Creation of stimuli-responsive metal complexes based on the ligand properties of low-coordinate boryl anion and their catalytic function

• Project Area: Stimuli-responsive Chemical Species for the Creation of Functional Molecules
• Project/Area Number: 24109012
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Nagoya University (2016); Chuo University (2012-2015)
• Principal Investigator: YAMASHITA Makoto 名古屋大学, 工学研究科, 教授 (10376486)
• Project Period (FY): 2012-06-28 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥39,260,000 (Direct Cost: ¥30,200,000、Indirect Cost: ¥9,060,000); Fiscal Year 2016: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000); Fiscal Year 2015: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000); Fiscal Year 2014: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000); Fiscal Year 2013: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000); Fiscal Year 2012: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
• Keywords: ホウ素 / 多座配位子 / 後周期遷移金属錯体 / 触媒反応 / アルカン / 脱水素 / 酸化 / 触媒・化学プロセス / 有機工業化学 / 均一系触媒

Outline of Final Research Achievements

Throughout this research, we obtained the following research results. (1) Five kinds of ligands were newly added to the library of boron-containing pincer ligand by using a novel synthetic methods. (2) We have succeeded in synthesis of the corresponding complexes by introduction of platinum, ruthenium, rhodium, and iridium into the PBP ligands in the library and have elucidated their properties. (3) Hydrosilylation of alkene progresses with PBP platinum catalyst, hydrogenation of aldehyde proceeds with PBP ruthenium catalyst, and dehydrogenation of alkane and dimethylamine-borane proceeds with PBP iridium catalyst.

Research Products

• [Int'l Joint Research] Hong Kong U. of Sci&Tech.(Hong Kong)
• [Int'l Joint Research] 香港科学技術大学(中国(香港))
• [Journal Article] Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4) (2017)
  • Author(s): Tsukahara, N.; Asakawa, H.; Lee, K.-H.; Lin, Z.; Yamashita, M.
  • Journal Title: J. Am. Chem. Soc. Volume: 139 Issue: 7 Pages: 2593-2596
  • DOI: 10.1021/jacs.7b00924
  • NAID: 120006305575
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] A Highly Active PBP-Iridium Catalyst for Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism (2017)
  • Author(s): Kwan, E. H.; Ogawa, H.; Yamashita, M.
  • Journal Title: ChemCatChem Volume: 9 Issue: 13 Pages: 2457-2462
  • DOI: 10.1002/cctc.201700384
  • NAID: 120006349131
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Direct and Base-Catalyzed Diboration of Alkynes using The Unsymmetrical Diborane(4), pinB-BMes2 (2016)
  • Author(s): Kojima, C.; Lee, K.-H.; Lin, Z.; Yamashita, M.
  • Journal Title: J. Am. Chem. Soc. Volume: 138 Issue: 20 Pages: 6662-6669
  • DOI: 10.1021/jacs.6b03686
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] A Long-Tethered (P-B-P)-Pincer Ligand: Synthesis, Complexation, and Application to Catalytic Dehydrogenation of Alkanes (2016)
  • Author(s): Kwan, E. H.; Kawai, Y. J.; Kamakura, S.; Yamashita, M.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 40 Pages: 15931-15941
  • DOI: 10.1039/c6dt02075e
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Ring Contraction of Pinacolatoboryl Group to Form 1,2-Oxaboretane Ring: Reaction of Unsymmetrical Diborane(4) with 2,6-Dimethylphenylisocyanide (2016)
  • Author(s): Katsuma, Y.; Asakawa, H.; Lee, K.-H.; Lin, Z.; Yamashita, M.
  • Journal Title: Organometallics Volume: 35 Issue: 15 Pages: 2563-2566
  • DOI: 10.1021/acs.organomet.6b00468
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] The Organometallic Chemistry of Boron-Containing Pincer Ligands based on Diazaboroles and Carboranes (2016)
  • Author(s): Yamashita, M.
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 89 Issue: 3 Pages: 269-281
  • DOI: 10.1246/bcsj.20150355
  • NAID: 130005137571
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Qualitative Analysis of a “Bora-Brook Rearrangement”: the Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group (2016)
  • Author(s): Kisu, H.; Sakaino, H.; Ito, F.; Yamashita, M.; Nozaki, K.
  • Journal Title: J. Am. Chem. Soc. Volume: 138 Issue: 10 Pages: 3548-3552
  • DOI: 10.1021/jacs.6b00283
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] An Isolable Anionic Gallabenzene: Synthesis and Characterization (2015)
  • Author(s): Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita
  • Journal Title: Organometallics Volume: 34 Issue: 10 Pages: 1806-1808
  • DOI: 10.1021/acs.organomet.5b00310
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis of Pincer Iridium Complexes Bearing A Boron Atom and iPr-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes (2015)
  • Author(s): Tanoue, K.; Yamashita, M.
  • Journal Title: Organometallics Volume: 34 Issue: 16 Pages: 4011-4017
  • DOI: 10.1021/acs.organomet.5b00376
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Assessing the Bronsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen (2014)
  • Author(s): Dettenrieder, N.; Aramaki, Y;. Wolf, B.; Maichle-Mossmer, C.; Zhao, X.; Yamashita, M.; Nozaki, K.; Anwander, R.
  • Journal Title: Angew. Chem. Int. Ed. Volume: 53 Issue: 24 Pages: 6259-6262
  • DOI: 10.1002/anie.201402175
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Facile Scission of Isonitrile Carbon-Nitrogen Triple Bond Using A Diborane(4) Reagent (2014)
  • Author(s): Asakawa, H.; Lee, K. H.; Lin, Z.; Yamashita, M.
  • Journal Title: Nature Commun. Volume: 5 Issue: 1 Pages: 4245-4245
  • DOI: 10.1038/ncomms5245
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] An Anionic Aluminabenzene bearing Aromatic and Ambiphilic Contributions (2014)
  • Author(s): Nakamura, T.; Suzuki, K.; Yamashita, M.
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 26 Pages: 9276-9279
  • DOI: 10.1021/ja504771d
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis, Structure, and Bonding Properties of Ruthenium Complexes Possessing A Boron-Based PBP Pincer Ligand and Their Application for Catalytic Hydrogenation (2014)
  • Author(s): Miyada, T.; Kwan, E. H.; Yamashita, M.
  • Journal Title: Organometallics Volume: 33 Issue: 23 Pages: 6760-6770
  • DOI: 10.1021/om500585j
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Dimesitylboryl- and Amino-Substituted Acetylene Having Butatriene-Type Resonance Contribution (2014)
  • Author(s): Onuma, K.; Suzuki, K.; Yamashita, M.
