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Study of formation and stability of helium cluster ions with a very low temperature drift tube

Research Project

Project/Area Number 01460047
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 物理学一般
Research InstitutionTokyo Metropolitan University

Principal Investigator

KOBAYASHI Nobuo  Tokyo Metropolitan University, Physics, Professor, 理学部, 教授 (30087100)

Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥6,500,000)
Fiscal Year 1991: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1990: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1989: ¥3,300,000 (Direct Cost: ¥3,300,000)
KeywordsHelium cluster ions / drift tube / magic number / ion mobility / orbittin resonance / 極低温移動管質量分析計 / オ-ビツティング共鳴 / 極低温移動管法 / 極低温度移動管
Research Abstract

A drift tube whose length is 10 cm is settled in a cryogenic system and cooled by liquid helium. In normal condition, the temperature of helium gas in the tube is about 4.5 k. When the liquid helium reservoir is evacuated with a pumping system, the temperature is lowered down to 3.5 k. Ions mass selected are injected into the tube. These ions are quickly thermalized by elastic collisions with He atoms and drift toward the end of the tube by a uniform electric field. Clusters are formed through three body collisions with He atoms during drifts of ions. The ions exited from the end of the tube are mass analyzed with a quadruple mass filter. Effective temperatures of the drifting ions are controlled by changing the electric field strength in the tube. Using this technique, following experiments have been made.
1). Stability of RgHe^+_ (Rg=He, Ne, Ar and Kr) have been studied. When the effective temperature of the ions are rather high, the clusters with larger size are dissociated by collisions with He atoms. Therefore, by measuring size distributions of clusters at various electric field strength, we can obtain an information on the stability of the clusters. It is suggested that an icosahedral structure with core ions He_2^+, NeHe^+, Ar^+ and Kr^+ is stable for RgHe_n^+ (Rg=He, Ne, Ar and Kr), respectively.
2) Stability of H^+He_n and H_3^+He_n. In the case of H^+He_n clusters, it is suggested that the stable structure is the icosahedron with the core ion HHe^+ like rare gas ions. On the other hand, for H_3^+He_n quite different structure with the magic number of n=10 and 11 is suggested to be stable.
3) Ion mobilities of He^+, Ne^+, Ar^+ and Kr^+ have been measured at gas temperature of 4.4 k. Many interesting features have been observed. Especially in the case of He^+, it has been found that the reduced mobility decreases below E/N=5 Td which may be attributed to an orbitting resonance.

Report

(4 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • 1989 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] T.M.Kojima: "Ion mobility measurements of He^+ in Hegas at 4.4K" Journal of The Physical Society of Japan. 61. 6-9 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T.M.Kojima: "Helium clustor ions Rg He_x^+)Rg=Ne,Ar,and Kr,x【less than or equal】14)formed in a drift tube cooled by liguid helium" Zeitschrift fiil physik D At.,Mol.and clusters. 22. 645-650 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T.M.Kojima: "Formation of helium cluster ions HHe_x^+(x【less than or equal】 in a very low temperature drift tuba" Zeitschrift fiil physik D At.,Mol.and clusters.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. M. Kojima: "Ion mobility measurements of He^+ in He gas at 4.4 k." J. Phys. Soc. Jpn.61. 6-9 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. M. Kojima: "Helium cluster ions RgHe_x^+ (Rg=Ne, Ar and Kr, x 14) formed in a drift tube cooled by liquid helium" Z. Phys. D Atoms, Molecules and Clusters. 22. 645-650 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. M. Kojima: "Formation of helium cluster ions HHe_x^+ (x 14) and H_3He_x^+ (x 13) in a very low temperature drift tube" Z. Phys. D Atoms, Molecules and Clusters.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T.M.Kojima: "Ion mobility measurements of He^+ in He Gas at 4.4K" Journal of the Physical Society of Japan. 61. 6-9 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.M.Kojima: "Helium cluster ions RgHe_x^+(Rg=Ne,Ar,and Kr,x⊆4)forned in a drift tube cooled by liguid helium" Zeitschrift fiir Physik D At.,Mol.and clusters. 22. 645-650 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.M.Kojima: "Formation of kelium cluster ions HHe_x^+(x⊆14)and H_3He_x^+(x⊆13)in a very low temperature dsift tube" Zeitschrift fiir physik D At,Mol and clusters.

    • Related Report
      1991 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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