| Budget Amount *help |
¥54,730,000 (Direct Cost: ¥42,100,000、Indirect Cost: ¥12,630,000)
Fiscal Year 2018: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2017: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2016: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2015: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2014: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
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| Outline of Final Research Achievements |
The gold nanoparticle networks with DAEs, which have same core structures but have different positions of thiol groups, were prepared and the change in conductance upon light irradiation was measured. For two DAEs, the direction of the photoswitching was opposite to show the importance of the topology of pi-conjugation.
Two-dimensional self-assembly of a 2-thienyl-type diarylethene was studied by STM at the liquid/solid interface by analyzing the concentration dependence of surface coverage. It was revealed that the assembling process of this compound was highly cooperative. By using high cooperative system, high sensitive photochemical control of the assembly was also demonstrated.
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