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Structure and Dynamics of Superionic Conductors

Research Project

Project/Area Number 01302014
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 固体物性
Research InstitutionTohoku University

Principal Investigator

ISHIGAME M.  Tohoku University, Research Institute for Scientific Measurements, Professor, 科学計測研究所, 教授 (40006143)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI M.  Niigata University, Faculty of Science, Associate Professor, 理学部, 助教授 (20018881)
ISHII T.  Okayama University, Faculty of Engineering, Assistant Professor, 工学部, 講師 (90033240)
OHACHI T.  Doshisha Univeristy, Faculty of Engineering, Professor, 工学部, 教授 (40066270)
HOSHINO S.  The University of Tokyo, , Emeritsu Professor, 名誉教授 (40013453)
MATSUBARA T.  Okayama univeristy of Science, Faculty of Science, Professor, 理学部, 教授 (60025202)
池沢 幹彦  東北大学, 科研, 教授 (10004334)
上田 顕  京都大学, 工学部, 教授 (20025852)
Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥4,700,000 (Direct Cost: ¥4,700,000)
Fiscal Year 1991: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1990: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1989: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsSuperionic Conductors / Solid Electrolytes / Ionic Conduction / Lattice Vibration / mixed Conductors / Lattice Dynamics / Light Scattering / Structure Analysis
Research Abstract

Many attempts have been made experimentally and theoretically to understand the properties of the ionic conduction in superionic conductors by physicists, chemists and material researchers. The purpose of this research project is as follows : Fundamental properties of superionic materials are discussed along the reseachers of the different fields. And then, we search the new direction of future study for understanding. the structure and dynamical properties of the superionic conductors. We had three meetings at Nasu (1989), Norikura (1990) and Kawatabi (1991), and 73 papers were presented. Stimulative and active discussions were made in these meeting, and we got much useful information about the problem. Especially, new experimental and theoretical studies were brought us the following good approach to understand the properties of the superionic materials : (1) The micro-structure or local-structure we re determined by the optical technique. (2) The properties were analysed as a prototype of the disorder system. (3) The influence of the core-electrons on the conduction ions should be taken into account in the theoretical works. (4) New materials were made by using new techniques. Through those discussions, we obtained a conclusion. Namely, following investigations are necessary for an advance to the next step of the study and for the understanding the conduction mechanism : (1) The study using the crystals in which the fundamental physical and chemical properties were well understood. (2) The development of the new materials of thin film and/or of layered structure (super-lattice structure) with clean surface and/or interface, and the measurements using those developed materials. (3) The study of the electronic states of core-electrons of the conduction ions.

Report

(4 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • 1989 Annual Research Report
  • Research Products

    (34 results)

All Other

All Publications (34 results)

