| Budget Amount *help |
¥48,880,000 (Direct Cost: ¥37,600,000、Indirect Cost: ¥11,280,000)
Fiscal Year 2018: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2017: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2016: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2015: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2014: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
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| Outline of Final Research Achievements |
In this study, based on two self-assembly motifs, i.e., "stackable nanorings" and "discrete nanorings", we examined the introduction of photoresponsive sites and the mixing of different molecules, and succeeded in constructing various complex self-assembly systems. By collaborating with many researchers in the pi-figuration, we were able to perform structural analyses that were previously inaccesible. Supramolecular polymers obtained by further developing discrete nanorings containing intrinsic curvatures not only have higher order structures reminiscent of proteins, but also are innovative nanomaterials that exhibit external stimulation or spontaneous unfolding/folding phenomena. In the future, further development of this system is expected as unprecedented “topological supramolecular polymers” .
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