| Research Collaborator |
OCHIAI Mitsuyoshi 東北大学, 大学院理学研究科, 大学院生
FUKUDA Testuya 東北大学, 大学院理学研究科, 大学院生
KOMURA Katsuto 東北大学, 大学院理学研究科, 大学院生
NISHIMURA Kimihiko 東北大学, 大学院理学研究科, 大学院生
YOSHIMOTO Takashi 東北大学, 大学院理学研究科, 大学院生
DHUNGANA P. Tara
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| Budget Amount *help |
¥34,710,000 (Direct Cost: ¥26,700,000、Indirect Cost: ¥8,010,000)
Fiscal Year 2016: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2015: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2014: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2013: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2012: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
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| Outline of Final Research Achievements |
We investigated new types of functional molecules and synthesized many “stimuli-responsive” metal complexes that have a variety of multiple bonds between silicon or germanium and transition metals. Spectroscopical properties and X-ray crystal structures of the products were clarified. The study of their reactivity resulted in finding several new types of reactions. Especially, through the investigation using triple bonded complexes, we obtained many kinds of new [2+2] cycloaddition products, ketone-coupling products, and also found the metathesis-like fragmentation reaction, which is the first example of this type of reaction in the silicon system and is a significant result from the viewpoint of the reaction chemistry.
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