: 130004426409
  • Peer Reviewed
• [Journal Article] 無機高分子の新展開：無機元素ブロック高分子材料へ (2012)
  • Author(s): 中 建介
  • Journal Title: 高分子 Volume: 61 Pages: 881-885
  • NAID: 10031117784
  • Peer Reviewed
• [Presentation] Synthesis of Element Block Polymers Based on T8-caged Silsesquioxanes (2017)
  • Author(s): 中 建介
  • Organizer: Indo-Japan Joint Symposium on Polymeric Materials
  • Place of Presentation: Keraka, INDIA
  • Year and Date: 2017-02-01
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of Element Block Polymers Based on T8-caged Silsesquoxanes (2016)
  • Author(s): 中 建介
  • Organizer: the 11th SPSJ International Polymer Conference (IPC2016)
  • Place of Presentation: 福岡
  • Year and Date: 2016-12-13
  • Int'l Joint Research
• [Presentation] 実践的ヒ素-炭素結合反応による有機ヒ素化合物の創出と機能開拓 (2016)
  • Author(s): 中 建介
  • Organizer: ヘテロ原子部会平成28年度第2回懇話会
  • Place of Presentation: 滋賀
  • Year and Date: 2016-11-29
  • Invited
• [Presentation] 機能性新素材を目指す元素ブロック高分子材料の創出 (2016)
  • Author(s): 中 建介
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川
  • Year and Date: 2016-09-14
  • Invited
• [Presentation] かご型シルセスキオキサンを基盤とした元素ブロック高分子の創出 (2016)
  • Author(s): 中 建介
  • Organizer: 日本ゾルゲル学会第14回討論会
  • Place of Presentation: 東京
  • Year and Date: 2016-08-08
  • Invited
• [Presentation] かご型シルセスキオキサンを基盤とした元素ブロック高分子の開発 (2016)
  • Author(s): 中 建介
  • Organizer: 第61回湘北地区懇話会講演会
  • Place of Presentation: 神奈川
  • Year and Date: 2016-08-01
  • Invited
• [Presentation] Element-Block Polymers Based on T8-caged Silsesquioxanes (2016)
  • Author(s): 中 建介
  • Organizer: IITG-KIT Joint Symposium on Soft and Biobased Materials
  • Place of Presentation: 京都
  • Year and Date: 2016-08-01
  • Int'l Joint Research / Invited
• [Presentation] Element-Block Polymers Based on T8-caged Silsesquioxanes (2016)
  • Author(s): 中 建介
  • Organizer: Collaborative Conference on 3D & Materials Research (CC3DMR)
  • Place of Presentation: Incheon/Seoul, South Korea
  • Year and Date: 2016-06-20
  • Int'l Joint Research / Invited
• [Presentation] かこ型シルセスキオキサンを基盤とした元素フロック高分子の開発 (2016)
  • Author(s): 中 建介
  • Organizer: 粉体粉末冶金協会平成28年度春季大会
  • Place of Presentation: 京都
  • Year and Date: 2016-05-24
  • Invited
• [Presentation] かご型シルセスキオキサンを主構成要素とした元素ブロック高分子材料の開発 (2016)
  • Author(s): 中 建介
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 京田辺市
  • Year and Date: 2016-03-26
  • Invited
• [Presentation] Synthesis of element block polymers based on T8-caged silsesquioxanes (2015)
  • Author(s): 中 建介
  • Organizer: Pacifichem 2015
  • Place of Presentation: ホノルル、Hawaii USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Synthesis of Element Block Polymers Based on T8-caged Silsesquoxanes (2015)
  • Author(s): 中 建介
  • Organizer: Pacific Polymer Conference 14,
  • Place of Presentation: Kauai, Hawaii USA
  • Year and Date: 2015-12-09
  • Int'l Joint Research / Invited
• [Presentation] 元素ブロック高分子材料の創出 (2015)
  • Author(s): 中 建介
  • Organizer: 関西接着ワークショップ 2015年度第３回研究会
  • Place of Presentation: 京都
  • Year and Date: 2015-12-03
  • Invited
• [Presentation] Synthesis of Element Block Polymers Based on T8-caged Silsesquioxanes (2015)
  • Author(s): 中 建介
  • Organizer: IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering
  • Place of Presentation: 横浜
  • Year and Date: 2015-10-18
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of Element Block Polymers Based on T8-caged Silsesquioxanes (2015)
  • Author(s): 中 建介
  • Organizer: International Science and Nature Congress
  • Place of Presentation: Kuala Lumpur, Malaysia
  • Year and Date: 2015-09-21
  • Int'l Joint Research / Invited
