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Kinetic and Equilibrium Studies of Ion Association Reaction Between Ternary Heteropolyacids and Cat Ionic Dyes

Research Project

Project/Area Number 01470037
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 分析・地球化学
Research InstitutionOkayama University

Principal Investigator

MOTOMIZU Shoji  Okayama Univ., Faculty of Sci., Associate Prof., 理学部, 助教授 (50032826)

Co-Investigator(Kenkyū-buntansha) OSHIMA Mitsuko  Okayama Univ., Faculty of Sci., Associate, 理学部, 助手 (80108117)
Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 1990: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1989: ¥4,300,000 (Direct Cost: ¥4,300,000)
KeywordsHeteropolyacid / Ion association / Cationic dyes / Silica determination / Phosphate determination / Vanadate determination / イオン会合反応 / 吸光光度法 / リン / ケイ素 / ストップトフロ-法 / フォトダイオ-ドアレイ分光法
Research Abstract

1. Metal ions such as IV_A and V_A ions react with heteropolyacids of phosphate, arsenate and silicate to form ternary heteropolyacids. Such ternary heteropolyacids can react with cationic dyes to form colored ion associates. The colored ion associates can be used for the sensitive and selective determination of phosphate, arsenate and silicate : they are present in an aqueous phase, and floated on the interface between an organic and an aqueous phase and are extracted into an organic phase. In this research, the mechanism of the ion association reactions are investigated.
2. The characteristics and behavior of triphenylmethane dyes in an aqueous medium and in two-phase equilibrium has been examined spectrophotometrically by a stopped-flow method. The addition of water molecule to the centered carbon atom of the triphenylmethane dyes was found to be a rate-determining step, and also the elimination of -OH from the centered carbon atom was found to be a rate-determining step.
3. Various f … More actors affecting the formation rate of heteropolyacids was examined : organic solvent such as alcohols and acetone, quaternary ammonium ions and protonated triphenylmethane dyes was found to accelerate the formation reaction of heteropolyacids.
4. Ion association reaction of heteropolyacids with cationic dyes was examined. Molybdenum (VI) can form an ion associate with malachite green (MG^+) in an aqueous phase. Molybdovanadete forms an ion associate with HMG^<2+> to form a yellow associate. The ternary heteropolyacids such as vanadomolybdophosphate and zirconomolybdophosphate form ion associate with cationic dyes, as well as molybdophosphate and molydbdosilicate do. These ion associates can be used for the spectrophotometric determination of phosphate, silicate and vanadate.
5. The sensitive and selective methods for the determination of phosphorus, silicone and vanadium were developed on the basis of the formation of ion associate with cationic dyes. Silicone at concentrations of sub-ppt levels has been determined by spectrophotometry. Less

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] Shoji Motomizu: "Spectrophotometric Determination of Silicate in Water with Molybdate and Malachite Green" Analytical Sciences. 5. 85-88 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 本水 昌二: "イオン会合を利用する分離・分析法の設計" 分析化学. 38. 147-170 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Shoji Motomizu: "Spectrophotometric Determination of Silicate with Molybdate and Malachite Green by FlotationーDissolution and FiltrationーDissolution Methods" Analyst (London). 114. 1679-1685 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Shoji Motomizu: "FlotationーExtraction and Spectrophotometric Determination of Silicate with Molybdate and Cationic Dyes" Analytical Sciences. 5. 767-769 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Shoji Motomizu: "Sensitivity Enhancement in the Spectrophotometric Determination of Silicate by a FlotationーExchangeーExtraction Method Using an Ion Associate" Analyst (London). 115. 1627-1630 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 本水 昌二: "モリブドリン酸生成反応における反応促進剤" 分析化学.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Motomizu et. al.: "Spectrophotometric Determination of Silicate in Water with Molybdate and Malachite Green" Anal. Sci.5(2). 85-88 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Motomizu: "Design of useful methods for separation and analysis based on ion association reactions" Bunseki Kagaku. 38(4). 147-170 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Motomizu et. al.: "Spectrophotometric Determination of Silicate with Molybdate and Malachite Green by Flotation-Dissolution and Filtration-Dissolution Methods" Analyst (London). 114(12). 1679-1685 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Motomizu et. al.: "Flotation-Extraction Spectrophotometric Determination of Silicate with Molybdate and Cationic Dyes" Anal. Sci.5(12). 767-769 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Motomizu et. al: "Sensitivity Enhancement in the Spectrophotometric Determination of Silicate by a Flotation-Exchange-Extraction Method Using an Ion Associate" Analyst (London). 115(12). 1627-1630 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] S. Motomizu et. al.: "Reaction Promotion for the formation of molybdophosphate"

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Shoji Motomizu: "Spectrophotometric Determination of Silicate in Water with Molybdate and Malachite Green" Analytical Sciences. 5. 85-88 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] 本水 昌二: "イオン会合を利用する分離・分析法の設計" 分析化学. 38. 147-170 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] Shoji Motomizu: "Spectrophotometric Determination of Silicate with Molybdate and Malachite Green by FlotationーDissolution and FiltrationーDissolution" Analyst(London). 114. 1679-1685 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] Shoji Motomizu: "FlotationーExtraction and Spectrophotometric Determination of Silicate with Molybdate and Cationic Dyes" Analytical Sciences. 5. 767-769 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] Shoji Motomizu: "Sensitivity Enhancement in the Spectrophotometric Determination of Silicate by a FlotationーExchangeーExtraction Method Using an Associate" Analyst(London). 115. 1627-1630 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 本水 昌二: "モリブドリン酸生成反応における反応促進剤" 分析化学.

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Motomizu et al.: "Spectrophotometric determination of silicate in water with molybdate and malachite green" Analytical Science. 5. 85-88 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Motomizu et al.: "Spectrophotometric determination of silicate with molybdate and malachite green by flotation/dissolution and filtration/dissolution methods" Analyst(London). 114. 1679-1683 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Motomizu et al.: "Spectrophotometric determination for silicate with molybdate and cationic dves by flotation/extraction method" Analytical Science. 5. 767-769 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Motomizu et al.: "Spectrophotometric determination of silicate with molybdate and malachite green" Proceedings of the Third Korea-Japan Japan Joint Symposium on Analytical Chemistry. 201-206 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Motomizu et al.: "Sensitivity enhancement of silicate determination by flotation/exchange extraction" Analytical Chemistry.

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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