| Budget Amount *help |
¥45,630,000 (Direct Cost: ¥35,100,000、Indirect Cost: ¥10,530,000)
Fiscal Year 2016: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2015: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2014: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2013: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2012: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Outline of Final Research Achievements |
Properties and structural control of surface/interface, mechanical properties, conductivity of various polymer based on element-blocks were investigated. As an element-block, fluorine, sulfur, silane were introduced into polymer in the main chain and/or side chains in this study. We could succeed to find peculiar outstanding novel properties as shown below:
1) Preparation of high water-repellent but high adhesive polymer surface with fluorine,2)Preparation of high molecular weight, high modulus, high water repellent polythiphene, 3) Synthesis of high elongation, high conductive polythiophene, These polymer/ phenomena have not yet observed, which could be only achieved using polymeric materials based on element-blocks.
In addition, many methods were employed to investigate 4) adhesion and polyolefin / polysilane interface. Polyolefin and polysilane are chemically quite different, but polysilane is a good adhesive to polyolefin, which was brought by thick interface (interphase).
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