  • Journal Title: Chem. Lett. Volume: 44 Issue: 3 Pages: 405-407
  • DOI: 10.1246/cl.141063
  • NAID: 130004868401
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Lowering Reduction Potential of Boron Compound by Substituent Effect of Boryl Group: One-Electron Reduction of Unsymmetrical Diborane(4) (2014)
  • Author(s): Asakawa, H. Lee, K. H.; Furukawa, K.; Lin, Z.; Yamashita, M.
  • Journal Title: Chem. Eur. J. Volume: 21 Issue: 11 Pages: 4267-4271
  • DOI: 10.1002/chem.201406609
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Aluminabenzene-Zirconium Complexes: Intramolecular Coordination of Chloride to Aluminium (2014)
  • Author(s): Nakamura, T.; Suzuki, K.; Yamashita, M.
  • Journal Title: Organometallics Volume: 34 Issue: 5 Pages: 813-816
  • DOI: 10.1021/acs.organomet.5b00073
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Rhombic Cyclobutadiene with a Boryl/Amino-Substitution Pattern: Boryl Group Migration Induced by Reaction with Water (2014)
  • Author(s): Onuma, K.; Suzuki, K.; Yamashita, M.
  • Journal Title: Org. Lett. Volume: 17 Issue: 5 Pages: 1212-1215
  • DOI: 10.1021/acs.orglett.5b00163
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Trial for anti-Markovnikov Hydration of 1-decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand (2014)
  • Author(s): Ogawa, H.; Yamashita, M.
  • Journal Title: Chem. Lett. Volume: 43
  • NAID: 130004868089
  • Peer Reviewed
• [Journal Article] Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen (2014)
  • Author(s): Dettenrieder, N.; Aramaki, Y;. Wolf, B.; Maichle-Mössmer, C.; Zhao, X.; Yamashita, M.; Nozaki, K.; Anwander, R.
  • Journal Title: Angew. Chem. Int. Ed. Volume: 53
  • Peer Reviewed
• [Journal Article] Oxidative Addition of a Strained C-C Bond onto Electron-Rich Rhodium(I) at Room Temperature (2013)
  • Author(s): Yusuke Masuda, Maki Hasegawa, Makoto Yamashita, Kyoko Nozaki, Naoki Ishida, and Masahiro Murakami
  • Journal Title: Journal of the American Chemical Society Volume: 135 Issue: 19 Pages: 7142-7145
  • DOI: 10.1021/ja403461f
  • Peer Reviewed
• [Journal Article] Oxygenation of a Ruthenium Complex Bearing A PBP-Pincer Ligand Induced a Formation of Boronato Ligand with A Weak Ru–O Bond (2013)
  • Author(s): Miyada, T.; Yamashita, M.
  • Journal Title: Organometallics Volume: 32 Issue: 19 Pages: 5281-5284
  • DOI: 10.1021/om400915x
  • Peer Reviewed
• [Journal Article] Isolation of PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C-H σ-Coordination as the Fourth Ligand (2012)
  • Author(s): Hasegawa, M.; Segawa, Y.; Yamashita, M.; Nozaki, K.
  • Journal Title: Angew. Chem. Int. Ed. Volume: 51 Issue: 28 Pages: 6956-6960
  • DOI: 10.1002/anie.201201916
  • Peer Reviewed
• [Journal Article] Tandem Hydroformylation/Hydrogenation of Alkenes to normal-Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst (2012)
  • Author(s): Takahashi, K. ; Yanashita, M. ; Nozaki, K.
  • Journal Title: Journal of the American Chemical Society Volume: 134 Issue: 45 Pages: 18746-18757
  • DOI: 10.1021/ja307998h
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of B-Heterocyclic π-radical and Its Reactivity as a Boryl Radical (2012)
  • Author(s): Yoshitaka Araraaki, Hideki Omiya, Makoto Yamashita, Koii
  • Journal Title: Jounal of the American Chemical Society Volume: 134 Issue: 49 Pages: 19989-19992
  • DOI: 10.1021/ja3094372
  • Peer Reviewed
• [Journal Article] Platinum Complexes Bearing a Boron-Based PBP Pincer Ligand : Synthesis, Structure, and Application as a Catalyst for Hydrosilylation of 1-Decene (2012)
  • Author(s): Ogawa, H.; Yamashita, M.
  • Journal Title: Dalton Trans. Volume: 46 Issue: 3 Pages: 625-629
  • DOI: 10.1039/c2dt31892j
  • Peer Reviewed
• [Presentation] テトラアリールジボラン(4)と水素分子の反応機構解析 (2017)
  • Author(s): 塚原菜那・浅川博祈・山下誠・Lee Ka-Ho・Lin Zhenyang
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶應大学日吉キャンパス
  • Year and Date: 2017-03-16
• [Presentation] Unusual reactivity of highly Lewis acidic diborane(4) compounds (2017)
  • Author(s): Makoto Yamashita
  • Organizer: the 11th Pure and Applied Chemistry International Conference 2017
  • Place of Presentation: Centra Government Complex Hotel & Convention Centre Chaeng Watthana
  • Year and Date: 2017-02-03
  • Int'l Joint Research / Invited
• [Presentation] Reactivity of Highly Lewis Acidic Diborane(4) Compounds (2017)
  • Author(s): Makoto Yamashita
  • Organizer: Main Group Chemistry Symposium
  • Place of Presentation: University of California, Los Angeles
  • Year and Date: 2017-01-14
  • Int'l Joint Research / Invited
• [Presentation] テトラアリールジボラン(4)による水素分子直接切断反応 (2016)
  • Author(s): 塚原菜那・浅川博祈・山下誠・Lee Ka-Ho・Lin Zhenyang
  • Organizer: 第43 回有機典型元素化学討論会
  • Place of Presentation: 仙台市民会館
  • Year and Date: 2016-12-09
• [Presentation] 豊かな社会を目指して元素を精密に操る合成化学 (2016)
  • Author(s): 山下 誠
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2016-11-16
  • Invited
• [Presentation] PNPピンサーIrおよびRh錯体を用いたアルカンの触媒的脱水素化反応 (2016)
  • Author(s): 中山 真・山下 誠
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2016-11-14
• [Presentation] イソシアニド存在下での含窒素複素環化合物と非対称ジボラン(4)との反応 (2016)
  • Author(s): 勝間 雄平・浅川 博祈・山下 誠
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2016-11-14