• [Presentation] カゴ型シルセスキオキサンを基盤とした元素ブロック高分子の創出 (2015)
  • Author(s): 中 建介
  • Organizer: 第45回繊維学会夏季セミナー
  • Place of Presentation: 北九州市
  • Year and Date: 2015-07-29
  • Invited
• [Presentation] ynthesis of Element Block Polymers Based on T8-caged Silsesquioxanes (2015)
  • Author(s): 中 建介
  • Organizer: East Asian Symposium on Polymers for Advanced Technology
  • Place of Presentation: 淡路島、兵庫
  • Year and Date: 2015-07-27
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of POSS-Based Compounds and Their Application, (2015)
  • Author(s): 中 建介
  • Organizer: The International Conference on Frontiers in Materials Processing Applications, Research & Technology
  • Place of Presentation: Hyderabad, India
  • Year and Date: 2015-06-12
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of element block polymers based on T8-caged silsesquioxanes (2015)
  • Author(s): 中 建介
  • Organizer: US-Japan Workshop on Advances in Organic/Inorganic Hybrid Materials 2015
  • Place of Presentation: 姫路
  • Year and Date: 2015-05-18
  • Int'l Joint Research / Invited
• [Presentation] 環状オリゴアルシンを用いた9-アルサフルオレンの合成 (2015)
  • Author(s): 加藤拓路，中 建介
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] 9-アルサフルオレン-白金(II)錯体の合成とその固体発光 (2015)
  • Author(s): 田中 進，加藤拓路，渡瀬星児，松川公洋，中 建介
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] ynthesis and coordination behavior of unsymmetrical cyclic arsenic compounds (2015)
  • Author(s): Adachi, H.; Imoto, H.; Naka, K.
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] 不完全かご型シルセスキオキサンを主骨格とする両親媒性分子の合成 (2015)
  • Author(s): 中尾優花，井本裕顕，中 建介，藤井秀司，中村吉伸
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] Synthesis of POSS-Based Compounds and Their Application (2015)
  • Author(s): Naka, K.; Araki, H.; Irie, Y.; Maegawa, T.
  • Organizer: IITG-KIT Joint Symposium on Biobased Materials
  • Place of Presentation: Guwahati, India
  • Year and Date: 2015-01-20
  • Invited
• [Presentation] 二官能性ヘキサイソブチルPOSS モノマー開発による主鎖型POSS ハイブリット高分子の合成 (2014)
  • Author(s): 前川昂之，田中一義，笛野博之，中 建介
  • Organizer: 第33 回無機高分子研究討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-11-13 – 2014-11-14
• [Presentation] 置換基変換によるヒ素含有環状二座配位子の配位構造制御 (2014)
  • Author(s): 安達大輝，中 建介
  • Organizer: 第33 回無機高分子研究討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-11-13 – 2014-11-14
• [Presentation] アルキレン鎖架橋イソブチル基含有スター型POSS 誘導体を用いた単一成分光学的透明膜の特性とナノ構造評価 (2014)
  • Author(s): 安本勇太，櫻井伸一，中建介
  • Organizer: 第33 回無機高分子研究討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-11-13 – 2014-11-14
• [Presentation] 置換基変換によるヒ素含有環状二座配位子の配位構造制御 (2014)
  • Author(s): 安達大輝，中 建介
  • Organizer: 第15回リング・チューブ超分子研究会シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2014-10-27 – 2014-10-28
• [Presentation] 縮合多環式ジイミド型有機ヒ素化合物の特性と金属錯体 (2014)
  • Author(s): 石徹白真，加藤 拓路，阿部 剛士，中 建介
  • Organizer: 第15回リング・チューブ超分子研究会シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2014-10-27 – 2014-10-28
• [Presentation] 二官能性へキサイソブチルPOSS誘導体を用いた高分子合成と特性 (2014)
  • Author(s): 前川昂之，入江 康行，田中 一義，笛野 博之，中 建介
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] アルキレン鎖架橋イソブチル基含有スター型POSS誘導体による単一成分光学的透明膜の作製とナノ構造評価 (2014)
  • Author(s): 安本勇太，櫻井伸一，中 建介
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] ビスアリール置換ヒ素含有環状二座配位子の合成とその錯体形成挙動 (2014)
  • Author(s): 安達大輝，中 建介
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 縮合多環式ジイミド型有機ヒ素化合物の特性と金属錯体 (2014)
  • Author(s): 石徹白真，加藤拓路，阿部剛士，中 建介
  • Organizer: 第63回高分子学会討論会
  • Place of Presentation: 長崎
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] Organic-Inorganic Hybrid Polymers: Synthesis and Function (2014)
  • Author(s): Naka, K.
