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Analytical Chemical Studies on SoluteーSolvent Interactions and Phase Transfer Reactions

Research Project

Project/Area Number 01303004
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 分析・地球化学
Research InstitutionKyoto University

Principal Investigator

MATSUI Masakazu  Kyoto Universty, Institute for Chemical Research Professor, 化学研究所, 教授 (90027037)

Co-Investigator(Kenkyū-buntansha) KIHARA Sorin  Kyoto University, Institute for Chemical Research, Associate Professor, 化学研究所, 助教授 (60161543)
SATO Masanori  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (30027859)
YOKOYAMA Yu  Osaka University, Fuculty of Science, Professor, 理学部, 教授 (10028095)
SENDA Mitsugi  Kyoto University, Faculty of Agriculture, Professor, 農学部, 教授 (90026419)
SUZUKI Nobuo  Tohoku University, Faculty of Science, Professor, 理学部, 教授 (10006025)
関戸 栄一  神戸大学, 理学部, 教授 (60030748)
Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 1990: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1989: ¥6,000,000 (Direct Cost: ¥6,000,000)
KeywordsSolute-Solvent interaction / Solute-Solute interaction / solvent-Solvent Interaction / Phase Transfer Reaction / Solvent Extraction / Spectrometric Measurement / Voltammetry at Liquid / Liquid Interface / Methods for Separation and Determination
Research Abstract

Results obtained in the present co-operative work are as follows.
Solute-solvent interaction in analytical chemical reactions. Solute-solvent interaction was evaluated through the studies on (1) solvent effects on the optical oxidation potentials of an ion, (2) solvent effects on the electrochemiluminescence, (3) reaction of hydroxide ion with electron acceptors in nonaqueous solvents, (4) ion association of metal perchlorates, and (5) complex formation between ion and solvent molecule.
Solute-slovent interaction and phase transfer reactions (solvent extraction). (1) Solvent extraction behavior of isopoly and heteropoly molybdates was systematized by applying solvatochromic parameters. (2) The solvatochromism was verified to be powerful for the explanation of solute-solvent interactions using macrocyclic tetramine nickel (II) complex. (3) Molybdophosphonate and molybdosulphate complexes were synthesized in a mixture of water and organic solvents, and their structures were determined. (4) … More Extraction behavior of silvior (I) complexes of tetrathio ethers was explained based on their structure. (5) The capacity factor of metal complexes in reversed phase liquid chromatography was evaluated taking into account the liquid-liquid partition modal. (6) Chirality recognition was improved employing the adduct formation of Lewis bases with beta-diketone chelates in various solvents (7) Some novel reagents were proposed for selective solvent extraction of metals.
Electrochemical studies on solute-solvent interaction. Voltammetry for ion transfer at the liquid/liquid interface was applied to elucidate (1) principles of ion sensors and their applicabilities to biochemical species and (2) the interaction between the ion transfer and the electron transfer at an aqueous/organic solution interface. Basic data relative to solute-solvent and solvent-solvent interactions was accumulated through measurements of liquid junction potentials between different solvents.
New analytical methods based on solut-solvent interaction. (1) A method for the determination of proton concentration in paper was developed extracting proton into nonaqueous solvent. (2) Method for speciation of actinide ions was proposed based on their complexing ability in aqueous media. Less

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (139 results)

All Other

All Publications (139 results)

