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Evaluation of Mechanical and Electrical Properties of Diamond Synthesized from Gas Phase

Research Project

Project/Area Number 01460089
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 機械材料工学
Research InstitutionTokyo Institute of Technology

Principal Investigator

YOSHIKAWA Masanori  TIT, Engineering, Professor, 工学部, 教授 (30016422)

Co-Investigator(Kenkyū-buntansha) TOKURA Hitoshi  TIT, Engineering, Associate Prof., 工学部, 助教授 (10016628)
KONDO Iwao  TIT, Engineering, Research Associate, 工学部, 助手 (20016421)
Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 1990: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1989: ¥5,000,000 (Direct Cost: ¥5,000,000)
KeywordsDiamond film / Gas Phase synthesis / Laser planing / Thermo-chemical reaction / Ion beam planing / Cutting tool / Wear resistance / Amorphous carbon / レ-ザプレ-ニング / イオンビ-ムスパッタリング
Research Abstract

YAG laser cutting and planing of diamond films synthesized by arc discharge plasma jet CVD have been described. As a result, by controlling the energy density, cutting of a CVD diamond is possible. As for etching of CVD diamond in oxygen gas, preferentially amorphous carbon, grain boundary and fault in grain are vaporized and then diamond grains are oxidized. In the case of cutting, diamonds are removed by oxidization and Vaporization in the oxygen gas or by graphitization in the argon gas. Therefore by laser irradiation in the oxygen gas, clear cross sections were grained without graphite deposition. Moreover by controlling the incident angle, the surface planing is possible. The roughness of diamonds surface after planing by parallel incident laser beam was about 3um Rmax.
Polishing is a essential technique to apply diamond films to industrial uses. It has been cleared that diamond film can be polished by using thermochemical reaction. The optimum condition of diamond film polishing u … More sing hot metallic plates is determined experimentally. Although diamond films deposited by microwave plasma CVD are not firmly connected to the surface of substrates, under low applied pressure and slow spinning speeds, diamond film can be polished smooth without peeling off the substrate by using hot metals. In this study, the effects of polishing conditions on polishing rate are xamined by changing the polishing plate materials, temperatures, atmospheric gases, applied pressures and spinning speeds. As an optimum polishing condition, a 7x7 mm diamond film with a surface of 2.5um Rmax is polished at 950C in vacuum for 15 minutes, using an iron polishing plate under an applied pressure 40kPa and a spinning speed 7mm/s. A smoothly polished surface of 2.5nm Ra is obtained.
In order to estimate the toughness of diamond films, diamond coating on a ceramic and a PCD substrate were carried out. And by using these deposits as cutting tools, Al-Si alloys were turned. Though small peeling-off was observed on a ceramic substart diamond films did not wear even if 5452m of the cutting distance. It shows that the diamond films have good wear-resistance. Less

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] 吉川 昌範: "YAGレ-ザ照射による気相合成ダイヤモンド薄板の加工" 精密工学会誌. 56. 2255-2260 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉川 昌範: "ダイヤモンドコ-ティング工具によるセラミックスの切削" 精密工学会誌. 56. 165-170 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M.Yoshikawa: "Study on the Polishing of Diamond by Metal Plate" Proc.ASPE. 220-223 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉川 昌範: "熱化学反応によるダイヤモンド膜の研磨(1)" 精密工学会誌. 57. 184-189 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉川 昌範: "熱化学反応によるダイヤモンド膜の研磨(2)" 精密工学会誌. 57. 504-509 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉川 昌範: "イオンビ-ム照射によるダイヤモンド膜の平滑化" ダイヤモンドシンポジウム講演要旨集. 4. 61-62 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉川 昌範: "ア-ク放電プラズマジェットCVD法によるダイヤモンドの結晶成長" 精密工学会春季学術講演会講演論文集. 春. 181-182 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa: "Processing of CVD Diamond Films by YAG Laser" JSPE,. Vol. 56. 2255-2260 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa,: "Cutting of Ceramic Materials by Diamond Coated Cutting Tools" JSPE,. Vol. 56. 165-170 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa,: "Study on the Polishing of Diamond by Metal Plate" ASPE Proc.220-223 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa: "On Polishing of Diamond Film with Hot Metal-(1)" JSPE,. Vol. 57. 184-189 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa: "On Polishing of Diamond Film with Hot Metal-(2)" JSPE,. Vol. 57. 504-509 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa: "Smoothing of Diamond Films by Ion Beam Irradiation" Proc. Dia. Sympo.61-62 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Yoshikawa: "Morphology of a Diamond Prepared by Arc Discharge Plasma Jet CVD" Proc. JSPE Annual Meeting. 181-182 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 吉川 昌範: "イオンビ-ム照射によるダイヤモンド膜の平滑化" 第4回ダイヤモンドシンポジウム講演要旨集. 61-62 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 吉川 昌範: "気相合成ダイヤモンド粒の切断砥石への適用" 精密工学会1990年秋季学術講演会論文集. 秋季. 719-720 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 吉川 昌範: "YAGレ-ザ照射による気相合成ダイヤモンド薄板の加工" 精密工学会誌. 24. 2255-2260 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 吉川 昌範: "ダイヤモンドコ-ティング工具による過共晶Alー24%Si合金の切削" 精密工学会誌. 24. 2237-2242 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 吉川 昌範: "熱化学反応によるダイヤモンド膜の研磨" 精密工学会誌. 25. 184-189 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 吉川 昌範: "ア-ク放電プラズマジェットCVD法によるダイヤモンドの結晶成長" 精密工学会1991年春季学術講演論文集. 春季. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 吉川昌範: "YAGレ-ザ照射によるダイヤモンド薄板の切断" ダイヤモンドシンポジウム講演要旨集. 3. 85-86 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 吉川昌範: "YAGレ-ザ照射による気相合成ダイヤモンドの加工" 精密工学会1990年春季学術講演会論文集. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 吉川昌範: "ダイヤモンドと水素の反応における金属の影響" 精密工学会1990年春季学術講演会論文集. (1990)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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