  • Organizer: The 12th Japan-Vietnam Joint Symposium, Can Tho University
  • Place of Presentation: ベトナム
  • Year and Date: 2014-09-17 – 2014-09-18
  • Invited
• [Presentation] 無機高分子の新展開を目指した元素ブロック高分子材料 (2014)
  • Author(s): 中 建介
  • Organizer: 日本セラミックス協会 第２７回秋季シンポジウム
  • Place of Presentation: 鹿児島
  • Year and Date: 2014-09-10
  • Invited
• [Presentation] 縮合多環式ジイミド型有機ヒ素化合物の立体異性化とその金属錯体形成 (2014)
  • Author(s): 石徹白真，中建介
  • Organizer: 第60回高分子研究発表会（神戸）
  • Place of Presentation: 神戸
  • Year and Date: 2014-08-24 – 2014-08-25
• [Presentation] 両親媒性POSS核デンドロン透明膜の作製とその表面特性 (2014)
  • Author(s): 宮内咲奈，尾木公一，中建介
  • Organizer: 第60回高分子研究発表会（神戸）
  • Place of Presentation: 神戸
  • Year and Date: 2014-08-24 – 2014-08-25
• [Presentation] 二官能性へキサイソブチルPOSS 誘導体を用いたポリイミドの合成 (2014)
  • Author(s): 前川昂之，入江康行，田中一義，笛野博之，中建介
  • Organizer: 第60回高分子研究発表会（神戸）
  • Place of Presentation: 神戸
  • Year and Date: 2014-08-24 – 2014-08-25
• [Presentation] Synthesis of POSS-Based Compounds and Their Application (2014)
  • Author(s): Naka, K.; Araki, H.; Irie, Y.
  • Organizer: 1st JAIST JAPAN-INDIA SYMPOSIUM ON AUTOMOTIVE TECHNOLOGIES
  • Place of Presentation: 石川
  • Year and Date: 2014-08-05 – 2014-08-06
  • Invited
• [Presentation] Synthesis of POSS-Based Compounds and Their Application (2014)
  • Author(s): Naka, K.
  • Organizer: The First International Symposium on Advanced Polymer Materials and Fiber Science
  • Place of Presentation: 京都
  • Year and Date: 2014-08-04 – 2014-08-05
• [Presentation] 二官能性へキサイソブチルPOSS誘導体の合成と高分子 (2014)
  • Author(s): 前川昂之，入江康行，田中一義，笛野博之，中 建介
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] トランス体縮合多環式ジイミド型有機ヒ素化合物を用いた金属錯体の合成 (2014)
  • Author(s): 石徹白真，中 建介
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] 対称および非対称ジフェニル置換ヒ素含有環状二座配位子を用いた金属錯体の合成 (2014)
  • Author(s): 安達大輝，中 建介
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] 種々のアルキレン鎖で架橋されたイソブチル置含有スター型POSS誘導体光学的透明膜の作製 (2014)
  • Author(s): 安本勇太，中 建介，櫻井伸一
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] 水素結合性末端POSS核デンドロンを用いた単一成分透明膜の作製 (2014)
  • Author(s): 宮内咲奈，尾木公一，中 建介
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋
  • Year and Date: 2014-05-28 – 2014-05-30
• [Presentation] POSSを基盤とした単一成分有機無機ハイブリッド材料の創出 (2014)
  • Author(s): 中 建介
  • Organizer: 14-1精密ネットワークポリマー研究会
  • Place of Presentation: 東京
  • Year and Date: 2014-04-18
  • Invited
• [Presentation] 環状有機ヒ素化合物を用いた金属錯体結晶の多形制御と機能 (2014)
  • Author(s): 中 建介
  • Organizer: 第1４回リング・チューブ超分子研究会シンポジウム
  • Place of Presentation: 九州大学伊都キャンパス
  • Invited
• [Presentation] シス体縮合多環式ジイミド型有機ヒ素化合物の立体異性化挙動 (2014)
  • Author(s): 石徹白 真・中 建介
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学 名古屋
• [Presentation] 二官能性かご型シルセスキオキサンの合成 (2014)
  • Author(s): 前川 昂之・中 建介
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学 名古屋
• [Presentation] 両親媒性POSS核デンドロン透明膜の作製 (2014)
  • Author(s): 宮内 咲奈・中 建介
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学 名古屋
• [Presentation] イミダゾリウム塩末端かご型オクタシリケート核デンドリマーを用いた色素増感太陽電池用固体電解質の開発 (2014)
  • Author(s): 入江 康行・藤永 浩明・岩崎 仁・中 建介
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学 名古屋