  • [Publications] S.Miyazaki: "Steric Effects of Polymethylene Chain Length on LiquidーLiquid Extraction of Copper(2)with Bis(4ーAcylpyrazolー5ーOne)Derivatives" lnorganic Chemistry. 28. 3014-3017 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Ozaki: "Solvent Extraction of Zinc with 1ー(2'ーChlorophenyl)ー3ーMethylー4ーAroylー5ーPyrazolones" Anal.Chim.Acta. 226. 187-192 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] E.lwamoto: "Basicity of Water in HydrogenーBonded Networks of Methanolー1,2ーDichloroethane Mixtures Using the【(1R,4S,8R,11S)ー1,4,8,11ーTetraーMethylー1,4,8,11ーTetraazacyclotetradecane】Nickel(II)Cation as a Probe of ElectronーPair Acceptance" Bull.Chem.Soc.Jpn.62. 1692-1697 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Nakamura: "Response and Application in Dipolar Aprotic Solvents of lonーSelective Electrodes Based on Polyacrylamide Modified with Acyclic Poly(Oxyethylene)Derivatives" Bull.Chem.Soc.Jpn.62. 3089-3092 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Umemoto: "Electrochmical Studis of the Reduction Mechanism of Tetrazolium Salts and Formazans" Bull.Chem.Soc.Jpn.62. 3783-3789 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Kihara: "The Electron Transfer at a Liquid/Liquid lntece Studied by CurrentーScan polarography at the Electrolyte Dropping Electrode" J.Electroanal.Chem.271. 107-125 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Izutsu: "Blackwell Scientific Publications Ltd." Acidーbase dissiciation constants in dipolar aprotic solvents. 170 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] I.watanabe: "Elsevier Science Publishers" Electronic Stats of lons and Molecules in Solution Studied by Photoelectron Emission Spectroscopy,in“Structre and Dynamics in Solution"ed.by H.Yamatera and H.Ohtaki. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] E.Yamada: "Thermodynamic Study on the Wxtractoin of Codalt Comples with 8ーQuinoliol into 1,1,2,2ーTetrachloroethane" Bull.Chem.Soc.Jpn.62. 1047-1052 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y.Wakui: "Solvent Effect on the LiquidーLiquid Partition of 21H,23HーPorphine betwern Various Organic Solvents and Acidic Aqueous Solutions" Bull.Chem.Soc.Jpn.62. 2520-2523 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Sami: "Solvent Extraction of Lanthanoid(III)with 2,2'ーBipyridine and Trichloroacetate lon" Anal.Sci.5. 587-590 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Imura: "Synergistic Extration of Holmium(III)with 2ーThenoyltrifluoroacetone and Multidentate Heterocyclic Amines" Anal.Sci.5. 751-754 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Miyanaga: "Anomalous Peak Intetersity in EXAFS Fourier Tranforms for Polynuclear Molibdate" Plysica B. 158. 240-241 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] I.Watanabe: "Studies on the Structure of the Paramagnetic uーoxo Dimer of Molybdenum(V)in Hydrochloric Acid Solution by EXAFS" Polyhedron. 8. 45-49 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Sakane: "EXAFS and XANES Spectra of Cobalt(3)EDTAなComplex in Solid and Solutions" Bull.Chem.Soc.Jpn.62. 1513-1516 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Miyanaga: "Anomalous Peak Intensitres in EXAFS of Polynuclear Molybdeum Conpounds" Bull.Chem.Soc.Jpn.62. 1791-1796 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Ikeda: "Microtechnique for Chemical Analysis of Clinical Samples by Totally Reflecting Xーray Fluorescence Spectrometry and Inelastic Electron Tunneling Spectroscopy" Z.Anai.Chem.334. 676 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M.Suzuki: "Effect of Temperature on the lon Transfer at the Aqueous/Organic Solution Interface Studied by CurrentーScan Polarography with the Electrolyte Solution Dropping Electrode" J.Electroanal.Chem.292. 231-244 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Murata: "Extraction of Molybdenum(VI)from Aqueous Solution by Donor Solvent" Polyhedron. 9. 1717-1721 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Doe: "Conductometric Study of Calcium(II),Strontium(II),and Barium(II)Perchlorates in MethanolーEthylene Glycol Mixtures" Bull.Chem.Soc.Jpn.63. 2785-2789 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Mukai: "Steric Effect of OrthoーSubstituents of 1ーPhenylー3ーMethylー4ーAroylー5ーPyrazolones on the Synergic Extraction of Lutetium with Trioctylphosphine" Anal.Chim.Acta. 239. 277-282 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Tsurubou: "Stereoselective Adduct Formation of αーAcylーCamphorato Copper(II)Chelates with Some Chiral Lewis Bases" Anal.Chim.Acta. