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高分子錯体の動的相互作用と電子過程

Research Project

Project/Area Number 01612004
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionWaseda University

Principal Investigator

土田 英俊  早稲田大学, 理工学部, 教授 (90063461)

Co-Investigator(Kenkyū-buntansha) 井口 洋夫  岡崎国立共同機構, 分子化学研究所, 所長 (00100826)
吉田 善一  京都大学, 工学部, 名誉教授 (60025814)
千田 貢  京都大学, 農学部, 教授 (90026419)
栗村 芳實  茨城大学, 理学部, 教授 (80007707)
戸嶋 直樹  東京大学, 工学部, 助教授 (50011010)
Project Period (FY) 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥23,000,000 (Direct Cost: ¥23,000,000)
Fiscal Year 1989: ¥23,000,000 (Direct Cost: ¥23,000,000)
Keywords高分子錯体 / 動的相互作用 / 電子過程 / 弱い配位系 / 多重相互作用 / 多電子移動 / 連続ポテンシャル場
Research Abstract

本総括班は、「高分子錯体」に属する各研究グループの中心になって、3年間にわたる研究計画の遂行を十分に徹底するとともに、研究計画の立案、調整、研究連絡、研究成果の取りまとめおよび関連研究分野との連携などを行い、本重点領域研究の効率よい展開を計った。第3年次として、全体研究計画のもと定量的・系統的な基礎解明を実験面で完了すべく、研究組織全員が一体となっての共同研究の推進を強力に支援するとともに、効率よい研究成果取りまとめのため、具体的に次を実施した。
(1)班長および総括班会議を延べ10回、全体会議2回を実施して、研究計画の推進、班間の連携強化、ならびに研究成果の評価と取りまとめを行った。また共同研究を直接支援した。
(2)合同班会議2回を合宿形式で実施し、班員間での共同と取りまとめ打ち合わせを徹底させた。また班を跨いだ課題のワークショップを設置した。
(3)本研究の内容を広く公開するため公開シンポジウムを2回(元年6月19日・20日・2年1月22日・23日)開催。いずれも多数の参加者を得、本研究の成果の公開と関連領域への波及に実を挙げることができた。
(4)高分子錯体に関する国内外の情報を集積し、広報するために「高分子錯体ニュース」を年4回(40〜60頁、各200部)発行した。
(5)研究協力者を置き,助言や実際的協力を得た。特に海外研究協力者4名を短期間招聘、公開シンポジウムでの講演を依頼、さらに滞在期間中に全班員との密度高い打ち合わせにより、充分な批判と国際的評価を得た。
(6)3年間の研究成果を取りまとめた元年度成果報告書(和文、英文)を発行した。
あわせ成書としての取りまとめ作業も進めた。

