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Elasticity and Unelasticity of Intermetallic Compounds

Research Project

Project/Area Number 01460213
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Physical properties of metals
Research InstitutionKyoto University

Principal Investigator

KOIWA Masahiro  Kyoto University Department of Metal Science and Technology, Professor, 工学部, 教授 (00005860)

Co-Investigator(Kenkyū-buntansha) NUMAKURA Hiroshi  Kyoto University Department of Metal Science and Technology, Instructor, 工学部, 助手 (40189353)
Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥7,000,000 (Direct Cost: ¥7,000,000)
Fiscal Year 1990: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1989: ¥4,500,000 (Direct Cost: ¥4,500,000)
KeywordsElastic constants / Rectangular parallelepiped resonance method / Intermetallic compounds / Nonstoichiometry / Ni-base compounds / Anisotropy factor
Research Abstract

1. The Rectangular Parallelepiped Resonance (RPR) method has been known to be a powerful method for determining the elastic constants, but the amount of numerical calculations for the data analysis is quite large. A new method of analysis is proposed, which is applicable to the case of specimens of cubic crystals. In this method, the resonance frequencies are calculated and stored for various combinations of Poisson's ratio, nu and anisotropy factor. A. The measured spectrum of resonance frequencies is compared in turn with the calculated spectra by a procedure of something like pattern comparison so as to determine roughly the values of elastic constants. Final refinements can be done successfully by the interpolation of the stored data.
2. The three elastic stiffness constants of various Ni-based intermetallic compounds Ni_3X (X=Mn, Fe, Al, Ga, Ge and Si) with L1_2 structure have been determined at room temperature by the rectangular parallelepiped resonance method. The elastic anisotropy factor, A, of the compounds is ge nerally large, ranging from 2.5 to 3.3, except for Ni_3Ge(A=1.71). The elastic constants exhibit some correlation with the lattice constants. The minor element, X, can be regarded as exerting "chemical pressure" which causes the expansion of the Ni lattice, thus resulting in the decreaseof the elastic constants.
3. The self-diffusion coefficients of both the constituents (D _<Ni> and D_<Ge> in Ni_3Ge) have been first measured for L1_2 compounds. The relation of the self-diffusivities in the temperature range from 1173 to 1273 K is given as follows : 22< D _<Ni>/D_<Ge><29, where D is self-diffusion coefficient.

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] M.Arita: "Diffusion Mechanisms in Ordered AlloysーA Detailed Analysis of Sixーjump Vacancy Cycle in the B_2 Type Lattice" Acta Metall.37. 1363-1374 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 小岩 昌宏: "金属間化合物における拡散" 日本金属学会会報. 28. 723-731 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Yasuda: "Determination of Elastic Constants of Single Crystais with Cubic Symmetry by Rectangular Parallepiped Resonance Method." Journal of Physis and Chemistry of Solids.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Yasuda: "Elastic Constants of Co_3Ti and CoTi Intermetallic Compounds." Materials Transactions,JIM.32. 48-51 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Yasuda: "Elasticity of Niーbased Ll_2ーtype Intermetallic Compounds." Acta Metallurgica.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Arita, M. Koiwa and S. Ishioka: "Diffusion Mechanism in Ordered Alloys -A Detailed Analysis of Six-jump Vacancy Cycle in the B_2 Type Lattice," Acta Metall.37. 1363-1374. (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Yasuda and M. Koiwa: "Determination of Elastic Constants of Single Crystals with Cubic Symmetry by Rectangular Parallepiped Resonance Method" J. Phys. Chem. Solids.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Yasuda, T. Takasugi and M. Koiwa: "Elastic Constants of Co_3Ti and CoTi Intermetallic Compounds," Mater. Trans., JIM.32. 48-51. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H. Yasuda, T. Takasugi and M. Koiwa: "Elasticity of Ni-based L1_2-type Intermetallic Compounds" Acta Metall.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] H.Yasuda: "Determination of Elastic Constants of Single Crystals with Cubic Symmetry by Rectangular Parallepiped Resonance Method." Journal of Physics and Chemistry of Solids.

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Yasuda: "Elastic Constants of Co_3Ti and CoTi Intermetallic Compounds." Materials Transactions,JIM.32. 48-51 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Yasuda: "Elasticity of Niーbased Ll_2ーtype Intermetallic Compounds." Acta Metallurgica.

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Arita: "Diffusion Mechanisms in Ordered Alloys-A Datailed Analysis of Six-jump Vacancy Cycle in the B_2Type Lattice" Acta Metall.37. 1363-1374 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 小岩昌宏: "金属間化合物における拡散" 日本金属学会会報. 28. 723-731 (1989)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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