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Yokoyama: "Dimerisation of Dimethyl Sulphoxide in Dipolar Aprotic Solvents using R,S,R,Sー1,4,8,11ーTetramethylー1,4,8,11ーTetra Azacyclotetradecane Nickel(II) as a Probe" J.Chem.Soc.,Faraday Trans.86. 2937-2941 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] E.Iwamoto: "Reaction of 1,2ーDichloroethane with Pyridine using the 1R,4S,8R,11SーTetramehylー1,4,8,11ーTetraazacyclotetradecane Nickel(II)cation as a Probe" Bull.Chem.Soc.Jpn.64. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Izutsu: "Electrochemical Approach to lon Solvations.Applications of lonーSelective Electrodes as Sensors for lon Solvations and the Liquid Junction Potential between Different Solvents." Ansl.Sci.(1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Izutsu: "Liquid Junction Potential between Different Solvents.Component due to the Differences in Electrolyte Concentrations and Ionic Mobilities." J.Electroanal.Chem.(1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 坂本 一光: "アセチルアセトン中のイオンー溶媒間相互作用第8報。ナトリウムイオンー溶媒間錯生成反応とイオンの溶媒間移行" 分析化学. 39. 333-340 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M.Sato: "Electrochemiluminescent Detction for HPLC and FIA" Vl th International Symposium on Bioluminescence and Chemiluminescence. 105 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S.Himeno: "Voltammetric Determination of Phosphonate Ion as a Heteropply Complex" Talata. 37. 1071-1075 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] N.Suzuki: "HighーPerformance ThinーLayer Chromatography of Rare Earyh Tetraphenylporphine Complexes" J.Chromatogr.504. 179-185 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Chayama: "LiquidーLiquid Extraction of Palladium(II)with Phenyleneincorporated Tetrakis(thioether)s" Bull.Chem.Soc.Jpn.63. 2420-2422 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Chayama: "Extraction Behavior of Silver Ion with Cyclic and Acyclis Tetrathio Ethers and the Molecular Structures of the Silver Ion" Anal.Sci.6. 883-887 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Z.Yoshida: "Electrode Processes of Plutonium Ions in phosphate Media" Fresenium Z.Anal.Chem.(1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Z.Yoshida: "Stripping Coulometry of Trace Amount of Uranium with Twin Column Electrodes of Glassy Carbon Fibera" Proc.Internat.Trace Analysis Symp.‘90.439-442 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 澤田 恵夫: "Oーニトロフェニルエ-テル類/水界面の分極性とそのイオン移動ボルタンメトリ-への応用" 分析化学. 39. 539-545 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 山本 行隆: "アンペロメトリ-型イオン選択性電極に基礎をおくカリウム及びナトリウムイオンセンサ-" 分析化学. 39. 655-660 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Sakane: "Structures of Fe(III) Complexes with EDTA and EDDDA in Aqueous Solution by EXAFS and XANES" Inorg.Chim.Acta. (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Izumi: "Activation of Gold Electrode by Electrochemical OxidationーReduction Pretreatment in Hydrochloric Acid" J.Electroanal.Chem.(1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Doe: "Mass Transfer of Acetylacetone,Etylene Glycol MonoーnーButyl Ethyer and Ethylene Glycol Monophenyl Ether Across Water ーCarbon Tetrachloride and WaterーChloroform Intefaces" Anal.Chim.Acta. 237. 237-240 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Maeda: "Voltammetric Study on the Oscillation of the Potential Difference at a Liquid/Liquid of Liquid/Membrane Interface Accompanied by Ion Transfer" J.Electroanal.Chem.295. 183-201 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K.Maeda: "Voltammetric Intepretation of Ion Transfer Couqled with the Electron Transfer at a Liquid/Liquid Interface" J.Electroanal.Chem.(1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] I.Sakamoto: "Silver IonーSolvent Complexing in Acetylacetone and lonic Gibbs Energies of Transfer" J.Electroanal.Chem.286. 181-206 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 岡崎 敏: "溶媒とイオンー非水電解質溶液の化学" さんえい出版, 370 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Miyazaki: "Steric effects of polymethylene chain length on liquid-liquid extraction of copper(II)with bis(4-acylpyrazol-5-one) derivatives." Inorganic Chemistry. 28. 3014-3017 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Ozaki: "Solvent extraction of zinc with 1-(2'-chlorophenyl)-3-methyl-4-aroyl-5-pyrazolones." Anal. Chim. Acta. 226. 