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Development of Efficient Conversion Processes for Victorian Brown Coal

Research Project

Project/Area Number 01044015
Research Category

Grant-in-Aid for international Scientific Research

Allocation TypeSingle-year Grants
SectionJoint Research
Research InstitutionTohoku University

Principal Investigator

NISHIYAMA Yoshiyuki (1990)  Chemical Research Inst. of Non. Aqueous Solutions, Tohoku Univ., 非水容液化学研究所, 教授 (10006299)

西山 よし行  東北大学, 非水溶液化学研究所, 教授

Co-Investigator(Kenkyū-buntansha) SHIBAOKA Michio  Division of Coal Technology, CSIRO, 顧問
PERRY G.J.  CCV研究所, 研究所長
LYNCH Leo J.  Division of Coal Technology, CSIRO, 石炭部, 部長代理
SMITH Ian W.  Division of Coal Technology, CSIRO, 石炭部, 副部長
KAWAMURA Kunio  Faculty of Engineering, Tohoku Univ., 工学部, 助手 (50204772)
ALLARDICE David J.  Coal Corporation of Victoria, 部長
FUTAMURA Shigeru  Faculty of Engineering, Univ. of Tokyo, 工学部, 助手 (60165446)
HAGA Tetsuya  Chemical Research Inst. of Non. Aqueous Solutions, Tohoku Univ., 非水容液化学研究所, 助手 (50134060)
JACKSON W. Roy  Department of Chemistry, Monash Univ., 化学科, 教授
LARKINS Frank P.  Department of Chemistry, Univ. of Tasmania, 化学科, 教授
FUJITSU Horoshi  Inst. of Advanced Material Study, Kyushu Univ., 機能物質科学研究所, 助教授 (00038605)
ITO Osamu  Chemical Research Inst. of Non. Aqueous Solutions, Tohoku Univ., 非水容液化学研究所, 助教授 (30006332)
OHTSUKA Yasuo  Chemical Research Inst. of Non. Aqueous Solutions, Tohoku Univ., 非水容液化学研究所, 助教授 (20091663)
YOKOYAMA Susumu  Faculty of Engineering, Hokkaido Univ., 工学部, 助教授 (30001291)
OKUWAKI Akitsugu  Faculty of Engineering, Tohoku Univ., 工学部, 教授 (70005320)
MOCHIDA Isao  Inst. of Advanced Material Study, Kyushu Univ., 機能物質科学研究所, 教授 (20037758)
SANADA Yuzo  Faculty of Engineering, Hokkaido Univ., 工学部, 教授 (50109485)
KAMIYA Yoshio  Faculty of Engineering, Science Univ. of Tokyo, 工学部, 教授 (40010764)
TAMAI Yasukatsu  Faculty of Engineering, Science Univ. of Tokyo, 工学部, 教授 (80006288)
MATSUDA Minoru  Chemical Research Inst. of Non. Aqueous Solutions, Tohoku Univ., 非水容液化学研究所, 教授 (90006297)
AGNEW J.B.  Adelaide大学, 化学工学科, 教授
AGNEW John B.  Department of Chemical Engineering, niv. of Adelaide
PERRY Geoffrey J.  Research Facility, Coal Corporation of Victoria
Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 1990: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1989: ¥3,500,000 (Direct Cost: ¥3,500,000)
KeywordsVictorian Brown Coal / Coal Liquefaction / Coal Pyrilysis / Coal Gasification / Active Carbon / Coal Oxidation / Coal Structure
Research Abstract

