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Synthesis and characterization of the inorganic/carbon intercalation compounds

Research Project

Project/Area Number 01550587
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 無機工業化学
Research InstitutionGunma University

Principal Investigator

OYA Asao  Gunma University, Faculty of Engineering, Associate professor, 工学部, 助教授 (10008469)

Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1990: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1989: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsInorganic / carbon intercalation compound / Carbonization / organic intercalation compound / Carbothermal reduction / Titanium carbide / Tungsten carbide / Carbide single crystal / 有機層間化合物 / 無機@炭素層間化合物 / 無機@有機層間化合物 / 酸化モリブデン / 炭化モリブデン / 熱炭素還元
Research Abstract

Phenanthroline was inserted between the layers of MoO_3, WOP_2O_7 and Ti_2O_5 to prepare the inorganic/organic layer-type complexes. The resulting complexes were carbonized to deduce the inorganic/carbon intercalation compounds from them. Another purpose is to characterize the intercalation compounds obtained. Conclusions are as follows ;
1. The inorganic/carbon intercalation compound with an ideal structure was not prepared, but the compounds consisting of an imperfect carbon layer were synthesized, on which characterization has not been done.
2. The host inorganic layer reacted and changed before the inserted phenanthroline is completely carbonized. An inorganic layered compound with a higher thermostability or an acceleration technique of carbonization should be used.
3. The carbothermal reduction in the complexes occurred at lower temperature by several 100^゚C rather than the conventional inorganic compound/carbon black mixtures.
4. The reaction process of the complex by heating is substantially same to that of the conventional inorganic compound/carbon black mixture. The deposited crystalline phases were same in both samples with few exceptions.
5. After heating to high temperature, a crystal shape of the complex remained more completely than the conventional inorganic compound/carbon black mixture.

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] A.Oya,M.Kasahara,F.Ohashi and S.Otani: "Carbothermal reduction of MoO_3/phenanthroline complex" J.Am.Ceram.Soc.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] A.Oya,T.Saito and S.Otani: "Thermal degradation behavior of WOP_2O_7/phenanthroline complex" J.Mater.Sci.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] A.Oya,H.Itaya and S.Otani: "Thermal degradation behavior of Ti_2O_5/phenanthroline complex" J.Am.Ceram.Soc.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] A. Oya, M. Kasahara, F. Ohashi and S. Otani: "Carbothermal reduction of MoO_3/phenanthroline complex" J. Am. Ceram. Soc.,.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] A. Oya, T. Saito and S. Otani: "Thermal degradation behavior of WOP_2O_7/phenanthroline complex" J. Mater. Sci.,.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] A. Oya, H. Itaya and S. Otani: "Thermal degradation behavior of Ti_2O_5/phenanthroline complex" J. Am. Ceram. Soc.,.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Asao OYA: "Carbothermal reduction of MoO_3/phenanthroline complex" Journal of American Ceramic Society.

    • Related Report
      1990 Annual Research Report
  • [Publications] Asao OYA: "Thermal degradation behavior of WOP_2O_7/phenanthroline intercalation compound under nitrogen" Journal of American Ceramic Society.

    • Related Report
      1990 Annual Research Report
  • [Publications] Asao OYA: "Thermal degradation behavior of Ti_2O_5/phenanthroline intercalation compound under nitrogen" Journal of American Ceramic Society.

    • Related Report
      1990 Annual Research Report
  • [Publications] 大谷朝男: "Thermal degradation behavior of MoO_3/phenanthroline intercalation compound under nitrogen" Journal of Mterials Science.

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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