187-192 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] E. Iwamoto: "Basicity of water in hydrogen-bonded networks of methanol-1, 2-dichloroethane mixtures using the [(1R, 4S, 8R, 11S)-1, 4, 8, 11-tetra-mathyl-1, 4, 8, 11-tetraazacyclotetradecane]nickel(11) cation as a probe of electron-pair acceptance." Bull. Chem. Soc. Jpn. 62. 1692-1697 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Nakamura: "Response and application in dipolar aprotic solvents of ion-selective electrodes based on polyacrylamide modified with acyclic poly(oxyethylene)derivatived." Bull. Chem. Soc. Jpn. 62. 3089-3092 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Umemoto: "Electrochemical studies of the reduction mechanism of tetrazolium salts and formazans." Bull. Chem. Soc. Jpn.62. 3783-3789 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Kihara: "The electron transfer at a liquid/liquid interface studied by current-scan polarogrephy at the electrolyte dropping electrode." J. Electroanal. Chem.271. 107-125 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] E. Yamada: "Thermodynamic study on the extraction of cobalt complex with 8-quinolinol into 1, 1, 2, 2-tetrachloroethane." Bull. Chem. Soc. Jpn.62. 1047-1052 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Wakui: "Solvent effect on the liquid-liquid partition of 21H, 23H-Porphine between various organic solvents and acidic aqueous solutions." Bull. Chem. Soc. Jpn.62. 1047-1052 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Sami: "Solvent extraction of lanthanoid(III) with 2, 2'-bipyridine and trichloroacetate ion." Anal. Sci.5. 587-590 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Imura: "Synergistic extraction of holmium(III) with 2-thenoyltrifluoroacetone and multidentate heterocyclic amines." Anal. Sci.5. 751-754 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Miyanaga: "Anomalous peak intetersity in EXAFS fourier tranforms for polynuclear molibdate." Plysica B. 158. 240-241 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] I. Watanabe: "Studies on the structure of the paramagnetic mu-oxo dimer of molybdenum(V) in hydrochloric acid solution by EXAFS." Polyhedron. 8. 45-49 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Sakane: "EXAFS and XANES spectra of cobalt(III) EDTA complex in solid and solutions." Bull. Chem. Soc. Jpn.62. 1513-1516 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Miyanaga: "Anomalous peak intensitres in the EXAFS of polynuclear molybdeum conpounds." Bull. Chem. Soc. Jpn.62. 1791-1796 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Ikeda: "Microtechnique for chemical analysis of clinical samples by totally reflecting X-ray fluorescence spectrometry and inelastic electron tunneling spectroscopy." Z. Anal. Chem.334. 676 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Suzuki: "Effect of temperature on the ion transfer at the aqueous/organic solution interface studied by current-scan polarography with the electrolyte solution dropping electrode." J. Electroanal. Chem.292. 231-244 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Murata: "Extraction of molybdenum(VI) from aqueous solution by donor solvent." Polyhedron. 9. 1717-1721 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Doe: "Conductometric study of calcium(II), strontium(II), and barium(II) perchlorates in methanol-ethylene glycol mixtures." Bull. Chem. Soc. Jpn.63. 2785-2789 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Mukai: "Steric effect of ortho-substituents of 1-phenyl-3-methyl-4-aroyl-5-pyrazolones on the synergic extraction of lutetium wity trioctylphosphine." Anal. Chim. Acta. 239. 277-282 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Tsurubou: "Stereoselective adduct formation of alpha-acyl-camphorato copper(II) chelates with some chiral lewis bases." Anal. Chim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Yokoyama: "Dimerisation of dimethyl sulphoxide in dipolar aprotic solvents using R, S, R, S-1, 4, 8, 11-tetramethy-1, 4, 8, 11-terta-azacyclotetradecane nickel(II) as a probe" J. Chem. Soc., Faraday Trans.86. 2937-2941 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] E. Iwamoto: "Reaction of 1, 2-dichloroethane with pyridine using the 1R, 4S, 8R, 11S, -tetramethyl-1, 4, 8, 11-tetraazacyclotetradecane nickel(II) cation as a probe." Bull. Chem. Soc. Jpn.64.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Izutsu: "Electrochemical approach to ion solvations. Applications of ion-selective electrodes as sensors for ion solvations and the liquid junction potential between different solvents." Anal. Sci.