| Budget Amount *help |
¥36,790,000 (Direct Cost: ¥28,300,000、Indirect Cost: ¥8,490,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2014: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2012: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
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| Outline of Final Research Achievements |
Model complexes of oxy-PHM were prepared and examined in dioxygen reactivity. The formed mononuclear Cu(II)-end-on-superoxide complexes exhibited C-H bond hydroxylation at the benzylic position of a ligand phenetyl side arm at higher temperature.
As model complexes of molybdoenzymes, molybdenum complexes having a terminal oxide, sulfide, and selenide group were prepared and the crystal structure, electronic structures, and reactivities were examined in a systematic way.
Model complexes of iron enzymes were synthesized and the reactivities were examined in the oxidation reactions. The complexes were found to catalyze alkene dihydroxylation with hydrogen peroxide as a terminal oxidant. In the presence of amines, the alkenes were converted to aminoalcohols. When 1,5-dienes were employed as the substrate, the oxidative cyclization proceeded to yield the corresponding tetrahydrofurans.
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