• [Presentation] テトラピロリルジボラン(4)の合成と反応性 (2016)
  • Author(s): 浅沼 秀治・山下 誠
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2016-11-14
• [Presentation] Reactivity of Unsymmetrical Diborane(4) toward Multiple Bond (2016)
  • Author(s): Makoto Yamashita
  • Organizer: The 17th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
  • Place of Presentation: Haeundae Centum Hotel
  • Year and Date: 2016-11-04
  • Int'l Joint Research / Invited
• [Presentation] 高ルイス酸性ジボラン(4)の特異な反応 (2016)
  • Author(s): 山下 誠
  • Organizer: 高分子討論会
  • Place of Presentation: 神奈川大学
  • Year and Date: 2016-09-14
  • Invited
• [Presentation] アルミニウム含有P-Al-PピンサーIr錯体の合成と性質 (2016)
  • Author(s): 渡邉聖也・山下誠
  • Organizer: 錯体化学会第66回討論会
  • Place of Presentation: 福岡大学七隈キャンパス
  • Year and Date: 2016-09-10
• [Presentation] PNPピンサーIrおよびRh錯体の合成とアルカン脱水素化触媒としての応用 (2016)
  • Author(s): 中山 真・山下 誠
  • Organizer: 錯体化学会第66回討論会
  • Place of Presentation: 福岡大学七隈キャンパス
  • Year and Date: 2016-09-10
• [Presentation] Bond Cleavage by Using Low-Coordinate Group 9 Metal Complexes Possessing a Boron-Based Pincer Ligand (2016)
  • Author(s): Makoto Yamashita
  • Organizer: The 1st Japan-Australia Joint Symposium on Coordination Chemistry
  • Place of Presentation: 福岡大学七隈キャンパス
  • Year and Date: 2016-09-10
  • Int'l Joint Research / Invited
• [Presentation] テトラアリールジボラン(o-tol)2B-B(o-tol)2の反応性 (2016)
  • Author(s): 塚原菜那・浅川博祈・山下誠
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島国際会議場
  • Year and Date: 2016-09-01
• [Presentation] イソシアニド存在下での非対称ジボランと含窒素複素環化合物の反応 (2016)
  • Author(s): 勝間雄平・浅川博祈・山下 誠
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島国際会議場
  • Year and Date: 2016-09-01
• [Presentation] テトラピロリルジボラン(4)の合成と反応性 (2016)
  • Author(s): 浅沼秀治・山下 誠
  • Organizer: 第27回基礎有機化学討論会
  • Place of Presentation: 広島国際会議場
  • Year and Date: 2016-09-01
• [Presentation] Chemistry of Highly Reactive Diborane(4): Bond Cleavage and Complicated Mechanism (2016)
  • Author(s): Makoto Yamashita
  • Organizer: CBC Seminar
  • Place of Presentation: Nanyang Technological University
  • Year and Date: 2016-08-19
  • Int'l Joint Research
• [Presentation] Reactivity of Unsymmetrical Diborane(4) toward Multiple Bond (2016)
  • Author(s): Makoto Yamashita
  • Organizer: International Symposium on Pure & Applied Chemistry 2016
  • Place of Presentation: Borneo Convention Centre Kuching
  • Year and Date: 2016-08-17
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and Application of Pyrrole-Based P-N-P Pincer Ir Complexes as Catalyst for Dehydrogenation of Alkane (2016)
  • Author(s): Shin Nakayama, Makoto Yamashita
  • Organizer: XXVII International Conference on Organometallic Chemistry
  • Place of Presentation: Melbourne Convention and Exhibition Centre
  • Year and Date: 2016-07-21
  • Int'l Joint Research
• [Presentation] Ortho-functionalization of nitrogen-containing heterocycle by using unsymmetrical diborane(4) and isocyanide (2016)
  • Author(s): Yuhei KATSUMA, Hiroki Asakawa, Makoto Yamashita
  • Organizer: XXVII International Conference on Organometallic Chemistry
  • Place of Presentation: Melbourne Convention and Exhibition Centre
  • Year and Date: 2016-07-21
  • Int'l Joint Research
• [Presentation] Convenient Synthesis of New Tetraaryldiborane(4) and Its Reduction (2016)
  • Author(s): Nana Tsukahara, Hiroki Asakawa, Makoto Yamashita
  • Organizer: XXVII International Conference on Organometallic Chemistry
  • Place of Presentation: Melbourne Convention and Exhibition Centre
  • Year and Date: 2016-07-21
  • Int'l Joint Research
• [Presentation] Dehydrogenation of Alkanes Catalyzed by Long-Tethered (P-B-P)-Pincer Iridium Complexes (2016)
  • Author(s): Enrique H. KWAN, Yasushi Jack KAWAI, Sei KAMAKURA, Hayato OGAWA, Makoto YAMASHITA
  • Organizer: XXVII International Conference on Organometallic Chemistry
  • Place of Presentation: Melbourne Convention and Exhibition Centre
  • Year and Date: 2016-07-21
• [Presentation] Synthesis of PNP-Ir Complexes and Their Application as Catalyst for Dehydrogenation of Alkanes (2016)
  • Author(s): Shin Nakayama, Makoto Yamashita
  • Organizer: ISHC-XX(第20回均一系触媒国際会議)
  • Place of Presentation: Kyoto Terrsa
  • Year and Date: 2016-07-14
  • Int'l Joint Research
• [Presentation] Dehydrogenation of Alkanes Catalyzed by Long-Tethered (P-B-P)-Pincer Iridium Complexes (2016)
  • Author(s): Enrique Huang Kwan, Yasushi Jack Kawai, Sei Kamakura, Hayato Ogawa, Makoto Yamashita
  • Organizer: ISHC-XX(第20回均一系触媒国際会議)
  • Place of Presentation: Kyoto Terrsa
  • Year and Date: 2016-07-14
  • Int'l Joint Research
• [Presentation] 高反応性diborane(4)の化学 (2016)
  • Author(s): 山下 誠
  • Organizer: 第33回東北大学無機・分析化学コロキウム
  • Place of Presentation: 東北大学川渡共同セミナーセンター
  • Year and Date: 2016-06-04
  • Invited
• [Presentation] iPrまたはtBuが置換したPNPピンサーIr錯体の合成とアルカン脱水素化触媒としての応用 (2016)
  • Author(s): 中山真、山下誠
  • Organizer: 第11回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2016-06-03
• [Presentation] Reactivity of Unsymmetrical Diborane(4) toward Multiple Bond and Its Complicated Mechanism (2016)
  • Author(s): Makoto Yamashita, Hiroki Asakawa, Chiemi Kojima, Yuhei Katsuma, Ka Ho Lee, Zhenyang Lin
  • Organizer: The 70th FUJIHARA Seminar
  • Place of Presentation: ザ・ルイガンズ スパ & リゾート
