| Budget Amount *help |
¥57,070,000 (Direct Cost: ¥43,900,000、Indirect Cost: ¥13,170,000)
Fiscal Year 2017: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2016: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2015: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2014: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2013: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
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| Outline of Final Research Achievements |
In this project, we focused on the contiguous π-coordination bonds which are formed at the molecular interface between the pπ-conjugated unsaturated hydrocarbons and the metal assemblies. We developed a synthetic method to construct the extended contiguous π-coordination bonds, that enabled construction of one-dimensional metal chain sandwich compounds having ten metal atoms. We also studied the two-dimensional contiguous multiple π-coordination bonds. Several aromatic ligands were successfully introduced on a trinuclear cluster face, and the ligand substitution mechanism was elucidated. Furthermore, we elucidated the bonding nature of the contiguous π-coordination bonds through experimental and theoretical analyses.
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