The present joint research which aims at the development of highly efficient conversion processes for Victorian Brown coal has started in 1988 and, in that year, five researchers were sent to Australian institutions to do experimental works. The results obtained were further developed at the related Universities in Japan in 1989 and 1990. In addition, two researchers were sent to Australia by the present program. For consultation, six Australian scientists were invited to Japan in 1989 and four Japanese members visited Australia in 1990. In each time, the program was discussed and views on coal research were exchanged. Valuable results were obtained as follows.
(1) The upgrading of liquefied oils was studied and high surface area ceramics were shown to be appropriate for the support of CoMo catalyst.
(2) An analysis of liquefaction of coals using model substances indicated that origin of long-chain alkanes and alkenes was aromatic esters.
(3) Catalysts in flash pyrolysis were found to promote the decomposition of oxygen-containing functional groups on coal surfaces as well as secondary reactions in gas phase.
(4) Changes in surface state of brown coal during heating were investigated and the role of these on the catalytic gasification of char was elucidated.
(5) A new process for producing a high performance active carbons from brown coal for removing SOx and NOx was developed.
(6) Proton Magnetic Resonance Thermal Analysis was used to see the changes in coal structure during heating and new mobile phases were detected. Also the reaction processes between brown coal and added materials were clarified.
(7) Products from oxidation of brown coal in alkaline medium with oxygen was separated effectively using high performance liquid chromatography.
The program gave prospect of new conversion processes and greatly contributed to the mutual understanding between the two parties.