  • Year and Date: 2016-04-20
  • Int'l Joint Research / Invited
• [Presentation] テトラアリールジボラン(4)の簡便合成と還元反応 (2016)
  • Author(s): 塚原菜那・浅川博祈・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-27
• [Presentation] 非対称ジボラン(4)とイソシアニドの反応による含窒素複素環化合物のオルト位官能基化反応 (2016)
  • Author(s): 勝間雄平・浅川博祈・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] ビスムタベンゼンの反応 (2016)
  • Author(s): 石井拓弥・仲村太智・鈴木克規・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] ボリルリチウムを用いた新規非対称ジボランの合成と性質 (2016)
  • Author(s): 木須遥規・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] ボリルアニオンによる炭化水素の脱プロトン化 (2016)
  • Author(s): 大里拓人・奥野友里・石田真太郎・岩本武明・山下誠・野崎京子
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-26
• [Presentation] Long-Tethered P-B-P Ligands: Synthesis, Complexation and Catalysis (2016)
  • Author(s): KWAN HUANG, Enrique; KAWAI, Jack Yasushi; KAMAKURA, Sei; OGAWA, Hayato; YAMASHITA, Makoto
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] ピロール骨格を有するPNP ピンサーIr 錯体のアルカン脱水素化触媒としての応用 (2016)
  • Author(s): 中山真・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] 高周期13 族元素含有ベンゼンの合成と性質 (2016)
  • Author(s): 仲村太智・鈴木克規・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] ホウ素置換ホスフィノホスフィドの合成と性質 (2016)
  • Author(s): 浅見俊介・岡本匡史・鈴木克規・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-25
• [Presentation] 炭素繊維製造中間原料のアルキル化と続くマイクロ波による脱水および生成物の物性評価 (2016)
  • Author(s): 山﨑露菜・藤本翔・山形憲一・福田武司・山下誠
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス
  • Year and Date: 2016-03-24
• [Presentation] 含ホウ素ピンサー配位子を有する金属錯体： 結合切断および触媒反応への応用 (2016)
  • Author(s): 山下 誠
  • Organizer: Chemistry in Paradise ～合成化学が創る未来～
  • Place of Presentation: 琉球大学
  • Year and Date: 2016-03-11
  • Invited
• [Presentation] 石油化学を目指した有機金属化学と有機元素化学:目的志向基礎化学の開拓 (2016)
  • Author(s): 山下 誠
  • Organizer: 有機合成化学の可能性： 反応性と選択性をいかに制御するか
  • Place of Presentation: 名古屋大学
  • Year and Date: 2016-01-14
  • Invited
• [Presentation] Synthesis of boron- and nitrogen-containing conjugated systems by reaction of bis(silyl)pyrazines with haloboranes (2015)
  • Author(s): Mao Noguchi, Taiga Yurino, Hayato Tsurugi, Kazushi Mashima, Katsunori Suzuki, Makoto, Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-19
  • Int'l Joint Research
• [Presentation] Synthesis, structure and property of Ir and Rh complexes bearing an iPr-substituted PBP ligand (2015)
  • Author(s): Keita Tanoue・Makoto Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-19
  • Int'l Joint Research
• [Presentation] Synthesis of 9-aza-10-boraanthracene bearing transformable boron-chlorine bond synthesis of 9-aza-10-boraanthra- cene bearing transformable boron-chlorine bonds (2015)
  • Author(s): K. Suzuki, K. Hayashi, S. Nema, M. Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-18
  • Int'l Joint Research
• [Presentation] Synthesis and properties of alumina- and galla-benzenes (2015)
  • Author(s): Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] Synthesis, structure, photophysical property, and one-electron reduction of boryl-substituted diphosphene (2015)
  • Author(s): Shunsuke ASAMI, Masafumi OKAMOTO, Katsunori SUZUKI, Makoto YAMASHITA
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] Synthesis of phospha-, stiba-, and bismutha-benzenes via transmetallation of the 2,5-bis(silyl)-1-alumina-2,4-cyclohexadiene (2015)
  • Author(s): Takuya Ishii ・Taichi Nakamura・Katsunori Suzuki・Makoto Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] Bond cleavage by using low-coordinate group 9 metal complexes possessing a boron-based pincer ligand (2015)
  • Author(s): Makoto Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-17
  • Int'l Joint Research / Invited
• [Presentation] Base catalyzed bora-Brook rearrangement: the effects of solvent polarity, the backbone of boryl group, and counter cation of base toward reaction rate (2015)
  • Author(s): Haruki Kisu, Makoto Yamashita, Fumihiro Ito, Hirotoshi Sakaino, Kyouko Nozaki
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-16
  • Int'l Joint Research
• [Presentation] Regioselective diboration using unsymmetrical diborane(4) in the absence of transition metal catalyst (2015)
  • Author(s): Chiemi Kojima, Makoto Yamashita
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-16
  • Int'l Joint Research
• [Presentation] Long-tethered P-B-P ligand: Synthesis, complexation, and catalysis (2015)
  • Author(s): E. Kwan Huang, Y. Kawai, S. Kamakura, M. Yamashita.
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Basicity of non-solvated boryl anion: Deprotonation of benzene (2015)
  • Author(s): Takuto Osato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Makoto Yamashita, Kyoko Nozaki
  • Organizer: The Pacifichem2015
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] ボリルリチウムを用いた新規非対称ジボラン化合物の合成 (2015)
  • Author(s): 木須遥規・山下誠
  • Organizer: 第42回有機典型元素化学討論会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2015-12-04
• [Presentation] アニオン性インダベンゼンの合成と性質 (2015)
  • Author(s): 仲村太智・鈴木克規・山下誠
  • Organizer: 第42回有機典型元素化学討論会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2015-12-04
• [Presentation] ホウ素置換ジホスフェンとn-BuLiの反応 (2015)
  • Author(s): 浅見 俊介・山下 誠
  • Organizer: 第42回有機典型元素化学討論会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2015-12-04