  • [Publications] M.Ishigame: "Light scattering in superionic conductors" Solid State Ionics. 47. 1-34 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S.Hoshino: "Structure and dynamics of solid state ionics" Solid State Ionics. 48. 179-202 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Kobayashi: "Review on structural and dynamical properties of silver chalcogenide" Solid State Ionics. 39. 121-149 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Tatsumisako: "Stabilization of superionic α-Agl at room temperature in a glass matrix" Nature. 354. 217-218 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K.Wakamura: "Observation of anomalously increasing phonon damping constant in the β phase of the fast-ionic conductor Ag_3SI" Phys.Rev.B41. 2758-2762 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H.Yugami: "Local Structure in superionic conductor Y^<3+>-doped CeO_2 studied by site selective spectroscopy" Phys.Rev.B44. 4862-4871 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 上田 顯: "コンピュ-タシミュレ-ション" 朝倉書店, 220 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 星埜 禎男: "物理学最前線28巻 超イオン導電体" 共立出版, 51 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. ISHIGAME: "Light scattering in superionic conductors" Solid State Ionics. 47-1. 1-34 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. HOSHINO: "Structure and dynamics of solid state ionics" Solid State Ionics. 48-3, 4. 178-202 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. KOBAYASHI: "Review on structural and dynamical properties of silver chalcogenide" Solid State Ionics. 39-3, 4. 121-149 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. TATSUMISAKO: "Stabilization of superionic alpha AgI at room temperature in a glass matrix" Nature. 354-6350. 217-218 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K. WAKAMURA: "Observation of anomalously increasing phonon dumping constant in the beta phase of the fast-ionic conductor Ag_3SI" Phys. Rev. B 41-5. 2758-2762 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Yugami: "Local structure in superionic conductor Y^<3+>-doped CeO_2 studied by site selective spectroscopy" Phys. Rev. B 44-10. 4862-4871 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Ishigame: "Light scattering in superionic conductors" Solid State Ionics. 47. 1-34 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Hoshino: "Structure and dynamics of solid state ionics" Solid State Ionics. 48. 179-202 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Tatsumisako: "Stabilization of superionic α‐Agl at room temperature in a glass matrix" Nature. 354. 217-218 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Kobayashi: "Molecular dynamics studies of molten Agl II. Fractal behavior of diffusion tragectory" J. Phys. Soc. Jpn.60. 4078-4082 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Ishii: "Kink hopping in one‐dimensional ionic conductors" J. Phys. Soc. Jpn.60. 4205-4212 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 湯上 浩雄: "超イオン導電体の基礎と応用への期待" 日本物理学会誌(BUTSURI). 47. 92-98 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 星埜 貞男: "物理学最前線28巻 超イオン導電体" 共立出版, 51 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.YUGAMI: "SITEーSELECTIVE SPECTROSCOPY OF Eu^<3+> IN YSZ AND Y^<3+>ーDOPED CeO_2" Solid State Ionics. 40/41. 316-319 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.ARASHI: "TEMPERATURE DEPENDENCE OF XANES IN CeO_2ーTb_2O_<3.5> MIXED CONDUCTOR" Solid State Ionics. 40/41. 539-543 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.ANIYA: "Liquidlike model for thermal conductivity in superionic conductors" PHYSICAL REVIEW B. 41ー10. 7113-7117 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.WAKAMURA: "Observation of anomalously increasing phonon damping constant in the β phase of the fastーionic conductor Ag_3SI" PHYSICAL REVIEW B. 41ー5. 2758-2762 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] S.SHIN: "PROTONIC CONDUCTION IN THE SINGLE CRYSTALS OF SrZrO_3 AND SrCeO_3 DOPED WITH Y_2O_3" Solid State Ionics. 40/41. 910-913 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.TOMOYOSE: "Dynamical properties of layered superionic conductors" PHYSICAL REVIEW B. 41ー14. 10012-10020 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.ISHIGAME: "RECENT ADVANCES IN FAST ION CONDUCTING MATERIALS AND DEVICES" World Scientific Publishing Company, 601 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 嵐治夫: "Investigations of Valence Chage of Tb ions in Zro0_2-Tb_4O_7 Mixed Conductor Using XANES Measurements" Solid State Ionics. vol.35. 323-327 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 星埜禎男: "Structure and Dynamics of Quenched α-Phase fo Superionic Conductor Ag_3SI" Journal of the PHysical Society of Japan. Vol57. 4205-4199 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] 橘文夫: "Residence time and density distribution of silver ions in α-Ag_2Te by molecular-dynamics simulation" Physical Review B. vol.40. 3360-3363 (1989-I)

    • Related Report
      1989 Annual Research Report
  • [Publications] 武沢和義: "Contribution of optical phonons to sound velocity in piezoelectric semiconductors" Physical Review B. vol.41. 1204-1206 (1990-I)

    • Related Report
      1989 Annual Research Report
  • [Publications] 武藤禎嗣: "Raman Scattering of the Superiocnic Conducting Glasses in the System Agi-Ag_2O-MoO_3" Solid State Ionics. vol.35. 307-310 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 湯上浩雄: "Control of Oxygen Deficiency in Superconducting Y_1Ba_2Cu_3O_<7-y> Films Using a Solid-State Electrolyte" Japanese Journal of Applied Physics. vol.28. 1411-1414 (1989)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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