• [Presentation] オクタ(3-アミノプロピル)オクタシルセスキオキサンを用いたアミノ官能基化金ナノ粒子の合成 (2013)
  • Author(s): 鈴木森世志、中 建介
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大 滋賀
  • Year and Date: 2013-03-22
• [Presentation] 室温で固体発光する新規ヒ素含有二座配位子―白金(II)錯体の合成 (2013)
  • Author(s): 畦崎光、中建介
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大 滋賀
  • Year and Date: 2013-03-22
• [Presentation] 種々のアミノマレイミド誘導体の合成とその固体発光置換基効果 (2013)
  • Author(s): 木崎浩平、中建介
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大 滋賀
  • Year and Date: 2013-03-22
• [Presentation] フェニルアセチレンと環状オリゴアルシンとのラジカル反応による新規ヒ素含有環状二座配位子の合成 (2013)
  • Author(s): 安達大輝、中建介
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大 滋賀
  • Year and Date: 2013-03-22
• [Presentation] イミド架橋ダンベル型POSS誘導体の合成と特性 (2013)
  • Author(s): 安本勇太、中建介
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大 滋賀
  • Year and Date: 2013-03-22
• [Presentation] Preparation of Imidazolium Cation Terminated POSS-Core Dendrimers and Their Application (2013)
  • Author(s): Naka, K.; Shinke, R.; Yamada, M.; Irie Y.
  • Organizer: 1st JAIST International Symposium on Ionics Materials
  • Place of Presentation: 北陸先端大 石川
  • Year and Date: 2013-03-14
  • Invited
• [Presentation] Synthesis of POSS-Based Compounds and Their Application (2013)
  • Author(s): Naka, K.; Araki, H.; Irie, Y.
  • Organizer: The 13th Pacific Polymer Conference (PPC13)
  • Place of Presentation: Kaohsiung, Taiwan
  • Invited
• [Presentation] 金ナノ粒子をテンプレートとした非対称官能基化かご型シルセスキオキサンの合成 (2013)
  • Author(s): 鈴木 森世志、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] イミダゾリウムヘキサフルオロリン酸塩末端エステル型POSS核デンドリマーを用いたリチウムイオン伝導性材料の開発 (2013)
  • Author(s): 入江 康行、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] TCNQアニオンラジカル導入POSS核デンドリマーの特性評価 (2013)
  • Author(s): 入江 康行、駒田 めぐみ、西野 孝、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] ヒ素含有配位子―白金(II)単核錯体の分子パッキングによる室温固体発光制御 (2013)
  • Author(s): 畦崎 光、渡瀬 星児、松川 公洋、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] アニオン性末端POSS核デンドリマー‐炭酸カルシウム複合微粒子を用いた交互積層法による高分子複合多層膜の作製 (2013)
  • Author(s): 中村 志穂、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] アミノマレイミド誘導体の合成とそのポリマーフィルム中の発光特性 (2013)
  • Author(s): 木崎 浩平、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] アミド架橋プロペラ型POSS誘導体の合成と特性 (2013)
  • Author(s): 安本 勇太、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] フェニルアセチレン類と環状オリゴアルシンとのラジカル反応による新規有機ヒ素化合物の合成 (2013)
  • Author(s): 安達 大輝、中 建介
  • Organizer: 第６２回高分子年次大会
  • Place of Presentation: 京都国際会議場、京都
• [Presentation] 粒径制御されたPOSS核デンドリマー‐バテライト複合微粒子の相転移を用いたカルサイト薄膜の作製 (2013)
  • Author(s): 中村 志穂、中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] イミダゾリウム塩末端ポリエステル型POSS核デンドリマーを用いた単一成分固体電解質の開発 (2013)
  • Author(s): 入江 康行、駒田 めぐみ、西野 孝、中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] ビフェニル基を末端に有するPOSS核デンドリマーを用いた単一成分自立透明膜の作製 (2013)
  • Author(s): 入江 康行、中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] 有機ヒ素白金(II)錯体とその空隙容量依存固体発光挙動 (2013)
  • Author(s): 畦崎 光、加藤 拓路、渡瀬 星児、松川 公洋、中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] オクタ(3-アミノプロピル)オクタシルセスキオキサンを用いたアミノ官能基化金ナノ粒子の合成とその特性 (2013)