• [Presentation] 高反応性ホウ素化合物の化学: ボリルアニオンと非対称ジボラン(4) (2015)
  • Author(s): 山下 誠
  • Organizer: 第42回有機典型元素化学討論会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2015-12-03
  • Invited
• [Presentation] Synthesis and Structures of Anionic Aluminabenzene and Their Zirconium Complexes (2015)
  • Author(s): Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita
  • Organizer: The 8th International Forum on Chemistry of Functional Organic Chemicals
  • Place of Presentation: The University of Tokyo
  • Year and Date: 2015-11-16
  • Int'l Joint Research
• [Presentation] Long-Tethered P-B-P Ligands: Synthesis, Complexation and Catalysis (2015)
  • Author(s): Enrique KWAN H, Yasushi KAWAI, Sei KAMAKURA, Makoto Yamashita
  • Organizer: The 8th International Forum on Chemistry of Functional Organic Chemicals
  • Place of Presentation: The University of Tokyo
  • Year and Date: 2015-11-16
  • Int'l Joint Research
• [Presentation] Synthesis of Anionic Aluminabenzene and Their Zirconium Complexes (2015)
  • Author(s): Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita
  • Organizer: Stimulating Meeting for Young Researchers in Chemistry on Stimuli-responsive Chemical Species
  • Place of Presentation: Kyoto University
  • Year and Date: 2015-11-12
  • Int'l Joint Research
• [Presentation] 新奇高反応性含ホウ素化合物の構造と反応性 (2015)
  • Author(s): 山下 誠
  • Organizer: ITbM/IGER Chemistry Workshop
  • Place of Presentation: 名古屋大学
  • Year and Date: 2015-10-30
  • Invited
• [Presentation] 高周期15 族ヘテロベンゼンの合成と構造 (2015)
  • Author(s): 石井拓弥・仲村太智・鈴木克規・山下 誠
  • Organizer: 第26回基礎有機化学討論会
  • Place of Presentation: 愛媛大学
  • Year and Date: 2015-09-26
• [Presentation] 溶媒和の無いボリルアニオンの発生とその塩基性 (2015)
  • Author(s): 大里拓人・奥野友里・石田真太郎・岩本武明・山下 誠・野崎京子
  • Organizer: 第26回基礎有機化学討論会
  • Place of Presentation: 愛媛大学
  • Year and Date: 2015-09-25
• [Presentation] ビスシリルピラジンとハロボランの反応によるホウ素、窒素含有共役系の合成およびその物性 (2015)
  • Author(s): 野口真緒・百合野大雅・劔 隼人・真島和志・鈴木克規・山下 誠
  • Organizer: 第26回基礎有機化学討論会
  • Place of Presentation: 愛媛大学
  • Year and Date: 2015-09-25
• [Presentation] 非対称ジボラン(4)を用いたピリジンのオルト位C-H 結合切断反応 (2015)
  • Author(s): 勝間雄平・浅川博祈・山下 誠
  • Organizer: 第26回基礎有機化学討論会
  • Place of Presentation: 愛媛大学
  • Year and Date: 2015-09-24
• [Presentation] iPr基が置換したPBP配位子を有するIr及びRh錯体の合成、構造、反応 (2015)
  • Author(s): 田上景太・山下誠
  • Organizer: 錯体化学会第６５回討論会
  • Place of Presentation: 奈良女子大学
  • Year and Date: 2015-09-21
• [Presentation] アルミナベンゼンとガラベンゼンの合成と性質 (2015)
  • Author(s): 仲村太智・鈴木克規・山下誠
  • Organizer: 第32回有機合成化学セミナー
  • Place of Presentation: ニューウェルシティ湯河原
  • Year and Date: 2015-09-15
• [Presentation] アルミナベンゼンとガラベンゼンおよびそのZr錯体の合成と性質 (2015)
  • Author(s): 仲村太智・鈴木克規・山下誠
  • Organizer: 第62回有機金属化学討論会
  • Place of Presentation: 関西大学千里山キャンパス
  • Year and Date: 2015-09-08
• [Presentation] Bond Cleavage by Using Low-Coordinate Group 9 Metal Complexes Possessing a Boron-Based Pincer Ligand (2015)
  • Author(s): Makoto Yamashita, Keita Tanoue, Yasushi Jack Kawai, Enrique Kwan-Huan
  • Organizer: 5th Asian Conference on Coordination Chemistry
  • Place of Presentation: The University of Hong Kong
  • Year and Date: 2015-07-15
  • Int'l Joint Research
• [Presentation] Synthesis and Structure of Aluminabenzene-Zirconium Complexes (2015)
  • Author(s): Taichi NAKAMURA, Katsunori SUZUKI, Makoto YAMASHITA
  • Organizer: 5th Asian Conference on Coordination Chemistry
  • Place of Presentation: The University of Hong Kong
  • Year and Date: 2015-07-13
  • Int'l Joint Research
• [Presentation] SYNTHESIS AND PROPERTIES OF REACTIVE DIBORANE(4) COMPOUNDS (2015)
  • Author(s): Makoto Yamashita
  • Organizer: ICHAC-11th
  • Place of Presentation: Caen, France
  • Year and Date: 2015-06-18
  • Int'l Joint Research / Invited
• [Presentation] Syntheses and Properties of diboryldiphosphene and diboryldiphosphene radical anion (2015)
  • Author(s): Shun-suke Asami, Masafumi Okamoto, Katsunori Suzuki, Makoto Yamashita
  • Organizer: ICHAC-11th
  • Place of Presentation: Caen, France
  • Year and Date: 2015-06-16
  • Int'l Joint Research
• [Presentation] SYNTHESIS AND PROPERTIES OF GROUP 13 ELEMENT-INCORPORATED BENZENES (2015)
  • Author(s): Taichi NAKAMURA, Katsunori SUZUKI, Makoto YAMASHITA
  • Organizer: ICHAC-11th
  • Place of Presentation: Caen, France
  • Year and Date: 2015-06-16
  • Int'l Joint Research
• [Presentation] Synthesis and Properties of Reactive Diborane(4) Compounds. (2015)
  • Author(s): Makoto Yamashita
  • Organizer: 第10回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research / Invited
• [Presentation] Bora-Brook rearrangement reaction and the effects of solvent polarity, the backbone of boryl group, and counter cation of base. (2015)
  • Author(s): Haruki Kisu, Makoto Yamashita, Fumihiro Ito, Hirotoshi Sakaino, Kyoko Nozaki
  • Organizer: 第10回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research
• [Presentation] Regioselective diboration using unsymmetrical diborane(4) in the absence of transition metal catalyst (2015)
  • Author(s): Chiemi Kojima, Makoto Yamashita
  • Organizer: 第10回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research
• [Presentation] Synthesis and properties of group 13 element-incorporated benzenes (2015)
  • Author(s): Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita