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Izutsu: "Liquid junction potential between different solvents. Component due to the differences in electrolyte concentrations and ionic mobilities." J. Electroanal. Chem.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Sato: "Electrochemiluminescent detectopm for HPLC and FIA." VI th International Symposium on Bioluminescence and Chemiluminescence. 105 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Himeno: "Voltammetric determination of phosphonate ion as a heteropoly complex." Talanta. 37. 1071-1075 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] N. Suzuki: "High-Performance thin-layer chromatography of rare earth tetraphenylporphine complexes." J. Chromatogr.504. 179-185 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Chayama: "Liquid-liquid extraction of palladium(II) with phenylene-incorporated tetrakis(thioether)s." Bull. Chem. Soc. Jpn.63. 2420-2422 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Chayama: "Extraction behavior of silver ion with cyclic and acyclis tetrathio ethers and the molecular structures of the silver ion." Anal. Sci.6. 883-887 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Z. Yoshida: "Electrode processes of pultonium ions in phosphate media." Fresenium Z. Anal. Chem.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Z. Yoshida: "Stripping coulometry of trace amount of uranium with twin column electrodes of glassy carbon fibers." Proc. Internat. Trace Analysis Symp. '90.439-442 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] I. Sakamoto: "Sodium ion-solvent complexing and ion transfer between solvents." Bunseki Kagaku. 39. 333-340 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Sawada: "Polarizability of o-nitrophenyl ethers/water interfaces and its applicability to ion-transfer voltammetry." Bunseki Kagaku. 39. 539-545 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Y. Yamamoto: "Potassium and sodium ion sensor based on amperometric ion selective electrode." Bunseki Kagaku. 39. 655-660 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Doe: "Mass transfer of acetylacetone, ethylene glycol mono-n-butyl ether and ethylene glycol monophenyl ether across water-carbon tetrachloride and water-chloroform interfaces." Anal. Chim. Acta. 237. 237-240 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Maeda: "Voltammetric study on the oscillation of the potential difference at a liquid/liquid of liquid/membrane interface accompanied by ion transfer." J. electroanal. Chem.295. 183-201 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] I. Sakamoto: "Silver Ion-solvent complexing in acetylacetone and ionic gibbs energies of transfer." J. Electroanal. Chem.286. 181-206 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Maeda: "Voltammetric interpretation of ion transfer coupled with the electron transfer at a liquid/liquid interface." J. Electroanal. Chem.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Sakane: "Structures of Fe(III) complexes with EDTA and EDDDA in aqueous solution by EXAFS and XANES." Inorg. Chim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Izumi: "Activation of gold electrode by electrochemical oxidation-reduction pretreatment in hydrochloric acid." J. Electroanal. Chem.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Mukai: "Steric Effect of OrthoーSubstituents of 1ーPhenylー3ーMethylー4ーAroylー5ーPyrazolones on the Synergic Extraction of Lutetium with Trioctylphosphine" Anal.Chim.Acta. 239. 277-282 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Tsurubou: "Stereoselective Adduct Formation of αーAcylーCamphorato Copper(II) Chelates with Some Chiral Lewis Bases" Anal.Chim.Acta. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Yokoyama: "Dimerisation of Dimethyl Sulphoxide in Dipolar Aprotic Solvents using R,S,R,Sー1,4,8,11ーTetramethylー1,4,8,11ーTetraーAzacyclotetradecane Nickel(II) as a Probe" J.Chem.Soc.,Faraday Trans.86. 2937-2941 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] E.Iwamoto: "Reaction of 1,2ーDichloroethane with Pyridine using the 1R,4S,8R,11SーTetramethylー1,4,8,11ーTetraazacyclotetradecane Nickel(II)cation as a Probe" Bull.Chem.Soc.Jpn.64. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Izutsu: "Electrochemical Approach to Ion Solvations.Applications of IonーSelective Electrodes as Sensors for Ion Solvations and the Liquid Junction Potential between Different Solvents." Anal.Sci.