Budget Amount *help |
¥37,440,000 (Direct Cost: ¥28,800,000、Indirect Cost: ¥8,640,000)
Fiscal Year 2016: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2015: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2014: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2013: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2012: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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Outline of Final Research Achievements |
To develop the novel catalysts utilizing the coordination/oxidation state diversity of heavy typical elements, the design, synthesis, and elucidation of the properties of novel low-valent heavy group 13 and 14 compounds and ligand systems containing heavy group 15 elements were investigated. We have revealed the synthesis of novel low-valent phosphorus ligands, the application of triphospha[3]radialene as a ligand, the synthesis of novel silyliumylidene species, novel transformation reactions using digermyne, and the activation of dihydrogen by aluminum compounds at ordinary temperatures and pressures.
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