  • Organizer: 第10回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research
• [Presentation] Syntheses and Properties of diboryldiphosphene and diboryldiphosphene radical anion (2015)
  • Author(s): Shun-suke Asami, Masafumi Okamoto, Katsunori Suzuki, Makoto Yamashita
  • Organizer: 第10回有機元素化学セミナー
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-06-08
  • Int'l Joint Research
• [Presentation] ビスシリルピラジンとハロボランの反応によるホウ素、窒素含有共役系の合成、構造およびその物性 (2015)
  • Author(s): 野口真緒、百合野大雅、劒 隼人、真島和志、鈴木克規、山下 誠
  • Organizer: 第69回有機合成化学協会関東支部シンポジウム
  • Place of Presentation: 横浜国立大学常盤台キャンパス
  • Year and Date: 2015-05-16
• [Presentation] 1,5-ビスシリル-1,4-ジインのヒドロアルミニウム化によるヘテラベンゼンの合成 (2015)
  • Author(s): 石井拓弥、仲村太智、鈴木克規、山下 誠
  • Organizer: 第69回有機合成化学協会関東支部シンポジウム
  • Place of Presentation: 横浜国立大学常盤台キャンパス
  • Year and Date: 2015-05-16
• [Presentation] i-Pr基置換PBP配位子を有するIr錯体による触媒的アルカン脱水素移動反応 (2015)
  • Author(s): 田上景太・山下誠
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-28
• [Presentation] 側鎖の長いP-B-P ピンサー配位子を有するIr錯体を用いたアルカンの脱水素化反応 (2015)
  • Author(s): 河合泰志・鎌倉聖・山下誠
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-28
• [Presentation] アルミナベンゼン-ジルコニウム錯体の合成と構造 (2015)
  • Author(s): 仲村太智・鈴木克規・山下誠
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-28
• [Presentation] 非対称diborane(4)化合物pinB-BMes2の反応性とその高い電子受容性の起源 (2015)
  • Author(s): 浅川博祈・山下誠・古川貢・Lin Zhenyang・Lee Ka Ho・山下 誠
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] ホウ素、窒素置換シクロブタジエンの反応 (2015)
  • Author(s): 小沼郁・鈴木克規・山下誠
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] 溶媒和の無いボリルアニオンの反応性 (2015)
  • Author(s): 大里拓人・奥野友里・石田真太郎・岩本武明・山下誠・野崎京子
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] 遷移金属非存在下でのアルキンのジボリル化反応における位置選択性制御 (2015)
  • Author(s): 小島千絵美・山下誠
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] Bora-Brook 転位における対カチオン効果 (2015)
  • Author(s): 木須遥規・山下誠・伊東史裕・境野裕健・野崎京子
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] ホウ素置換アルコキシドのbora-Brook転位と速度論解析 (2014)
  • Author(s): 木須遥規・山下誠・伊藤史裕・境野裕健・野崎京子
  • Organizer: 第41回有機典型元素化学討論会
  • Place of Presentation: 宇部市文化会館ホール
  • Year and Date: 2014-11-28
• [Presentation] Synthesis of Long-Tethered P-B-P Ir complex Having a Boron-Containing Ligand and Its Application to Catalysic Dehydrogenation of Alkane (2014)
  • Author(s): Yasushi Kawai, Sei Kamakura, Makoto Yamashita
  • Organizer: Conference on C-C Bond Cleavage
  • Place of Presentation: Kyoto University
  • Year and Date: 2014-10-25
• [Presentation] Synthesis and Application of Ir Complexes Bearing an iPr-substituted PBP Ligand (2014)
  • Author(s): Keita Tanoue, Makoto Yamashita
  • Organizer: Conference on C-C Bond Cleavage
  • Place of Presentation: Kyoto University
  • Year and Date: 2014-10-25
• [Presentation] 非対称diborane(4)を用いたアルキンの直接ジボリル化反応における位置選択性制御 (2014)
  • Author(s): 小島千絵美・山下 誠
  • Organizer: 日本化学会秋季事業第4回CSJ化学フェスタ2014
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-10-14
• [Presentation] ホウ素置換アルコキシドのbora-Brook転位反応 (2014)
  • Author(s): 木須遥規・山下 誠・伊東史裕・境野裕健・野崎京子
  • Organizer: 日本化学会秋季事業第4回CSJ化学フェスタ2014
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-10-14
• [Presentation] 溶媒和のないボリルアニオンによるベンゼンの脱プロトン化 (2014)
  • Author(s): 大里拓人・奥野友里・石田真太郎・岩本武明・山下 誠・野崎京子
  • Organizer: 日本化学会秋季事業第4回CSJ化学フェスタ2014
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-10-14
• [Presentation] 溶媒和の無いボリルアニオンの合成と性質 (2014)
  • Author(s): 大里拓人・奥野友里・石田真太郎・岩本武明・山下誠・野崎京子
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学医学部百年講堂
  • Year and Date: 2014-09-25
• [Presentation] iPr基が置換したPBP配位子を有するIr錯体の合成・構造・アルカン脱水素化反応に対する触媒活性 (2014)
  • Author(s): 田上景太・山下誠
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学医学部百年講堂
  • Year and Date: 2014-09-24
• [Presentation] アニオン性アルミナベンゼン配位子を持つZr錯体の合成 (2014)
  • Author(s): 仲村太智, 鈴木 克規, 山下 誠
  • Organizer: 錯体化学会第64回討論会
  • Place of Presentation: 中央大学後楽園キャンパス
  • Year and Date: 2014-09-18
• [Presentation] アニオン性アルミナベンゼンの合成、構造解析およびその反応性 (2014)
  • Author(s): 仲村太智, 鈴木 克規, 山下 誠
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学川内北キャンパス
  • Year and Date: 2014-09-08
• [Presentation] 非対称ジボランを用いたアルキンのジボリル化反応 (2014)
  • Author(s): 小島千絵美、山下誠
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学川内北キャンパス
  • Year and Date: 2014-09-08
• [Presentation] 窒素ホウ素置換シクロブタジエンの合成と構造 (2014)
  • Author(s): 小沼郁、鈴木克規、山下誠
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学川内北キャンパス
  • Year and Date: 2014-09-07
• [Presentation] 非対称ジボラン(4)の1電子還元によるアニオンラジカルの合成と性質 (2014)
  • Author(s): 浅川 博祈、山下誠、Lee Ka Ho、Lin Ahenyang，古川貢
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学川内北キャンパス
  • Year and Date: 2014-09-07
• [Presentation] Diboration of Alkynes in the Absence of Transition Metals (2014)
  • Author(s): Chiemi KOJIMA, M. Yamashita
  • Organizer: International Meeting on Boron Chemistry (IMEBORON XV)
  • Place of Presentation: Prague
  • Year and Date: 2014-08-25
• [Presentation] SYNTHESIS AND STRUCTURE OF B,N-SUBSTITUTED CYCLOBUTADIENE (2014)
  • Author(s): Kaoru Onuma, Katsunori Suzuki, M. Yamashita
  • Organizer: International Meeting on Boron Chemistry (IMEBORON XV)
  • Place of Presentation: Prague
  • Year and Date: 2014-08-25
• [Presentation] Generation of Boryl Anion in Saturated Hydrocarbon Using Ternary Reducing Agent (2014)