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Izutsu: "Liquid Junction Potential between Different Solvents.Component due to the Differences in Electrolyte Concentrations and Ionic Mobilities." J.Electroanal.Chem.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 坂本 一光: "アセチルアセトン中のイオンー溶媒間相互作用第8報.ナトリウムイオンー溶媒間錯生成反応とイオンの溶媒間移行" 分析化学. 39. 333-340 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Sato: "Electrochemiluminescent Detection for HPLC and FIA" VI th International Symposium on Bioluminescence and Chemiluminescence. 105 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Himeno: "Voltammetric Determination of Phosphonate Ion as a Heteropoly Complex" Talanta. 37. 1071-1075 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] N.Suzuki: "HighーPerformance ThinーLayer Chromatography of Rare Earth Tetraphenylporphine Complexes" J.Chromatogr.504. 179-185 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Chayama: "LiquidーLiquid Extraction of Palladium(II) with Phenyleneーincorporated Tetrakis(thioether)s" Bull.Chem.Soc.Jpn.63. 2420-2422 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Chayama: "Extraction Behavior of Silver Ion with Cyclic and Acyclis Tetrathio Ethers and the Molecular Structures of the Silver Ion" Anal.Sci.6. 883-887 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Murata: "Extraction of Molybdenum(VI) from Aqneous Solution by Donor Solvent" Polyhedron. 9. 1717-1721 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Doe: "Conductometric Study of Calcium(II),Strontium(II),and Barium(II) Perchlorates in MethanolーEthylene Glycol Mixtures" Bull.Chem.Soc.Jpn.63. 2785-2789 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Doe: "Mass Transfer of Acetylacetone,Ethylene Glycol MonoーnーButyl Ether and Ethylene Glycol Monophenyl Ether Across WaterーCarbon Tetrachloride and WaterーChloroform Interfaces" Anal.Chim.Acta. 237. 237-240 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Maeda: "Voltammetric Study on the Oscillation of the Potential Difference at a Liquid/Liquid of Liquid/Membrane Interface Accompanied by Ion Transfer" J.Electroanal.Chem.295. 183-201 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Maeda: "Voltammetric Interpretation of Ion Transfer Coupled with the Electron Transfer at a Liquid/Liquid Interface" J.Electroanal.Chem.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] I.Sakamoto: "Silver IonーSolvent Complexing in Acetylacetone and Ionic Gibbs Energies of Transfer" J.Electroanal.Chem.286. 181-206 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Z.Yoshida: "Electrode Processes of Plutonium Ions in Phosphate Media" Fresenium Z.Anal.Chem.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Z.Yoshida: "Stripping Coulometry of Trace Amount of Uranium with Twin Column Electrodes of Glassy Carbon Fibers" Proc.Internat.Trace Analysis Symp.'90.439-442 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 澤田 惠夫: "Oーニトロフェニルエ-テル類/水界面の分極性とそのイオン移動ボルタンメトリ-への応用" 分析化学. 39. 539-545 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 山本 行隆: "アンペロメトリ-型イオン選択性電極に基礎をおくカリウム及びナトリウムイオンセンサ-" 分析化学. 39. 655-660 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Sakane: "Structures of Fe(III) Complexes with EDTA and EDDDDA in Aqueous Solution by EXAFS and XANES" Inorg.Chim.Acta. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Izumi: "Activation of Gold Electrode by Electrochemical OxidationーReduction Pretreatment in Hydrochloric Acid" J.Electroanal.Chem.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 岡崎 敏: "溶媒とイオンー非水電解質溶液の化学" さんえい出版, 370 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Miyazaki: "Steic effects of polymethylene chain length on liquid-liquid extraction of copper(11)with bis(4-acylpyrazol-5-one)derivatives." Inorganic Chemistry. 28. 3014-3017 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ozaki: "Solvent extraction of zinc with 1-(2´-chlorophenyl)-3-methyl-4-aroyl-5-pyrazolones." Analytica Chimica Acta. 226. 187-192 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] E.Iwamoto: "Basicity of water in hydrogen-bonded networks of methanol-l,2-dichloroethane mixtures using the[(1R,4s.8R,11S)-1,4,8,11-tetra-methyl-1,4,8,11tetraazacyclo-tetradecane]nickel(11)cation as a probe of electronpair acceptance." Bull.Chem.Soc.Jpn.62. 1692-1697 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Yokoyama,: "Dimerization of dimethyl sulfoxide in dipolar aprotic solvents using R,S,R,S-1,4,8,11-tetramethyl-1,4,8,11tetraazacyclotetracecanenickel(11)ad a probe." J.Chem.Soc.,Faraday Trans.

