| Project/Area Number |
01470023
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
有機化学一般
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| Research Institution | Osaka University |
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Principal Investigator |
SAWADA Masami Osaka University, the Institute of Scientific and Industrial Research, Associate Professor, 産業科学研究所, 助教授 (70029883)
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| Co-Investigator(Kenkyū-buntansha) |
TAKAI Yoshio Osaka University, the Institute of Scientific and Industrial Research, Research, 産業科学研究所, 助手 (20127244)
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| Project Period (FY) |
1989 – 1990
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| Project Status |
Completed (Fiscal Year 1990)
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| Budget Amount *help |
¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 1990: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1989: ¥3,700,000 (Direct Cost: ¥3,700,000)
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| Keywords | Substituent Effects / N-15 NMR SCS / O-17 NMR SCS / Solid Pt-195 NMR SCS / Solid C-13 NMR SCS / Pyridine N-Oxide / Platinum (II) Complex / LSFE Equation / 核磁気共鳴 / 置換基化学シフト / 固体高分解能NMR / Nー15 NMR化学シフト / Oー17 NMR化学シフト / アゾキシベンゼン / 拡張 湯川ー都野式 |
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| Research Abstract |
The project studies have been conducted for the five systems, especially aiming to clarify the Subーstituent electronic effects in a higher order approximation : (1) ^<17>O and ^<15>N nmr SCS (substituent chemical shift) of 4'-substituted -NNO- azoxybenzenes (AZOXY), (2) ^<15> nmr SCS of (4-substituted benzylidene) phenylamine-N-oxides (NITRON), (3) solid state ^<195>Pt and ^<13>C nmr SCS of 1-(4-substituted pyridine 1-oxide)-3-ethylene-2, 4-dichloro-platinum (II) complexes (PYNOPT), and further, (4) ^<17>O and ^<15>N nmr SCS of 3- and 4-substituted pyridine 1-oxides (PYNO), and (5) substituent effects on basicities of the PYNO derivatives.
The nmr SCSs of the entire systems, except for the PYNOPT one, can be best described in terms of the LSFE equation allowing the duality of resonance effects. The importance of such duality has been demonstrated for understanding the general electronic substituent effects of these hetero aromatic systems having N-O dative bonds. In the PYNOPT system, more reliable data, especially solid state ^<17>O and ^<15>N nmr SCS, have been waited for future analysis.
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