| Budget Amount *help |
¥45,630,000 (Direct Cost: ¥35,100,000、Indirect Cost: ¥10,530,000)
Fiscal Year 2016: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2015: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2014: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2013: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2012: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Outline of Final Research Achievements |
π-Conjugated polymers possessing diverse elements and elements-blocks are attractive materials for advanced optoelectronic applications. Due to the highly reactive nature of the elements-containing building blocks, however, most of these materials are hardly accessible by the conventional synthetic methods such as the transition metal-catalyzed polycondensation technique.
We have established the synthesis method of novel π-conjugated polymers possessing various elements-blocks units by polymer reactions of regioregular organometallic polymers possessing reactive titanacyclopentadiene units with the electrophilic reagents possessing element-blocks. Their applications to opto-electronic devices have also been performed to demonstrate their excellent features originated from the elements-blocks.
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