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Nakamura: "Response and application in dipolar aprotic solvents of ion-selective electrodes based on polyacrylamide modified with acyclic poly(oxyethylene)derivatives." Bull.Chem.Soc.Jpn.62. 3089-3092 (1989)

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      1989 Annual Research Report
  • [Publications] Z.Bai: "Enhanced voltammetric wave of iron(111)-EDTA at a chitin-containing carbon-paste electrode and its analytical application." Electroanalysis. 2. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Izutsu: "Liquid junction potential between different solvents.Some new informations on the component due to solvent-solvent interactions." J.Electroanal.chem.

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Umemoto: "Electrochemical studies of the reduction mechanism of tetrazolium salts and formazans." Bull.Chem.Soc.Jpn.62. 3783-3789 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Doe: "Conductometric study of Ca(II),Sr(II),and Ba(II)-perchlorates in methanol-ethlene glycol mixtures." Bull.Chem.Soc.Jpn.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Doe: "Transfer of acetylacetone,ehylene glycol mono-nbuthyl ehter,and ethylene glycol monophenyl ether across H_2O-CC1_4 and H_2-O-CHC1_3 interfaces." Anal.Chim.Acta.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Kihara: "The electron transfer at a liquid/liquid interface studied by current-scan polarography at the electrolyte dropping electrode." J.electroanal.Chem.271. 107-125 (1989)