Report

(1 results)
  • 1989 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] E.Tsuchida,H.Nishide,M.Yuasa,E.Eshima,Y.Matsushita: ""Polymerized Liposome/LipidーHeme as an Oxygen Transporter under Physiological Condition"" Macromolecules. 22. 2103-2107 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] L.Wang,T.Takahashi,H.Ohno,E.Tsuchida: ""Porphnato Zinc Complexes Incorporated into the Bilayer Membrane of Lipid Liposomes"" J.Macromol.Sci.-Chem.A26. 481-493 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] L.Wang,H.Ohno,E.Tsuchida: ""Reversidle Association of Porphyrin Derivative Incorporate into Hydrophobic Region of Phospholipid Bilayer"" Polymer J.21. 505-510 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] S.Takeoka,H.Sakai,L.Wang,H.Ohno,E.Tsuchida: ""Study on the Phase Transition Behavior of Polymerized Liposomes through the Interaction of DieneーGroups in Their Acyl Chains"" Polymer J.21. 641-648 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Yamamoto,S.Yoshioka,H.Nishide,E.Tsuchida: ""Preparation of Poly(phenylene sulfide)s:Polymerization of Aromatic Disulfides with Lewis Acids"" Bull.Chem.Soc.Jpn.62. 3655-3660 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] E.Tsuchida,K.Yamamoto,M.Jikei,H.Nishide: ""New Synthesis of Poly(phenylene suflide)s through O_2 Oxidative Polymerization of Diphenyl Disulfide with VO Catalyst"" Macromolecules. 22. 4138-4140 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] E.Tsuchida,E.Hasegawa,Y.Chika,T.BabeH.Nishide: ""Oxygenation of Porphnatoiron(II)Containing Glycerophosphoーcholines in Phosphlipid Bilayers"" Chem.Lett.1989. 1727-1730 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] E.Tsucida,H.Ohno,N.Kobayashi,H.Ishizuka: ""Poly〔(ωーcarboxy1)oxyethylene)methacrylate〕as a New Type of Polymeric Solid Electrolyte for AlkaliーMetal Ion Transpot"" Macromolecules. 22. 1771-1775 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Ohono,E.Tsuchida: ""Design of Single Ionic Conduction in Polymeric Solid Electrolytes"" J.Macromol.Sci.-Chem.A26. 551-566 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] E.Hasegawa,M.Fukuzumi,H.Nishide,E.Tsuchida: ""Synthesis of a Negativelyーcharged Porphinatoiron(II)Having a Phosphoserine Groups and Oxygenation in Phospholipid"" Chem.Lett.1990. 123-126 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Y.Kurimura: ""Macromolecule Metal ComplexesーReactions and Molecular Recognition"" Adv.Polymer Sci.90. 106-138 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Y.Kurimura,T.Kikuchi,E.Tsuchida: ""ElectronーTransfer Reaction of Macromolecular Cobalt(III)Complex with Ru(NH_3)_6^<2+>.Effect of Microenvironment Occupied by Polymer Backbone"" Macromolecules. 22. 1645-1648 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] K.Miki,M.Senda: ""Bioelectrocatalysis at NADーDependent Dehydrogenase and DiaphroraseーModified Carbon Paste Electrodes Containing Mediators"" Anal.Sci.3. 269-274 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Ikeda,M.Senda: ""Amperometric Enzyme Electrode for Maltose based on an Oligosaccharide DehydrogenaseーModifed Carbon paste Electrode ContainingーBenzoquinone"" J.Electroanal.Chem.261. 351-362 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Kakiuchi,M.Senda: ""The Electrocapillary of the Phosphatidycholine Monolayer at the Polarzed OilーWater Interface.II.Double Layer Structure of Dilauroylphoatidylcholine Monolayer at the NitrobenzeneーWater Interface"" Bull.Chem.Soc.Jpn.62. 403-409 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] N.Toshima: ""Transient Spectroscopy of the Redox Reactions of the Prussian Blue Membrane Having Electronic State Gradient"" Chem.Lett.1989. 1099-1102 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] W.Mizutani,N.Toshima: ""Measurements of Copper Phythalocyanine Ultrathin Films by Scaning Tunneling Microscopy and Spectroscopy"" Jpn.J.App.Phy.28. L1460-L1463 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] N.Toshima: ""Colloidal Dispenrsions of PalladiumーPalldium Bimetallic Clusters Protected by Polymers.Preparation and Application to Catalysis"" Chem.Lett.1989. 1769-1772 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] I.Mita,K.Horie,K.Hirao: ""Photochemistry in Polymer Solids.9.Photoisomeriazation of Azobenzene in a Polycarbonate Film"" Macromolecules. 22. 558-563 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] A.Furusawa,I.Mita,K.Horie,K.Kuroki: ""Photochemical Hole Burning of Tetraphenylporphin in Phenoxy Resion at 4.2ー80K"" J.Appl.Phys.66. 6041-6047 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] A.Furusawa,K.Horie,I.Mita: ""Low Energy Excitation Modes of Amorphous Polymers Probed by Photochemical Hole Burning"" Chem.Phys.let.161. 227-231 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Nishide,M.Ohyanagi,K.Suenaga,E.Tsuchida: ""OxygenーPermeation in Siliconeーbound Cobaltporphyrin Membrane"" J.Polym.Sci.,Polym.Chem.Ed.27. 1439-1443 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] H.Nishide,H.Kawakami,Y.Kurimura,E.Tsuchida: ""Revercible Coordination and Facilitated Transport of Molecular Nitrogen in Poly(vinylーcyclopentadienylmanganese)Membrane"" J.Amer.Chem.Soc.111. 7175-7179 (1989)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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