| Budget Amount *help |
¥70,720,000 (Direct Cost: ¥54,400,000、Indirect Cost: ¥16,320,000)
Fiscal Year 2017: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2016: ¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2015: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2014: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2013: ¥13,780,000 (Direct Cost: ¥10,600,000、Indirect Cost: ¥3,180,000)
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| Outline of Final Research Achievements |
Electric measurement of single molecules which pi-systems were altered by external stimuli such as heat, light, acid, etc. was planned. Bicyclo[2.2.2]octadiene ring system was chosen as such an external-stimulus-changeable moiety and porphyrin, and hexapyrrolohexaazacoronene (HPHAC) were chosen as such pi-systems. In bisthiaporphyrins fused with BCOD and benzene rings, their macrocyclic ring current routes were altered from on a long axis to on short axes by protonation.
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