  • Author(s): T. OSATO, Y. OKUNO, S. ISHIDA, T. IWAMOTO, M. Yamashita, K.NOZAKI
  • Organizer: International Meeting on Boron Chemistry (IMEBORON XV)
  • Place of Presentation: Prague
  • Year and Date: 2014-08-25
• [Presentation] Bora-Brook Rearrangement in Ambident Boryl-substituted Alkoxide: Migration of A Boryl Group from Carbon Atom to Oxigen Atom (2014)
  • Author(s): Haruki Kisu, Makoto Yamashita, Fumihiro Ito, Hirotoshi Sakaino, Kyoko Nozaki
  • Organizer: International Meeting on Boron Chemistry (IMEBORON XV)
  • Place of Presentation: Prague
  • Year and Date: 2014-08-25
• [Presentation] Synthesis and Reactivity of Unsymmetrical Diborane(4) Compound (2014)
  • Author(s): Hiroki Asakawa, Ka Ho Lee, Zhenyang Lin, Ko Furukawa, Makoto Yamashita
  • Organizer: International Meeting on Boron Chemistry (IMEBORON XV)
  • Place of Presentation: Prague
  • Year and Date: 2014-08-25
• [Presentation] Synthesis, Characterization, and Reactions of Aluminabenzene (2014)
  • Author(s): T. Nakamura, K. Suzuki, M. Yamashita
  • Organizer: the 248th ACS National Meeting
  • Place of Presentation: San Francisco
  • Year and Date: 2014-08-10
• [Presentation] Synthesis and property of Ir complexes bearing an iPr-substituted PBP ligand (2014)
  • Author(s): K. Tanoue, M. Yamashita
  • Organizer: the 248th ACS National Meeting
  • Place of Presentation: San Francisco
  • Year and Date: 2014-08-10
• [Presentation] Reactivity of Unsymmetrical Diborane(4) Compound (2014)
  • Author(s): Hiroki Asakawa, Ka Ho Lee, Zhenyang Lin, Ko Furukawa, Makoto Yamashita
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo
  • Year and Date: 2014-07-17
• [Presentation] Synthesis, Structure, and Catalytic Activity of Ir Complexes Bearing an iPr-Substituted PBP Ligand for Transfer Dehydrogenation of Alkanes (2014)
  • Author(s): Keita Tanoue, Makoto Yamashita
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo
  • Year and Date: 2014-07-17
• [Presentation] Synthesis of Anionic Aluminabenzene Bearing Aromatic and Ambiphilic Resonance Contribution (2014)
  • Author(s): Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo
  • Year and Date: 2014-07-15
• [Presentation] Generation of Boryl Anion in Saturated Hydrocarbon Using Ternary Reducing Agent (2014)
  • Author(s): T. OSATO, Y. OKUNO, S. ISHIDA, T. IWAMOTO, M. Yamashita, K.NOZAKI.
  • Organizer: XXVI International Conference on Organometallic Chemistry
  • Place of Presentation: Royton Sapporo
  • Year and Date: 2014-07-14
• [Presentation] 側鎖の長いP-B-P ピンサーIr 錯体の合成 (2014)
  • Author(s): 河合 泰志・鎌倉 聖・山下 誠
  • Organizer: 第3回 JACI/GSCシンポジウム
  • Place of Presentation: 東京国際フォーラム
  • Year and Date: 2014-05-23
• [Presentation] ホウ素および窒素置換基を有するシクロブタジエンの合成と構造 (2014)
  • Author(s): 小沼郁・鈴木克規・山下誠
  • Organizer: 第67回有機合成化学協会関東支部シンポジウム
  • Place of Presentation: 慶應義塾大学
  • Year and Date: 2014-05-17
• [Presentation] 遷移金属非存在下での末端アルキンのジボリル化反応 (2014)
  • Author(s): 小島千絵美、山下誠
  • Organizer: 第67回有機合成化学協会関東支部シンポジウム
  • Place of Presentation: 慶應義塾大学
  • Year and Date: 2014-05-17
• [Presentation] PBPピンサー型配位子を有する白金錯体を用いたアルケンのヒドロシリル化反応 (2013)
  • Author(s): 小川 隼人・山下 誠
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-25
• [Presentation] PBPピンサー配位子を有するRu錯体の合成と反応性 (2013)
  • Author(s): 宮田 卓真・山下 誠
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-25
• [Presentation] アルカン認識部位を持つcalix[4]arene誘導体の合成と性質 (2013)
  • Author(s): 嶋田 紘介・山下 誠
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-23
• [Presentation] シクロペンタジエノン配位子を有する一元系Ru触媒を用いた末端アルケンの直鎖選択的ヒドロホルミル化/水素化による直鎖アルコール合成 (2013)
  • Author(s): 高橋 講平・山下 誠・野崎 京子
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-23
• [Presentation] Rh/Ru混合触媒系を用いた末端アルケンの直鎖選択的ヒドロホルミル化/水素化による直鎖アルコール合成と速度論解析による反応機構研究 (2013)
  • Author(s): 高橋 講平・山下 誠・野崎 京子
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-23
• [Presentation] ホウ素置換ホスフィンの合成と性質 (2013)
  • Author(s): 浅見 俊介・岡本 匡史・山下 誠・鈴木 克規
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-22
• [Presentation] 新規非対称diborane(4)化合物の合成と性質 (2013)
  • Author(s): 浅川 博祈・山下 誠
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-22
• [Presentation] 含ホウ素複素環πラジカルの合成とボリルラジカルとしての反応性 (2013)
  • Author(s): 荒巻 吉孝・大宮 秀貴・山下 誠・中林 耕二・大越 慎一・野崎 京子
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 南草津
  • Year and Date: 2013-03-22
• [Presentation] 含ホウ素多座配位子を有する金属錯体の構造と機能 (2013)
  • Author(s): 山下 誠
  • Organizer: 分子研研究会 金属錯体機能の根源を探る～分子構造とその変化様式の探求最前線
  • Place of Presentation: 岡崎
  • Year and Date: 2013-03-14
  • Invited
• [Presentation] 特徴的な多座配位子を有する後周期遷移金属錯体の合成と性質および触媒機能 (2012)
  • Author(s): 山下 誠
  • Organizer: 2012 高分子・ハイブリッド材料研究センター(PHyM)若手フォーラム
  • Place of Presentation: 仙台
  • Year and Date: 2012-12-21
  • Invited
• [Presentation] ホウ素置換ホスフィンの合成と性質 (2012)
  • Author(s): 浅見 俊介・岡本 匡史・鈴木 克規・山下 誠
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: 盛岡
  • Year and Date: 2012-12-07
• [Presentation] Syntheses, Properties, and Catalytic Performance of Late-Transition Metal Complexes Bearing A Characteristic Multidentate Ligand (2012)
  • Author(s): Makoto Yamashita
  • Organizer: 8th RIKEN International Symposium “Frontiers of Organometallic Chemistry”
  • Place of Presentation: 和光
  • Year and Date: 2012-11-30
  • Invited