  • Author(s): 鈴木 森世志、中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] フェニルアセチレン類を用いた環状有機ヒ素化合物の合成とその金属錯体 (2013)
  • Author(s): 安達 大輝・中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] アミノマレイミド誘導体含有ポリマーフィルムの作製とその発光特性 (2013)
  • Author(s): 木崎 浩平・中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] アルキレン鎖で架橋されたスター型POSS誘導体の合成と特性 (2013)
  • Author(s): 安本 勇太・中 建介
  • Organizer: 第 62 回高分子討論会
  • Place of Presentation: 金沢大学 金沢
• [Presentation] 混合原子価TCNQを導入したPOSS核デンドリマーによる導電性固体膜の開発 (2013)
  • Author(s): 入江康行・中 建介
  • Organizer: 第32回無機高分子研究討論会
  • Place of Presentation: 東京理科大学 東京
• [Presentation] POSS核デンドリマー‐バテライト複合微粒子の相転移を用いたカルサイト薄膜の作製 (2013)
  • Author(s): 中村志穂・中 建介
  • Organizer: 第32回無機高分子研究討論会
  • Place of Presentation: 東京理科大学 東京
• [Presentation] かご型シルセスキオキサン核デンドリマーによる固体導電材料の開発 (2012)
  • Author(s): 入江康行、山田真紀、新家隆介、中 建介
  • Organizer: 第56回日本学術会議材料工学連合講演会
  • Place of Presentation: 京都
  • Year and Date: 2012-10-29
• [Presentation] 元素ハイブリッド技術を利用した有機-無機ハイブリッド材料の開発 (2012)
  • Author(s): 中 建介
  • Organizer: 関西HI研究会 第34回研究会
  • Place of Presentation: 関西大 吹田
  • Year and Date: 2012-10-16
  • Invited
• [Presentation] イミド基含有縮合多環式有機ヒ素骨格の合成とその金属錯体 (2012)
  • Author(s): 阿部 剛士・中 建介
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋国際会議場 名古屋
  • Year and Date: 2012-09-19
• [Presentation] 両親媒性POSS核デンドロン会合体の作製 (2012)
  • Author(s): 尾木 公一・中 建介
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋国際会議場 名古屋
  • Year and Date: 2012-09-19
• [Presentation] Synthesis of organoarsenic compounds and their functions (2012)
  • Author(s): Naka, K.
  • Organizer: ACS 244th National Meeting
  • Place of Presentation: Philadelphia, Pennsylvania USA
  • Year and Date: 2012-08-19
  • Invited
• [Presentation] Preparation of Functionalized POSS-Core Dendrimers and Their Application (2012)
  • Author(s): Naka, K.
  • Organizer: The Second Japan-Korea Joint Symposium on Polymer Nanohybrid Materials
  • Place of Presentation: 京都工芸繊維大学 京都
  • Year and Date: 2012-08-06
  • Invited
• [Presentation] フェニルアセチレン類と環状オリゴアルシンとのラジカル反応による新規ヒ素含有二座配位子の合成
  • Author(s): 安達大輝、中建介
  • Organizer: 第59回高分子研究発表会(神戸)
  • Place of Presentation: 兵庫県民会館 神戸市
• [Presentation] アミノマレイミド誘導体の合成とその発光特性
  • Author(s): 木崎浩平、中建介
  • Organizer: 第59回高分子研究発表会(神戸)
  • Place of Presentation: 兵庫県民会館 神戸市
• [Presentation] 酸二無水物を用いたダンベル型およびプロペラ型POSS誘導体の合成
  • Author(s): 安本勇太、中建介
  • Organizer: 第59回高分子研究発表会(神戸)
  • Place of Presentation: 兵庫県民会館 神戸市
• [Remarks] 中研究室 京都工芸繊維大学
  • URL: http://www.cis.kit.ac.jp/~kenaka/index.html
• [Remarks] 中研究室、京都工芸繊維大学大学院、工芸科学研究科、物質工学部門、応用錯体化学分野
  • URL: http://www.cis.kit.ac.jp/~kenaka/index.html
• [Remarks] 中研究室,京都工芸繊維大学大学院,工芸科学研究科,物質工学部門,応用錯体化学分野
  • URL: http://www.cis.kit.ac.jp/~kenaka/index.html
• [Remarks] 中研究室ホームページ
  • URL: http://www.cis.kit.ac.jp/~kenaka/index.html
• [Patent(Industrial Property Rights)] フッ素含有シルセスキオキサン、フッ素含有シルセスキオキサンの製造方法、及び重合体 (2016)
  • Inventor(s): 中 建介、井本裕顕、山中貴大
  • Industrial Property Rights Holder: 中 建介、井本裕顕、山中貴大
  • Industrial Property Rights Type: 特許
  • Filing Date: 2016-11-16