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Observations of Surface Defects and Related Phenomena to Surface Defects

Research Project

Project/Area Number 01420017
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field Applied materials
Research InstitutionWaseda University

Principal Investigator

OSHIMA Chuhei  Waseda Univ. Appl. Phys. Professor, 理工学部, 教授 (10212333)

Co-Investigator(Kenkyū-buntansha) OHTSUKI Yoshihiko  Waseda Univ. Physics Professor, 理工学部, 教授 (50063649)
Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥20,500,000 (Direct Cost: ¥20,500,000)
Fiscal Year 1991: ¥6,200,000 (Direct Cost: ¥6,200,000)
Fiscal Year 1990: ¥6,200,000 (Direct Cost: ¥6,200,000)
Fiscal Year 1989: ¥8,100,000 (Direct Cost: ¥8,100,000)
KeywordsScanning LEED microscopy / Scanning tunneling microscopy / High resolution electron loss spectroscopy / Monolayer graphite / Reconstructed surface of Si / Si-metal Interfaces / Electromigration of metal islands on Si surfaces / Si表面構造 / 炭化物上の箪原子層グラファイト / エレクトロマイグレ-ション / 超高眞空走査型電子顕微鏡 / 表面エピタキシャル成長 / 表面・界面 / 表面格子欠陷
Research Abstract

Structures and defects in solid surfaces have been investigated by scanning LEED microscopy, scanning tunneling microscopy (SIM) and high-resolution electron energy-loss spectroscopy. The results obtained in 3 years are as follows :
1. Bonding state of monolayer graphite formed on TiC (lll)
The monolayer graphite formed on a single crystal surface of TiC (lll) has been investigated by high-resolution electron energy-loss spectroscopy. The dispersion of phonon spectra of the monolayer graphite on TiC shows anomalous bonding state between monolayer graphite and substrate. The bonding &tate is discussed based on the calculation.
2. initial. stage of epitaxial growth of metal film. s. on Si surfaces
Initial stage of epitaxial growth of various metal films on Si (001) and Si (111) 7x7 has been investigated by LEED, AES, -SIM and scanning LEED microscopy. We found a number of super-structures by LEED and several structures of them were determined by SIM. Furthermore, oscillatory diffusion of a Au-monolayer film on Si (lll) was discovered by scanning LEED microscopy.
3. Combination of scanning LEED microscopy with STM
The spatial resolution of scanning LEED microscopy has been improved by combination with STM. The chemical bonding state of monolayer graphite on TiC (lll) and a phase transition from single to doublle domain for Si (001) vicinal surfaces are investigated by this technique.
4. Electromigration of metal islands on Si (001)
Electromigration of metal islands formed on Si (001) has been investigated by ultrahigh vacuum SEM, For the origin of the driving force dn electromigration, it is found that local temperature difference due to the Peltier effect causes electromigration towards the direction to the high temperature by the effect of surface tension.
The 20 papers have been published during the term of this project.

Report

(4 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • 1989 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] T. Aizawa et al.: "Anomalous bond of monolayer graphite on transition metal carbide surfaces" Phys. Rev. Lett.64. 768-771 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Itoh et al.: "Scanning tunneling microscopy of monolayer graphite grown on a TiC (111) surface" Surf. Sci. Lett.254. L437-L442 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Ichinokawa et al.: "Surface analytical scanning electron microscopy in ultrahigh vacuum combined with scanning tunneling microscopy" Surf. & Interf. Analysis. 16. 87-96 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Ichinokawa et al.: "Oscillatory diffusion in gold submonolayers over the Si (111)7x7 surface" Surf. Sci. Lett.209. L144-L150 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Itoh et al.: "Low-energy electron diffraction and scanning tunneling microscopy studies on the Pt/Si (001) surface" Phys. Rev. B. (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Ichinokawa et al.: "Electromigration of metallic islands on Si (001) surface" Phys. Rev. Lett.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] A.Nagashima: "Electronic states of monolayer graphite formed on TiC(111) surface" Phys.Rev.B. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Itoh: "Scanning tunneling microscpy of monolayer graphite epitaxially grown on TiC(111) surface" Surf.Sci.254. L437-442 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Ichinokawa: "Epitaxial growth in Cu/Si(001)2X1 at high temperature" Surf.Sci.241. 416-424 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Itoh: "LEED and STM studies on the Pt/Si(001) surface" Phys.Rev.B. April. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Ichinokawa: "Electromigration of metallic islands on Si(001) surface" Phys.Rev.Lett.April. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Itoh: "Structure of doubleーatomicーheight steps in Si(001) vicinal surface observed by STM" Surf.Sci.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 大島 忠平: "固体表面上の単原子層グラファイト" 固体物理. 26. 37-43 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Ichinokawa: "Epitaxial Growth in Cu/Si(001)2x1 at High Temperatures" Surface Science. 241. 416-424 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Iizuni: "Electromigration of Metallic Islands on Si(100) Surface" Phys.Rev.Letter. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Ichinokawa: "Surface Analytical Electron Microscopy in Ultrahigh Vacuum Combined with Scanning Tunneling Microscopy" Surface and Interface Analysis. 16. 87-96 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Itoh: "Scanning Tunneling Microscopy of Monolayer Graphite on TiC(111) Surface" Surface Science. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 飯泉 浩志: "Si(100)上の金属クラスタ-のElectromigration" 日本学術振興会第141委員会資料. 66. 44-47 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] C.Ohshima: "STM Observation of monolayer graphite epitaxially grown on TiC(111)surface" Phys.Rev.B. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ichinokawa: "Analytical Scanning Electron Microscopy for Solid Surface" J.Electron Microscopy Technique.

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ichinokawa: "STM Observation of MoS_2 surface and gold clusters deposited on MoS_2 surface" J.Vac.Sci and Techn.Jan/Feb. 254-259 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ichinokawa: "Surface analytical scanning electron microscopy in UHV combined with scanning tunneling microscopy" Proc.ECASIA ′89(John Wiley and Sons Ltd.). 25-35 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ichinokawa: "Surface Defects of MoS2 crystal observed by Scanning LEED microscopy" Surface Science. 220. L2774-L2779 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ichinokawa: "Nueleation of Cu islands on Si(100)2x1 surface observed by scanning LEED microscopy" Surface Science. (1990)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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