• [Presentation] Syntheses and Properties of Late Transition Metal Complexes Bearing a PBP-Pincer Ligand (2012)
  • Author(s): Makoto Yamashita
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山
  • Year and Date: 2012-09-21
• [Presentation] PBPピンサーRu錯体の合成と性質 (2012)
  • Author(s): 宮田 卓真・山下 誠
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山
  • Year and Date: 2012-09-21
• [Presentation] PBPピンサー型配位子を有する白金錯体の合成と性質 (2012)
  • Author(s): 小川 隼人・山下 誠
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山
  • Year and Date: 2012-09-21
• [Presentation] 新規含ホウ素複素環ラジカルの合成と性質 (2012)
  • Author(s): 荒巻 吉孝・大宮 秀貴・山下 誠・中林 耕二・大越 慎一・野崎 京子
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都
  • Year and Date: 2012-09-20
• [Presentation] Syntheses and Properties of Transition Metal Complexes Bearing a Boron-Based PBP Pincer Ligand:Effect of Boron Atom (2012)
  • Author(s): Makoto Yamashita
  • Organizer: 25th International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon
  • Year and Date: 2012-09-05
• [Presentation] Tandem Hydroformylation/Hydrogenation of Terminal Alkenes to n-Alcohol Using a Rh/Ru Dual Catalyst System (2012)
  • Author(s): Kohei Takahashi, Makoto Yamashita, Kyoko Nozaki
  • Organizer: 25th International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon
  • Year and Date: 2012-09-04
• [Presentation] Syntheses and Properties of Platinum Complexes Bearing a PBP-Pincer Ligand (2012)
  • Author(s): Hayato Ogawa, Makoto Yamashita
  • Organizer: 25th International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon
  • Year and Date: 2012-09-04
• [Presentation] Synthesis and Properties of Potassium Diaminodihydroborate with Two Tethers (2012)
  • Author(s): Takuma Miyada, Makoto Yamashita
  • Organizer: 25th International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon
  • Year and Date: 2012-09-04
• [Presentation] Syntheses and Properties of Late-Metal Complexes Bearing a Boron-Based Pincer Ligand
  • Author(s): Makoto Yamashita
  • Organizer: "Heterobimetallic Compounds and their Chemistry" in 245th ACS National Meeting
  • Place of Presentation: New Orleans
  • Invited
• [Presentation] Catalytic Hydrosilylation of Alkene Using Platinum Complexes Bearing a PBP Pincer Ligand
  • Author(s): Hayato Ogawa, Makoto Yamashita
  • Organizer: OMCOS 17
  • Place of Presentation: Fort collins
• [Presentation] 電子的に非対称なジボラン(4)によるイソニトリルのCN三重結合切断反応
  • Author(s): 浅川 博祈・山下 誠
  • Organizer: 第24回基礎有機化学討論会
  • Place of Presentation: 学習院大学目白キャンパス
• [Presentation] Synthesis and Property of a Mesityl-Substituted Unsymmetrical Diborane(4)
  • Author(s): H. Asakawa, M. Yamashita
  • Organizer: EUROBORON6
  • Place of Presentation: Radziejowice
• [Presentation] 新規非対称ジボランの合成とCOおよびCN三重結合との反応性
  • Author(s): 浅川 博祈・山下 誠
  • Organizer: 日本化学会秋季事業第3回CSJ化学フェスタ2013
  • Place of Presentation: タワーホール船堀
• [Presentation] 側鎖の長いPBPピンサーIr錯体の合成
  • Author(s): 河合 泰志, 鎌倉 聖, 山下 誠
  • Organizer: 錯体化学会第63回討論会
  • Place of Presentation: 琉球大学
• [Presentation] 非対称ジボラン(4)と一酸化炭素およびイソニトリルの反応
  • Author(s): 浅川 博祈・山下 誠
  • Organizer: 第40回 有機典型元素化学討論会
  • Place of Presentation: 近畿大学
• [Presentation] 新規非対称diborane(4)を用いた三重結合切断反応と機構解析
  • Author(s): 浅川博祈・山下誠
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] 遷移金属非存在下での末端アルキンのジボリル化反応
  • Author(s): 小島千絵美・山下誠
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] 側鎖の長いP-B-PピンサーIr錯体の合成
  • Author(s): 河合泰志・鎌倉聖・山下誠
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] ホウ素化合物におけるホウ素置換基の効果
  • Author(s): 山下 誠
  • Organizer: 理研セミナー
  • Place of Presentation: 理化学研究所
  • Invited
• [Presentation] 化学とのお付き合い:夢を追いつつ学生と共に面白く生きる
  • Author(s): 山下 誠
  • Organizer: 第２回卓越拠点有機若手ワークショップ
  • Place of Presentation: 京都大学
  • Invited
• [Presentation] Metal-Free Triple Bond Scission Using Unsymmetrical Diborane(4)
  • Author(s): Makoto Yamashita
  • Organizer: The 1st International Symposium for Young Chemists on Stimuli-Responsive Chemical Species for the Creation of Functional Molecules
  • Place of Presentation: 五反田
  • Invited
• [Presentation] 新奇ホウ素化合物が拓く新しい化学:ホウ素求核剤の化学と非対称ジボランによる三重結合切断反応
  • Author(s): 山下 誠
  • Organizer: 山口大学常盤台コロキアム
  • Place of Presentation: 山口大学
  • Invited
• [Book] Synthesis and Application of Organoboron Compounds (2015)
  • Author(s): Yamashita, M.; Nozaki, K.
  • Total Pages: 325
  • Publisher: Springer International Publishing
• [Remarks] 名古屋大学大学院工学研究科有機・高分子化学専攻有機元素化学研究室(山下誠教授)
  • URL: http://oec.chembio.nagoya-u.ac.jp/
• [Remarks] 中央大学理工学部応用化学科有機元素化学研究室研究内容
  • URL: http://www.chem.chuo-u.ac.jp/~element/research.html
• [Remarks] 中央大学理工学部応用化学科有機元素化学研究室発表論文
  • URL: http://www.chem.chuo-u.ac.jp/~element/publications.html
• [Remarks] 有機元素化学研究室発表論文
  • URL: http://www.chem.chuo-u.ac.jp/~element/publications.html
• [Remarks] 有機元素化学研究室学会発表リスト
  • URL: http://www.chem.chuo-u.ac.jp/~element/presentations.html
• [Remarks] 有機元素化学研究室
  • URL: http://www.chem.chuo-u.ac.jp/~element/
• [Remarks] 中央大学理工学部応用化学科有機元素化学研究室
  • URL: http://www.chem.chuo-u.ac.jp/~element/
• [Patent(Industrial Property Rights)] 有機電子デバイス及びその製造方法 (2016)
  • Inventor(s): 福田 武司・菱沼 賢智・山下 誠・山形 憲一
  • Industrial Property Rights Holder: 福田 武司・菱沼 賢智・山下 誠・山形 憲一
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2016-034062
  • Filing Date: 2016-02-25