| Budget Amount *help |
¥36,270,000 (Direct Cost: ¥27,900,000、Indirect Cost: ¥8,370,000)
Fiscal Year 2018: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2017: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2016: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2015: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2014: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
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| Outline of Final Research Achievements |
In recent years, non-planar extended pi-conjugated compounds have attracted great attention because of their unique physical properties and functions originated from steric distortion and chirality. However, due to the large distortion and steric hindrance of these compounds, the synthesis of designed new compounds is often challenging. Therefore, in this study, we examined the development of new highly active transition-metal complexes as catalysts and their application to the synthesis of novel non-planar extended pi-conjugated compounds. As a result, we succeeded in synthesizing various new non-planar extended pi-conjugated compounds (helicenes, cyclophanes, cycloparaphenylenes, etc.). We also succeeded in their catalytic asymmetric syntheses and chemical modifications that allow their organization and assembling.
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