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Development of a Device for Trace Gas Concentration Measurement Based on the Quick Scanning Tunable Diode Absorption Spectrometry

Research Project

Project/Area Number 01850091
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 計測・制御工学
Research InstitutionOkayama University.

Principal Investigator

KOGA Ryuji  Okayama Univ., Fac. Engineering, Professor., 工学部, 教授 (20027147)

Co-Investigator(Kenkyū-buntansha) WADA Osami  Okayama Univ., Fac. Eng., Lecturer., 工学部, 講師 (10210973)
SANO Hiroya  Fukuyama Univ., Fac. Eng., Professor., 工学部, 教授 (10033143)
KOSAKA Megumi  Okayama Univ., Fac. Eng., Teaching Assistant., 工学部, 教務員 (00170233)
Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥12,500,000 (Direct Cost: ¥12,500,000)
Fiscal Year 1991: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1990: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1989: ¥10,100,000 (Direct Cost: ¥10,100,000)
KeywordsAtmosphere / Methane / Concentration / Real-Time / Non-contact / Long-path / Scintillation / Tunable-Diode-Laser / 鉛塩半導体レ-ザ
Research Abstract

A device to measure atmospheric methane concentration has been developed. Its principle is based on measuring the absorption spectrum of atmosphere along the laser beam running over a long-path of 1 to 150m through open air. A PbSnTe tunable diode laser-fabricated by Fujitsu Laboratories Ltd. was employed, which covers the nu_4 band around nu=1300 cm^<-1> at around 77K of the diode temperature. Theoretical sensitivity is as low as 0.8 ppb with 50m optical path length.
A portable device was constructed comprising an optical head, a retro-reflector, an electronic systems and a personal computer along with a battery power supply. Temporal resolution is possible to be as short as 10 seconds for each measured concentration of methane.
Subjects to be newly developed were the optical architecturecomprising laser-beam transmitter/ receiver and corner-cube retroreflectors, electronic circuit system's to extract the second higher harmonic spectrum and the software that derive methane concentration from the measured spectrum suppressing spectral interferences.
Three measurements which are continuous for 24 or 48 hours were achieved in the experimental rice-paddy field of Okayama University. A quick response of atmospheric methane density to soil temperature were confirmed. This is due to the non-contact and real-tithe characteristic of our device in contrast to the chamber method. Results are compared with those by the gas chromatography and by, -the chamber method. The device was safe after two sudden rain-storms attacked it, which eventually demonstrated the reliability of the device.
Additional research on the atmospheric scintillation in the far infrared region were carried for the further improvement of this system.

Report

(4 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • 1989 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] Ryuji Koga: "A Quick Spectrophotometry of Atmopheric Gas Density with Tunable Diode Lasers and Digital Signal Processing" The 1st China-Japan Int.Symp.on Instrumentation,Measurement and Automatic Control,November 1989. 96-103 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef Bouzidi: "Spectrometric Measurement of Atmospheric CH_4 with a Tunable Pb-Salt Diode Laser Relevant to the Prediction of Global" INSTRUCTION AUX AUTEURS DES COMMUNICATIONS AUX JOURNEES TUNISIENNES D'ELECTROTECHNIQUE ET D'AUTOMATIQUE,December 1989. (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef Bouzidi: "Second Harmonic Detection of Atmospheric Trace Gases with a Train-Pulse Driven Lead-Salt Tunable Diode Laser for an Operation at Peltier" Memoirs of the Faculty of Engineering,Okayama University. 25. 37-50 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef Bouzidi: "Application of the Adjoint Spectrum to the Frequency Tracking in Spectrometry with Tunable Diode Lasers" Memoirs of the Faculty of Engineering,Okayama University. 26. 43-49 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Ryuji Koga: "Tunable Diode eSpectrometry of Atmospheric Methane Density with a Long and Open Optical Path for in situ and Real-Time Measurements under Turbulent" Proceeding of the First Asia/Pacific Inernational Symposium on Instrumentation,Measurement and Automatic Control,Shanghai China,August 1991. 55-60 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef Bouzidi: "Adjoint spectrum I;an algorithm to extract target spectra under spectral interferences for use in on-line spectrometry" Japan.J.Appl.Phys.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Naoki Kagawa: "Suppression of etalon fringe in an absorption spectrometry with infrared tunable diode laser" Japan.J.Appl.Phys.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Ryuji Koga, Bouzidi Moncef, Xu hai, Osami Wada and Hiroya Sano: "A Quick Spectrophotometry of Atmospheric Gas Density with Tunable Diode Lasers and Digital Signal Processing" The 1st China - Japan Int. Symp. on Instrumentation, Measurement and Automatic Control. November. (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Bouzidi Moncef, Ryuji Koga, Osami Wada and Hiroya Sano: "Spectrometric Measurement of Atmospheric CH_4 with a Tunable Pb-Salt Diode Laser Relevant to the Prediction of Global Temperature Rise" Instruction Aux Auteurs Des Communications Aux Journies Tunisiennes D'Electrotechnique et D' Automatique (J. T. E. A). December. (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef Bouzidi, Ryuji Koga, Osami Wada, Naoki Kagawa, Xu Hai, Megumi Kosaka and Hiroya Sano: "Second Harmonic Detection of Atmospheric Trace Gases with a Train - Pulse Driven Lead - Salt Tunable Diode Laser for an Operation at Peltier Cooling Temperature" Memoirs of the Faculty of Engineering, Okayama University. 25, No. 1, November. (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef Bouzidi, Ryuji Koga, Osami Wada, Naoki Kagawa, Xu Hai, Megumi Kosaka and Hiroya Sano: "Application of the Adjoint Spectrum to the Frequency Tracking in Spectrometry with Tunable Diode Lasers" Memoirs of the Faculty of Engineering, Okayama University. 26, No. 1, November. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Ryuji Koga, Naoki Kagawa, Moncef Bouzidi, Xu Hai, Osami Wada and Hiroya Sano: "Tunable diode spectrometry of atmospheric methane density with a long and open optical path for in situ and real - time measurements under turbulent conditions" Proceeding of the First Asia / Pacific International Symposium on Instrumentation, Measurement and Automatic Control, Shanghai, China. August. (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Moncef BOUZIDI, Naoki KAGAWA, Osami WADA and Ryuji KOGA: "Adjoint spectrum I : an algorithm to extract target spectra under spectral interferences for use in on - line spectrometry." Japan. J. Appl. Phys.(1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Naoki KAGAWA, Osami WADA, and Ryuji KOGA: "Suppression of etalon fringe in an absorption spectrometry with infrared tunable diode laser." Japan. J. Appl. Phys.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] R.Koga,M.Bouzidi,H.Xu,O,Wada and H.Sano: "A quick spectromety of atmospheric gas density with tunable diode lasers and digital signal processing" Proceedings of the first China-Japan international symposium on instrumentation,measurement and automatic control. 96-103 (1989)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2019-02-15  

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