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      1989 Annual Research Report
  • [Publications] M.Suzuki: "Effect of temperature on the ion transfter at the aqueous/organic solution interface studies by currentscan polarography with the electrolyte solution dropping electrode." J.Electroanal.Chem.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Sakamoto: "Ion-solvent interactions in acetylacetone VII. The effect of temperature on the complexing of silver ion with some donor solvents." 電気化学. 58. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 坂本一光: "アセチルアセトン中のイオン-溶媒相互作用第8報ナトリウムイオン-溶媒間錯生成反応とイオンの溶媒間移行" 分析化学. 39. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Sakamoto: "Silver ion-solvent compexing in acetylacetone and ionic gibbs energies of transfer." J.Electroanal.Chem.(1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] E.Yamada: "Thermodynamic study on the extraction of cobalt complex with 8-quinolinol into m1,1,2,2-tetrachloroethane." Bull.Chem.Soc.Jpn.62. 1047-1052 (1989)

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      1989 Annual Research Report
  • [Publications] Y.Wakui: "Solvent effect on the liquid-liquid partition of 21H,23H-porphine between various organic solvents and acidic aqueous solutions." Bull.Chem.Soc.Jpn.62. 2520-2523 (1989)

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      1989 Annual Research Report
  • [Publications] T.Sami: "Solvent extraction of lanthanoid(III)with 2,2´-bipyridine and trichloroacetate ion." Anal.Sci.5. 587-590 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Imura: "Synergistic extraction of holmum(III)with 2-thenoyltrifluoroacetone and multidentate heterocyclic amines." Anal.Sci.5. 751-754 (1989)

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      1989 Annual Research Report
  • [Publications] S.Himeno: "Synthesis and characterization of 18-moybdo-pyrophosphate complex." Bull.Chem.Soc.Jpn.

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Hori: "Formation of pentamolybdodisulfate(VI)(4-)ion in Na_2MoO_4H_2SO_4 systems containing organic solvents." J.Chem.Soc.Dalton.

    • Related Report
      1989 Annual Research Report
  • [Publications] Z.Yoshida: "Electrode processes of plutonium ions in nitric acid in the presence of phosphoric acid." Fresenius Z,Anal.Chem.

    • Related Report
      1989 Annual Research Report
  • [Publications] 関戸栄一: "Ni-8-キリノ-ル陽イオン錯体抽出のTBPEによるイオン対抽出" 日本化学会第48春季年会発表.

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      1989 Annual Research Report
  • [Publications] T.Miyanaga: "Anomalus peak intetersity in EXAFS fourier tranforms for polynuclear molibdate." Plysica B.158. 240-241 (1989)

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      1989 Annual Research Report
  • [Publications] I.Watanabe: "Studies on the structure of the paramagneticμ-oxo dimer of molybdenum(V)in hydrochloric acid solution by EXAFS." Polyhedron. 8. 45-49 (1989)

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      1989 Annual Research Report
  • [Publications] H.Sakane: "EXAFS and XANES spectra of cobalt(III)EDTA complex in solid and solutions ." Bull.Chem.Soc.Jpn.62. 1513-1516 (1989)

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      1989 Annual Research Report
  • [Publications] T.Miyanaga: "Anomalus peak intensitres in the EXAFS of polynuclear molybdeum conpounds." Bull.Chem.Soc.Jpn.62. 1791-1796 (1989)

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      1989 Annual Research Report
  • [Publications] S.Ikeda: "Microtechnique for chemical analysis of clinical samples by totatly reflecting X-ray fluorescence spectrometry and inelastic elctron tunneling spectroscopy." Z.Anal.Chem.334. 677 (1989)

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      1989 Annual Research Report
  • [Publications] K.Izutsu: "Acid-base dissociation constants in dipolar aprotic Solvents." Blackwell Scientific Publications Ltd., 170 (1990)

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      1989 Annual Research Report
  • [Publications] 岡崎敏: "溶媒とイオン-非水電解質溶液の化学" 谷口印刷出版部(松江市), 385 (1990)

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      1989 Annual Research Report
  • [Publications] I.Watanabe: "Electronic States of Ions and Molecules in Solution Studied by Photoelectron Emission Specroscopy,in "Structure and Dynamics in Solution"ed.by H.Ymatera and H.Ohtaki" Elsevier Science Publishers, (1990)

    • Related Report
      1989 Annual Research Report

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