Report

(1 results)
  • 1990 Final Research Report Summary
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] S.Futamura,W.R.Jackson, G.J.Stray,S.C.Lim,and F.P.Larkins: "Thermolysis and Hydrogenolysis of Model Organic Compounds Relevant to the Production of Longーchain Hydrocarbons from Reactions of Coals" Proceedings 1989 International Conference on Coal Science. 2. 891-894 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Yokoyama,H.Mishima,M.Satou,and Y.Sanada: "Chemical Structural Change in Product Oil during Upgrading Reaction for SRCーII by GCーMS" Proceedings 1989 International Conference on Coal Science. 2. 1119-1122 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M.Satou,S.yokoyama,and Y.Sanada: "Distribution in CoalーDerived Oil of Aromatic Hydroarbon Compound Types Grouped According to Boiling Point by High Performance Liquid Chromatography/Mass Spectrometry" FUEL. 68. 1048-1051 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Futamura,S.Koyanagi and Y.Kamiya: "Hydrogen Shuttling Effect of Azaaromatics in the Hydrogenolysis of the Diarylmethane" FUEL. 68. 130-132 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Futamura, S.Koyanagi and Y.Kamiya: "Additive Effects of SolventーRefined Coal Fractions and Aromatic Compounds on the Hydrogenolysis of Diarylmethanes" ENERGY & FUELS. 3. 381-385 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Yokoyama,H,Mishima,M.Satou,and Y.Sanada: "Unsubstituted Polycyclic Aromatic Hydrocarbons Produced by Catalytic Hydropyrolysis of Coal Liquids" ENERGY & FUELS. 3. 398-402 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Futamura,K.Fujimoto and Y.Kamiya: "Catalysis of αーFe and Fe^<1ーX>S toward the Hydrogenolysis of Transーstilbene in Hydroaromatic Hydrocarbon Solvents" Bull.Chem.Soc.Jpn.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 二タ村 森,小柳 精也,神谷 佳男: "9ーベンジルフェナントレンの水素化分解に及ぼす鉄系触媒と溶媒の効果" 燃料協会誌.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Yokoyama,Y.Sanada,S.Supaluknari,M.E.Hughes and F.P.Larkins: "catalyst Activity for Upgrading a Model Feedstock and a Coal Derived Liquid" ENERGY & FUELS.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Fujitsu,I.Mochida,V.Verheyen,G.J.Perry and D.J.Allardice: "Preparation of High Performance Active Carbon from Brown Coal" FUEL.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Haga,Y.Nishiyama,P.K.Agarwal and J.B.Agnew: "Surface Structural Changes of Coal upon Heat Treatment at 200ー900℃" ENERGY & FUELS. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Haga,M.Sato,Y.Nishiyama,P.K.Agarwal and J.B.Agnew: "Influence of Structural Parameters of Coal Char on Kー and CaーCatalyzed Steam Gasifications" ENERGY & FUELS. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] R.Sakurovs,L.J.Lynch and O.Ito: "The Effect of Elemental Sulfur on the Fusibility of Coals" Proceedings 4th Australian Coal Science Conference. 1-10 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] W.A.Barton,O.Ito and L.J.Lynch: "Extraction and Swelling of Bituminous Coals with Mixed Solvents" Proceedings 4th Australian Coal Science Conference. 289-297 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Kawamura,A.Okuwaki,T.V.Verheyen and G.J.Perry: "HPLC Analysis and Its Separation Behavior of Aromatic Carboxylic Acids from Oxidation of Loy Yang Coal in the Elevated Temperature Alkaline Solution" FUEL.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Futamura, W. R. Jackson, G. J. Stray, S. C. Lim, and F. P. Larkins: "Thermolysis and Hydrogenolysis of Model Organic Compounds Relevant to the Production of Long-Chain Hydrocarbons from Reactions of Coals" Proceedings 1989 International Conference on Coal Science. 2. 891-894 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Yokoyama, H. Mishima, M. Satou, and Y. Sanada: "Chemical Structural Change in Product Oil during Upgrading Reaction for SRC-II by GC-MS" Proceedings 1989 International Conference on Coal Science. 2. 1119-1122 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Satou, S. Yokoyama, and Y. Sanada: "Distribution in Coal-Derived Oil of Aromatic Hydrocarbon Compound Types Grouped According to Boiling Point by High Performance Liquid Chromatography/Mass Spectrometry" FUEL. 68. 1048-1051 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Futamura, S. Koyanagi, and Y. Kamiya: "Hydrogen Shuttling Effect of Azaaromatics in the Hydrogenolysis of the Diarylmethane" FUEL. 68. 130-132 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Futamura, S. Koyanagi, and Y. Kamiya: "Additive Effects of Solvent-Refined Coal Fractions and Aromatic Compounds on the Hydrogenolysis of Diarylmethanes" ENERGY & FUELS. 3. 381-385 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Yokoyama, H. Mishima, M. Satou, and Y. Sanada: "Unsubstituted Polycyclic Aromatic Hydrocarbons Produced by Catalytic Hydropyrolysis of Coal Liquids" ENERGY & FUELS. 3. 398-402 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Futamura, K. Fujimoto, and Y. Kamiya: "Catalysis of alpha-Fe and Fe_<1-X>S toward the Hydrogenolysis of Trans-stilbene in Hydroaromatic Hydrocarbon Solvents" Bull. Chem. Soc. Jpn.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Futamura, S. Koyanagi, and Y. Kamiya: "Effects of Iron-group Catalysts and Solvents on the Hydrogenolysis of 9-Benzylphenanthrene" J. Fuel Soc. Jpn.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Yokoyama, Y. sanada, S. Supaluknari, M. E. Hughes, and F. P. Larkins: "Catalyst Activity for Upgrading a Model Feedstock and a Coal Derived Liquid" ENERGY & FUELS.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Fujitsu, I. Mochida, T. V. Verheyen, G. J. Perry, and D. J. Allardice: "Preparation of High Performance Active Carbon from Brown Coal" FUEL.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Haga, Y. Nishiyama, P. K. Agarwal, and J. B. Agnew: "Surface Structural Changes of Coal upon Heat Treatment at 200-900^゚C" ENERGY & FUELS. in press. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Haga, M. Sato, Y. Nishiyama, P. K. Agarwal, and J. B. Agnew: "Influence of Structural Parameters of Coal Char on K- and Ca-Catalyzed Steam Gasifications" ENERGY & FUELS. in press. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] R. Sakurovs, L. J. Lynch, and O. Ito: "The Effect of Elemental Sulfur on the Fusibility of Coals" Proceedings 4th Australian Coal Science Conference. 1-10 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] W. A. Barton, O. Ito, and L. J. Lynch: "Extraction and Swelling of Bituminous Coals with Mixed Solvents" Proceedings 4th Australian Coal Science Conference. 289-297 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Kawamura, A. Okuwaki, T. V. Verheyen, and G. J. Perry: "HPLC Analysis and Its Separation Behavior of Aromatic Carboxylic Acids from Oxidation of Loy Yang Coal in the Elevated Temperature Alkaline Solution" FUEL.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary

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Published: 1989-04-01   Modified: 2016-04-21  

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